The invention relates to preparation of a TpHz-TFHz
composite material and application of the TpHz-TFHz
composite material in photocatalytic full
water splitting performance. In order to solve the problems of low light
utilization rate and low total
water splitting efficiency of the existing single COF materials, namely TpHz and TFHz photocatalytic total
water splitting materials, the invention provides a preparation method of a novel TpHz-TFHz
composite material, which comprises the following steps: firstly, mixing 1, 3, 5-trialdehyde
phloroglucinol, hydrazine
hydrate, 2, 4, 6-tri (4-
aldehyde phenyl)-1, 3, 5-trialdehyde
phloroglucinol, hydrazine
hydrate and 2, 4, 6-tri (4-
aldehyde phenyl)-1, 3, 5-tri (4-
aldehyde phenyl)-1, 3, 5-tri (4-aldehyde phenyl)-1, 3, 5-tri (4-aldehyde phenyl)-1, 3, 5-tri (4-aldehyde phenyl) The preparation method comprises the following steps: uniformly stirring 1, 3, 5-
triazine and hydrazine
hydrate in a
mixed solution of DMSO,
ethanol and
acetic acid to prepare TpHz COF and a TFHz COF precursor; and heating the two obtained COF precursors at 120 DEG C for 72 hours by a solvothermal method, and reacting to obtain the TpHz-TFHz composite material. The preparation process is simple and effective, the
reagent consumption is low, and the yield is high; the photocatalyst provided by the invention can effectively solve the problem of low photocatalytic complete water splitting efficiency, experiments show that the composite material has excellent photocatalytic complete water splitting performance, the rate of
hydrogen production by complete water splitting under
visible light irradiation can reach 70.71 [mu] mol.h <-1 >. G <-1 >, and the rate of
oxygen production can reach 35.35 [mu] mol.h <-1 >. G <-1 >.