The invention discloses a process for producing qualified
arsenic oxide from an
arsenic-containing material by a full-wet method. The process comprises the following steps that pressurizing, heating,oxidizing and leaching are carried out on the
arsenic-containing material, a mixture of
arsenic sulfide and an
adhesive is added into arsenic-containing low-acid leached ore pulp for purifying,
solid-liquid separation is carried out, an adsorbent and a
calcium remover are added into the solution, cooling is carried out to normal temperature, standing and aging are carried out for 24-48 hours, andprecisely filtering is carried out; and
sulfur dioxide is introduced into purified liquid, arsenic
pentoxide is reduced and crystallized to obtain
arsenic trioxide, and
air drying and
dehydration arecarried out to obtain qualified analytically pure
arsenic trioxide products. The process has compact flow and full-wet method closed cycle operation, and has the advantages of work environment friendliness, safety and the like, the qualified
arsenic trioxide products are produced at a time, the problem of arsenic open circuit is solved, productization of arsenic is achieved, the
product value is greatly improved, and the process has good advantages in arsenic-containing material treatment and
recovery.