The invention discloses a process for producing qualified 
arsenic oxide from an 
arsenic-containing material by a full-wet method. The process comprises the following steps that pressurizing, heating,oxidizing and leaching are carried out on the 
arsenic-containing material, a mixture of 
arsenic sulfide and an 
adhesive is added into arsenic-containing low-acid leached ore pulp for purifying, 
solid-liquid separation is carried out, an adsorbent and a 
calcium remover are added into the solution, cooling is carried out to normal temperature, standing and aging are carried out for 24-48 hours, andprecisely filtering is carried out; and 
sulfur dioxide is introduced into purified liquid, arsenic 
pentoxide is reduced and crystallized to obtain 
arsenic trioxide, and 
air drying and 
dehydration arecarried out to obtain qualified analytically pure 
arsenic trioxide products. The process has compact flow and full-wet method closed cycle operation, and has the advantages of work environment friendliness, safety and the like, the qualified 
arsenic trioxide products are produced at a time, the problem of arsenic open circuit is solved, productization of arsenic is achieved, the 
product value is greatly improved, and the process has good advantages in arsenic-containing material treatment and 
recovery.