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48 results about "Superoxide ions" patented technology

Superoxide is the anionic form O2. It is important as the product of the one-electron reduction of dioxygen (oxygen gas), which occurs widely in nature. With one unpaired electron, the superoxide ion is a free radical. It is also paramagnetic.

Preparation method and application for two-dimensional metal organic framework nanosheet

The invention discloses a two-dimensional metal organic framework nanosheet and a preparation method thereof. The preparation method comprises the following steps: adding a layered metal organic framework bulk material into a solvent, carrying out stripping under stirring, then carrying out standing to obtain a supernatant, and centrifuging the supernatant so as to obtain a precipitate, i.e., thetwo-dimensional metal organic framework nanosheet. The method provided by the invention can realize large-scale preparation of the two-dimensional metal organic framework nanosheet, and is convenientand practicable in operation. The two-dimensional metal organic framework nanosheet has a thickness of only 1 to 10 nm. The invention also discloses an application of the two-dimensional metal organicframework nanosheet in electrochemical detection of superoxide ions. Specifically, the two-dimensional metal organic framework nanosheet is made into a dispersion which is then subjected to drip-coating of an electrode, and then the superoxide ions are detected through a cyclic voltammetric method or / and an amperometric method. The two-dimensional metal organic framework provided by the inventionhas excellent electrocatalytic performance to the superoxide ions and is capable of converting the superoxide ions into water.
Owner:ZHEJIANG UNIV

Practical intelligent reminding device for formaldehyde removal

The invention relates to the technical field of devices for formaldehyde removal, and discloses a practical intelligent reminding device for formaldehyde removal. The device includes a casing, whereina mixed liquid is arranged inside a closed box, a transparent glass plate is connected to a position right above the closed box, and a photoresistor is arranged right above the transparent glass plate; and a sodium hydroxide solution is arranged on the left side of the inner part of a filter box, an activated carbon adsorption plate is connected to the interior of the filter box, and a quicklimelayer is connected to the interior of the filter box. After chlorine gas is introduced into a hydrogen peroxide solution, peroxide ions are oxidized into superoxide ions firstly, a further reaction isperformed on formaldehyde and the superoxide ions, and a reaction is performed between formaldehyde and hydroxide ions further; since the superoxide ions are extremely unstable, excess energy is released in the form of photons when excited-state oxygen atoms are turned into ground-state oxygen atoms, and the resistance value of the photoresistor can be changed through the brightness of red light,so that the content of indoor formaldehyde is predicted further, the transfer amount of chlorine gas is controlled accordingly, and waste of materials is avoided.
Owner:温州捷朴环保科技有限公司

Flowing electrolyte fuel cell with improved performance and stability

A flowing electrolyte fuel cell system design (DHCFC-Flow) is provided. The use of a flowing oxygen-saturated electrolyte in a fuel cell offers a significant enhancement in the cell performance characteristics. The mass transfer and reaction kinetics of the superoxide / peroxide / oxide ion (mobile oxygen ion species) in the fuel cell are enhanced by recirculating an oxidizing gas-saturated electrolyte. Recirculating oxygen-saturated electrolyte through a liquid channel enhances the maximal current observed in a fuel cell. The use of a oxygen saturated electrolyte ensures that the reaction kinetics of the oxygen reduction reaction are fast and the use of convection ameliorates concentration gradients and the diffusion-limited maximum current density. The superoxide ion is generated in situ by the reduction of the oxygen dissolved in the gaseous electrolyte. Also, a dual porosity membrane allows the uniform flow of fuel (e.g., methane) on the fuel side, without allowing phase mixing. The capillary pressure for liquid intrusion into the gas phase and vice versa is quite large, estimated to be 1-10 psi. This makes it easier to control the fluctuations in gas / liquid velocity which might otherwise lead to phase mixing and the loss of fuel cell performance. In one variation, a dual-porosity membrane structure is incorporated in the system to allow uniform flow of fuel and prevent mixing of fuel with a liquid electrolyte.
Owner:XEROX CORP

Fish meal waste gas purifying and decomposing device

The invention discloses a fish meal waste gas purifying and decomposing device, which belongs to the field of fish meal environmental protection equipment. The device comprises a cover plate, strong oxidization nets, a groove body, ultraviolet lamps, a steel strip and soft magnetic strips, wherein the cover plate is arranged on the upper part of the groove body through a screw hole; the strong oxidization nets are arranged in the groove body at certain intervals; a plurality of ultraviolet lamps are arranged on both sides of the groove body; the steel strip is U-shaped; the surface of the steel strip is coated with zinc or chromium; the edges of the strong oxidization nets are provided with the soft magnetic strips, so that the strong oxidization nets are convenient to detach and clean; the groove body is arranged in a maze form; the strong oxidization nets are made of metal titanium wire nets, and are used for oxidizing titanium into titanium dioxide nanotube arrays in an electrolyte containing fluorine ions at a low-voltage; and the voltage of the low voltage is 20-60V. According to the fish meal waste gas purifying and decomposing device, superoxide ion radicals and hydroxyl radicals with extremely strong oxidizing actions generated by titanium dioxide under the irradiation of ultraviolet light can be used for decomposing organic matters with odor in fish meal waste gas into nontoxic carbon dioxide, water and nontoxic inorganic small molecular minerals, so that the device is simple and practical.
Owner:ZHEJIANG OCEAN UNIV +1

Preparation method of novel mildew-proof environment-friendly coating

The invention provides a preparation method of a novel mildew-proof environment-friendly coating, and mainly solves the problems that a mildew preventive in a traditional mildew-proof coating is easyto decompose, and organic pollutants such as formaldehyde can be released in the using process. The specific implementation method comprises the following steps: carrying out ultrasonic treatment on the compound mildew preventive and an organic additive in the coating for 30-60 minutes in advance; putting talcum powder, nano titanium dioxide and nano zinc oxide powder into a container according tothe mass ratio of 200: 5: 1, conducting ultrasonic dispersion for 30-60 min, and then mixing and stirring the materials, other filler and additives for 15 min so as to obtain the novel mildew-proof environment-friendly coating. The novel mildew-proof coating has broad-spectrum antibacterial and mildewproof effects and can also play a synergistic photocatalysis role under illumination, generates superoxide ions, hydroxyl radicals and other active substances and can adsorb and kill various bacteria and purify indoor VOCs. The formula and the preparation process similar to those of the novel mildew-proof environment-friendly coating are not found yet by consulting related literatures.
Owner:HEILONGJIANG UNIV

Flowing electrolyte fuel cell with improved performance and stability

A flowing electrolyte fuel cell system design (DHCFC-Flow) is provided. The use of a flowing oxygen-saturated electrolyte in a fuel cell offers a significant enhancement in the cell performance characteristics. The mass transfer and reaction kinetics of the superoxide / peroxide / oxide ion (mobile oxygen ion species) in the fuel cell are enhanced by recirculating an oxidizing gas-saturated electrolyte. Recirculating oxygen-saturated electrolyte through a liquid channel enhances the maximal current observed in a fuel cell. The use of a oxygen saturated electrolyte ensures that the reaction kinetics of the oxygen reduction reaction are fast and the use of convection ameliorates concentration gradients and the diffusion-limited maximum current density. The superoxide ion is generated in situ by the reduction of the oxygen dissolved in the gaseous electrolyte. Also, a dual porosity membrane allows the uniform flow of fuel (e.g., methane) on the fuel side, without allowing phase mixing. The capillary pressure for liquid intrusion into the gas phase and vice versa is quite large, estimated to be 1-10 psi. This makes it easier to control the fluctuations in gas / liquid velocity which might otherwise lead to phase mixing and the loss of fuel cell performance. In one variation, a dual-porosity membrane structure is incorporated in the system to allow uniform flow of fuel and prevent mixing of fuel with a liquid electrolyte.
Owner:XEROX CORP

Application of graphene-based nano composite material in remediation of petroleum hydrocarbon contaminated soil

The invention belongs to the technical field of petroleum hydrocarbon contaminated soil remediation, and particularly relates to an application of a graphene-based nano composite material in remediation of petroleum hydrocarbon contaminated soil, wherein the application comprises the following steps: S1, preparing the graphene-based nano composite material: adding graphite powder and sodium nitrate into concentrated sulfuric acid, uniformly mixing, stirring for 10-15 minutes in an ice bath state, and keeping the temperature at 5 DEG C or below; and adding potassium permanganate into the solution. By arrangement of the graphene-based nano composite material, the graphene-based nano composite material contains titanium dioxide, radiation energy of ultraviolet light with the wavelength lower than 387 nm is absorbed through the titanium dioxide, and high-activity electrons and electron-holes are generated; meanwhile, dissolved oxygen, hydroxyl radicals, organic pollutants, water molecules and the like in soil can be adsorbed by utilizing the huge specific surface area of the material, so that a series of chemical reactions are carried out on the surface of the material, and finally, the organic pollutants are degraded to generate hydroxyl free radicals and superoxide ions.
Owner:中骏生态环境(上海)有限公司

Device and method for detecting concentration of trace superoxide ion free radicals in water by adopting chemiluminescence reagent

The invention relates to a device and a method for detecting the concentration of trace superoxide ion free radicals in water by adopting a chemiluminescence reagent. The device comprises a to-be-detected water body container bottle, a chemiluminescence reagent container bottle, a peristaltic pump, a spiral luminescent tube, a photon counter, a computer and a waste liquid bottle. And the to-be-detected water body container bottle and the chemiluminescence reagent container bottle are respectively communicated with the liquid inlet end of the spiral luminescent tube through the peristaltic pump. The photon counter is arranged on one side of the spiral light-emitting tube and used for recording light signals in the spiral light-emitting tube. The photon counter is connected with the computer. The waste liquid bottle is connected with the liquid outlet end of the spiral luminous tube. And a chemiluminescence reagent solution is contained in the chemiluminescence reagent container bottle.According to the method, a chemiluminescence reagent reacts with a to-be-detected water body solution containing superoxide ions to generate an optical signal, and primary attenuation fitting is carried out according to the dynamic track of the optical signal to deduce the concentration of the superoxide ions in the to-be-detected water body.
Owner:ANHUI ELECTRIC POWER DESIGN INST CEEC

Spherical particles containing TiO2 purification factors

The invention relates to the technical field of chemical engineering, and discloses spherical particles containing TiO2 purification factors. The spherical particles comprise the following raw materials in parts by weight: 100-200 parts of titanium sulfate, 50-100 parts of a reaction solvent, 10-20 parts of a surfactant, 20-30 parts of sulfuric acid and 40-60 parts of urea. The spherical particlescontaining the TiO2 purification factors are uniform in particle size distribution, are free of agglomeration or large particles, and have good dispersibility. When the TiO2-containing purification factors are illuminated in an application process, hydroxyl free radicals and superoxide ion free radicals generated on the surface have very strong oxidizing capacity. Reaction energy of the hydroxylfree radicals is 402.8 MJ/mol, and bonds such as C-C, C-H, C-N, C-O, N-H and the like in organic matter can be sufficiently destroyed, so that organic pollutants are completely oxidized into carbon dioxide and water under the action of hydroxyl free radicals and superoxide ion free radicals, main indoor pollutants such as hydrocarbons, benzene, formaldehyde, sulfides, ammonia and the like can be effectively removed, and the formaldehyde removal effect is excellent.
Owner:河南嘉利美环保材料有限公司
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