The invention discloses a (ZrM)-(CuN)-Ni-Al-(Re) amorphous alloy which comprises the following components in percentage by atom: 40-65% of Zr, 18-46% of Cu, 2-15% of Ni, 4-15% of Al, 0.1-3% of M(Hf, Ti or Hf+Ti), 0.05-3% of N (Ag) and 0.1-2% of rare-earth element RE (Y, Gd, Sc, Er or composition thereof). By adding small amounts of M, N and RE elements on the basis of the Zr-Al-Ni-Cu amorphous alloy, the alloy has the advantages of higher amorphous formation capacity, excellent manufacturability and favorable mold resistance, maintains the excellent mechanical properties of the Zr-Al-Ni-Cu amorphous alloy, and is an ideal material for preparing complex thin-wall parts in the fields of consumer electronics, medical care, automobiles and the like.