48 results about "Strontium borate" patented technology

The invention relates to a large size potassium strontium borate nonlinear optical crystal, the preparation and use thereof. The formula of the crystal is: KSr4B3O9, which belongs to rhombic system, the space group is Pna2(1), and the molecular weight is 566.01, and the crystal size is 10-60mmx10-60mmx10-60mm. The preparation contains the following steps of: evenly mixing the potassium strontium borate compound with a fusing assistant, heating, maintaining the constant temperature, cooling to the saturation temperature and obtaining a mixture solution, placing a seed crystal into the mixture solution, lowering the temperature to the saturation temperature to obtain the required crystal, and subsequently extracting the crystal from the liquid level, cooling to room temperature, and finally obtaining the large size potassium strontium borate nonlinear optical crystal. The nonlinear optical effect of the crystal is approximately the same as the KDP, the transparent optical band is 220nm-3000nm. The crystal is simple in operation, low in cost, large in crystal size, short in growth period, less in coating, high in laster damage threshold, good in mechanical property, firm, stable in physicochemical properties, uneasy to deliquescence, convenient for processing and storage, or the like. Accordingly, the nonlinear optical crystal of the invention can be abroadly applied in nonlinear optical devices such as frequency doubler, optical parametric oscillator or the like.

Strontium, calcium, strontium calcium, strontium calcium magnesium, calcium magnesium aluminates, and strontium borates activated with Pr3+ exhibit characteristics of quantum-splitting phosphors under VUV excitation. A large emission peak at about 405 nm under VUV excitation is used conveniently to identify quantum-splitting phosphors. Improvements may be achieved with addition of fluorides or boric acid as a flux during the preparation of the phosphors. It is also possible to predict improvement in quantum efficiency by observing the ratio of emission intensities at about 480 nm and about 610 nm.

The invention relates to a preparation method of strontium fluoroborate nonlinear optical crystals, and applications of the strontium fluoroborate nonlinear optical crystals. Compound synthesis is realized via solid phase reaction, and crystal growth is realized via flux growth method. The preparation method is simple in operation, and low in cost. The obtained strontium fluoroborate nonlinear optical crystals will not deliquesce in the air, possesses excellent mechanical properties and stable physico-chemical properties, is unbreakable, is convenient for processing, and is suitable for preparation of nonlinear optical devices. Frequency-doubled effect of the strontium fluoroborate nonlinear optical crystals obtained by the preparation method is three times of that of KDP, and the strontium fluoroborate nonlinear optical crystals can be widely used in nonlinear optical devices such as double frequency converters and optical parametric oscillators.

A erbium- and ytterbium-intermingled gadolinium-strontium borate laser crystal and its preparing method and its use, relate to artificial lens field. Er3+/Yb3+:Sr3Gd(BO3)3 crystal having high quality and bigger size is produced by the pulling method at 1354 DEG C, at the crystal rotational speed of 5-20 turns/minute, under the drawing speed of 0.5-2 mm/hour. The crystal belongs to trigonal system, space group of which is R3, and the refractive index is 1.73. The crystal is a novel Erbium- and ytterbium-intermingled laser crystal, which is suitable to be pumped by laser diode(LD), accordingly the infrared laser output of 1.5 mum wavelength can be reduced.

The invention discloses a nonlinear optical crystal material Sr3Y3BiB4O15 and a preparation method and application thereof. The crystal material is bismuth yttrium strontium borate shown as the chemical formula of Sr3Y3BiB4O15, belongs to a hexagonal system, and has the space group of P63 and the unit cell parameters of a=10.6975(13)A and c=6.7222(12)A. A crystal structure comprises BO3 radicals which are arranged in accordant direction and a BiO3 radical with lone pair electrons which are arranged in accordant direction, so that nonlinear effect is 3 to 5 times that of KH2PO4. A crystal has moderate hardness, is free from being deliquesced or cleaved, and is easy to cut, polish and store. The crystal grows by a flux growth method. The preparation method comprises the following steps of: mixing bismuth yttrium strontium borate and a fluxing agent; heating the mixture to obtain solution; stirring; preserving heat; cooling until the temperature is 0.5 to 3 DEG C above a saturation point; adding crystal seeds; controlling an appropriate temperature lowering speed; when the crystal grows to a certain degree, extracting the crystal out of a liquid surface; and slowly lowering the temperature to room temperature so as to obtain Sr3Y3BiB4O15 monocrystal. The crystal can serve as a frequency doubling crystal in an optical parametric oscillator and a harmonic generator. Moreover, the crystal comprises a yttrium element, so that other rare earth ions can be doped so as to obtain a self-frequency-doubling laser crystal.

The invention discloses a lithium strontium borate non-linear optical crystal, wherein the molecular formula of lithium strontium borate is LiSrB9O15; the crystal belongs to trigonal system; the space group is R3c; the crystal cell parameters are as follows: a is equal to 10.6096(2)Angstrom, b is equal to 10.6096(2)Angstrom, c is equal to 17.5423(9)Angstrom, Alpha and Beta are equal to 90 degrees, Gamma is equal to 120 degrees and Z is equal to 6; the light-transmitting wave band of the crystal is 190-3000 nm; the non-linear optical effect is about 2.5 times of KDP; a Q-switched Nd:YAG laser (1064 nm) is used as a light source and can generate laser radiation with the wavelength of 532 nm; the crystal is not deliquescent, can reach centimetre level in size and is easy to cut, polish and preserve. The crystal can be used for manufacturing non-linear optical devices, such as double frequency generators, upper frequency converters, lower frequency converters or optical parameter oscillators.

A UV-emitting phosphor comprising SrB₄O₇:Eu phosphor particles that have been treated to yield a surface layer containing from greater than 0 to about 25 atomic percent aluminum. The holdover stability of the treated SrB₄O₇:Eu phosphor improves the 100-hour maintenance in a fluorescent tanning lamp to the extent that the treated phosphor may be subject to a holdover period of more than 25 days without a significant change in its 100-hour maintenance.

The invention discloses a europium-doped lanthanum strontium triborate-based green fluorescent powder, which uses Sr3La(BO3)3 as a matrix, and has a general chemical formula of Sr3-xLa(BO3)3:xEu, wherein 0.02≤x≤0.20, through Doped with activated ions Eu3+ to prepare europium-doped lanthanum strontium triborate-based green light emitting phosphors. Under near-ultraviolet and blue light excitation, red light with a main peak at around 615nm is obtained, which is suitable for near-ultraviolet or blue light excitation, and the emission peaks are located at 594nm respectively. , 615nm, 625nm, 709nm, the color coordinates are located in the red light region, the chemical properties are stable, the luminous performance is good, the luminous intensity is high, and the color rendering is good. It is a green phosphor with excellent luminous performance; the invention also discloses its preparation Method: SrCO3, La2O3, H3BO3 and Eu2O3 are mixed and ground, calcined in the air atmosphere, kept warm, cooled with the furnace and then ground, and finally europium-doped lanthanum strontium triborate-based green phosphor is obtained, which is prepared based on solid-phase synthesis method , strong operability, simple heating process, simple method, good reproducibility, and short preparation period.

The invention relates to a preparation method for a nano-structure strontium borate SrB6O10/5H2O:Eu<3> luminous material. According to the invention, the strontium borate is uniform in shape and adopts a nano structure assembled by nanosheets, and the thickness of each of the nanosheet is 100 nm; and analytic reagents SrOH2/8H2O, Na2B4O7/10H2O, H3BO3 and EuNO3, which are purchased through commercial sources, are taken as main raw materials, and a simple water solution reaction method is adopted to prepare the material under the assistance of additives at the temperature of 50-80 DEG C. The method is simple and low in reaction temperature. The strontium borate SrB6O10/5H2O:Eu<3> luminous material is high in color purity and in rare earth ion quenching concentration, and strong in Eu<3> stability compared with an anhydrous strontium borate substrate luminescent material SrB6O10:Eu<3>, and can be applied to the fields of development displaying, light sources and the like.

The invention relates to a method for preparing strontium chloroborate whiskers. The method comprises the following steps: (1) uniformly mixing a strontium-containing raw material, a boron-containing raw material and a flux, and then grinding to a particle size of less than 60 mesh to obtain a mixed raw material; (2) ) placing the mixed raw materials in a high-temperature furnace, raising the temperature to 650-800° C. at a heating rate of 5-10° C./min, keeping the temperature for 6-15 hours, and cooling naturally to obtain a sintered product; (3) sintering the The product is put into deionized water, soaked for 2 to 15 hours, filtered and washed to obtain a white solid powder of the crude product; (4) drying the solid powder of the crude product to constant weight to obtain white strontium chloroborate crystals beard products. The invention has simple process and low cost, and the obtained strontium chloroborate whisker product has good microscopic appearance, high product purity and high yield.

The invention relates to a compound mono-boric dihydroxyl strontium decaborate monohydrate nonlinear optical crystal and a preparation method and use thereof. The compound mono-boric dihydroxyl strontium decaborate monohydrate nonlinear optical crystal has a chemical formula of Sr2(B5O8(OH))2B(OH]3.H2O, has the molecular weight of 653.21, belongs to a monoclinic crystal system, has the space group of P21 and has the crystal cell parameters that a is equal to 6.7003(2) angstroms, b is equal to 20.7996(3) angstroms, c is equal to 6.6013(3) angstroms, beta is equal to 119.2503(3) degrees, and V is equal to 802.53(3) angstroms<3>. The compound nonlinear optical crystal is obtained through a programmed cooling or natural cooling method by adopting a hydrothermal method; the powder frequency-doubled effect of the crystal is about twice that of KDP(KH2PO4), and the ultraviolet cutoff edge of the crystal is smaller than 190nm, so that the crystal can serve as a deep-ultraviolet nonlinear optical crystal. A growth process of the crystal has the advantages of simplicity in operation, low cost, low raw material toxicity, short growth cycle, stable physicochemical properties and the like, and the crystal is extensively applied to nonlinear optical devices, such as frequency doubling generators, up frequency converters, down frequency converters or optical parametric oscillators.

The invention discloses Tb<3+>-activated activated barium strontium fluoborate green fluorescent powder as well as preparation and application thereof. The general chemical formula of the fluorescentpowder is Ba<3-x>Tb<x>Sr2B4O10F2, wherein x is the substitution molar ratio of Tb<3+> to Ba<2+>, and x is greater than or equal to 0.005 and less than or equal to 0.35. The method comprises the following steps: (1) preparing fluorine-free barium strontium borate precursor powder Ba<2-x>TbxSr2B4O10 by using a chemical sol-gel method; and (2) adding barium fluoride and ammonium fluoride into the prepagreen fluorine-free barium strontium borate precursor powder, fully mixing all the components, tabletting the mixture, and then preparing the Tb<3+>-activated barium strontium fluoborate green luminescent fluorescent powder Ba<3-x>Tb<x>Sr2B4O10F2 through solid-phase sintering. The green fluorescent powder is in a pure phase and uniform in particle, can emit green light with the central wavelength of 545 nanometers under excitation of near ultraviolet light 276 nanometers, and is high in luminous intensity and good in thermal stability; therefore, the green fluorescent powder can be used forpreparing an illumination or display device taking near ultraviolet light as an excitation light source.

The invention discloses a divalent-bismuth-ion-doped strontium borate fluorescent material and a preparation method thereof. The preparation method comprises the following steps of: respectively weighing compound raw materials containing strontium, boron and bismuth according to a molecular formula: Sr1-xB4O7:xBi or Sr1-xB6O10:xBi, wherein x is not less than 0.001 and not more than 0.05; evenly grinding and mixing the raw materials, then, preburning, and controlling the temperature at 300-500 DEG C; after preburning, evenly grinding and mixing again, carrying out high-temperature burning twice, and controlling the temperature at 600-900 DEG C; and putting a sample in a reducing atmosphere at the temperature of 600-900 DEG C, and carrying out reaction for 15 min to 10 hours. The luminous intensity of the fluorescent powder prepared by the preparation method disclosed by the invention is over 2 times or 140 times of that of a bismuth-doped sample with the same concentration, which is synthesized in an air atmosphere, and the color-rendering performance of a white LED (Light Emitting Diode) is hopeful to improve.