The invention relates to a grinding medium applied to the powder body engineering in industries, such as construction materials, cement and the like, in particular to a production process method of ahigh-carbon multi-element alloy casting grinding ball. The casting grinding ball comprises the following chemical components by weight percent: 1.4-2.5% of carbon, 0.75-0.82% of silicon, 0.46-0.9% ofmanganese, 4.5-6.0% of chromium, 0.04-0.06% of phosphorus, 0.04-0.054% of sulfur, 0.04-0.06% of copper, 0.03-0.04% of molybdenum, 0.02-0.03% of nickel, 0.02% of tungsten, 0.13-0.15% of compound heavyrare earth modificator and 90.4-91.4% of iron. The production operation comprises steps of smelting, casting, heat treatment, mechanical property detection and pouring inspection, wherein heat treatment quenching is oil quenching treatment. The improvements are that: (A) austenitizing treatment is carried out before quenching; and (B) the temperature of quenching oil is 80-140 DEG C, and the quenching time is 6-20 minutes. The formula of the invention is adopted to thin the crystal grains of a grinding ball, the tissues are compact, and the toughness is enhanced; by adopting the technology ofthe invention, the hardness of a high-chromium grinding ball reaches HRc62-64, and the toughness and the wear resistance of the grinding ball are obviously enhanced. On the precondition of further enhancing the properties of wear resistance and crushing resistance of the grinding ball, the content of the noble metal of chromium is reduced, and the manufacturing cost of the grinding ball is also lowered.