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38results about How to "Improve extraction rate" patented technology

Fully closed system for regenerating alkaline etching liquid and recovering copper in PCB

The invention relates to a technology for regenerating alkaline etching waste liquid and recovering copper in a PCB. Along with the etching process, the concentration of copper ions in the etching liquid is increased until the etching liquid can not be used and becomes waste liquid. The technology adopts the following four fully closed cycles which are mutually nested: an etching liquid cycle, anextracting agent cycle, a stripping agent cycle and an ammonia gas cycle; and four main materials interact but are recycled continuously. The technical method comprises the following steps: using an extracting agent to extract partial copper from the etching waste liquid; after gravity separation, air flotation separation and fiber degreasing, controlling and adjusting the concentration of copperions to achieve the level of fresh etching liquid through the specific gravity; using a water injector to add liquid ammonia, and using pH to automatically control and adjust the ammonia concentration; and after adjusting other components, recycling for production. The extracting agent containing copper is processed by back extraction by using sulfuric acid, the extracting agent returns to the extracting section for being reused after separation, and the copper sulfate is electrolyzed into copper to be sold. The whole line recycles various resources to achieve the purposes of waste utilizationand resource recovery, and no wastes are discharged.
Owner:涂方祥

Method of separating and recovering zinc from electroplating sludge

The invention belongs to the field of metallurgy and particularly relates to a method of separating and recovering zinc from electroplating sludge, comprising the steps of 1, performing leaching treatment: leaching the electroplating sludge with an organic acid, and carrying out solid-liquid separation to obtain leaching residue and leachate; 2, removing iron and chromium by neutralizing: adding a neutralizing agent into the leachate obtained in step 1, and carrying out solid-liquid separation to obtain ferric hydroxide precipitate, chromic hydroxide precipitate and leachate; 3, performing extracting: mixing P204, tributyl phosphate, an organic extracting agent N1923 and a solvent oil to obtain a mixed extracting agent, extracting the leachate generated in step 2, with the mixed extracting agent, and adding an organic acid to carry out re-extraction to obtain raffinate and zinc-containing re-extracted liquor, namely purified liquor containing zinc sulfate. The method has the advantages that the zinc may be extracted and separated from sulfuric acid leachate of the electroplating sludge so that the zinc is comprehensively recycled, an extracting process needs no caustic soda liquid for saponification, recycling cost is decreased, and economic benefit is increased.
Owner:广西银亿再生资源有限公司 +1

Suspension point contact type supercritical extraction device

The invention discloses a suspension point contact type supercritical extraction device. The invention belongs to the technical field of supercritical extraction. A hanging basket static extraction mode in a traditional extraction kettle can be abandoned; the deformation characteristic of an empty throwing material receiving film is utilized; contained materials are shaken and thrown in the air; apowdery material is promoted to keep a dispersed suspended state; then, supercritical fluid sequentially passes through a limited space to be in full contact with the materials; the extraction rate of effective substances is obviously improved; through the characteristics of the empty throwing material receiving film and the assisting action of an assisting hanging piece, on one hand, the material dispersion effect is improved, meanwhile, the posture can be changed by overturning, the material is in contact with the supercritical fluid, the materials are fully extracted, and extraction dead corners are not prone to occurring; on the other hand, the situation that the extraction effect is affected due to the static adhesion phenomenon of the powdery materials can be avoided; the one-way extraction rate of the materials can be greatly increased, and the extraction efficiency is greatly improved.
Owner:NANTONG HUAAN SUPER CRITICAL EXTRACTION

Supercritical water/supercritical carbon dioxide combined treatment method for arsenic-contaminated soil

The invention relates to a supercritical water/supercritical carbon dioxide combined treatment method for arsenic-contaminated soil, and belongs to the technical field of soil remediation. The supercritical water/supercritical carbon dioxide combined treatment method comprises: placing arsenic-contaminated soil in a high-temperature and high-pressure reaction kettle I, adding a metal binder, introducing carbon dioxide gas, carrying out heating pressurizing to achieve the supercritical state of the carbon dioxide, and carrying out contact extraction for 15-120 min to obtain repaired soil and the extracted product, wherein the temperature of the carbon dioxide in the supercritical state is 40-80 DEGC, and the pressure is 10-45 MPa; and adding the extracted product, water and an excess oxidant to a high-temperature and high-pressure reaction kettle II, uniformly mixing to obtain a reaction system, carrying out heating pressurizing on the reaction system in the high-temperature and high-pressure reaction kettle II under a closed condition until the reaction system achieves a water supercritical state, and carrying out a reaction for 5-45 min to obtain the reaction product system, wherein the temperature of the supercritical state is 380-650 DEGC, and the pressure is 23-55 MPa. According to the present invention, arsenic is gently extracted by supercritical carbon dioxide so as to repair contaminated soil while recover the arsenic in the form of arsenic trioxide.
Owner:KUNMING UNIV OF SCI & TECH

Interlayer conical cover dispersing component and method for dispersing liquid phase

ActiveCN108245929AAct as a liquid sealWith adjustable operation flexibilityLiquid solutions solvent extractionIsosceles trapezoidEngineering
The invention discloses an interlayer conical cover dispersing component and a method for dispersing liquid phase. The dispersing component comprises an outer-layer conical cover and an inner-layer conical cover which have the same center shaft; an interlayer gap is formed between the conical cover and the conical pipe; the lower end of the gap is connected by a horizontal ring-shaped bottom plateand is sealed; the vertical section of the outer-layer conical cover is shaped like an isosceles triangle or an isosceles trapezoid; multiple rows of sieve pores are formed in the side wall of the outer-layer conical cover along different height, and the outer-layer conical cover has a fan-shaped sieve plate structure when being unfolded; the upper end and the lower end of the inner-layer conicalpipe are open to form liquid flow hole channels, and the height of the inner-layer conical pipe is less than that of the outer-layer conical cover; when the vertical section of the outer-layer conical cover is shaped like the isosceles trapezoid, the outer part of outer-layer conical cover is closed by a round top plate; and at least one sieve pore is formed in the round top plate. The interlayerconical cover dispersing component has the advantages of high operation flexibility, high mass transfer efficiency, stable and reliable extraction process and the like.
Owner:ZHEJIANG UNIV

Gas chromatography sample thermal desorption and automatic sample injection device

The invention discloses a gas chromatography sample thermal desorption and automatic sample injection device. The device comprises a miniature high-temperature heater, a sample tube, a nitrogen supply device, a heat insulation tube, an injection needle a and an injection needle b, wherein the sample tube is arranged in the miniature high-temperature heater, the nitrogen supply device is connected with the miniature high-temperature heater and communicated with the sample tube, the injection needle a and the injection needle b are connected to the two ends of the heat insulation tube respectively, and the injection needle a is inserted in the sample tube with the upper end opening closed. The device is a gas chromatography sample pretreatment device integrating extraction, purification and separation, it is not needed to modify matched gas chromatography at all, a sample obtained after thermal desorption is directly pressed into a vaporizing chamber, and thus chromatography sample injection analysis is performed. The device is easy and convenient to operate, high in extraction rate, good in reproducibility, small in sample use quantity, high in thermal desorption and sample injection speed, high in separation efficiency and suitable for analysis of high-boiling-point ingredients of trace solids and liquid samples.
Owner:YANBIAN UNIV

Separating and recycling method for thallium in nickel-cobalt sulfate solution

The invention provides a separating and recycling method for thallium in a nickel-cobalt sulfate solution. The separating and recycling method includes the following steps that a), the nickel-cobalt sulfate solution, a pH adjusting agent and an oxidizing agent are mixed for carrying out an oxidation reaction, and a reaction mixed solution is obtained; b), the reaction mixed solution obtained in the step a) and chlorate salt are mixed, then an extracting solvent is adopted for quenching, and after two phases are separated, an organic phase including thallium and raffinate are obtained, whereinthe extracting solvent is composed of tertiary amine, tributyl phosphate and sulfonated kerosene; and c), ammonia water is adopted for the organic phase including thallium for back extraction, and after the two phases are separated, thallium-containing back extracting liquid and a lean organic phase are obtained. Compared with the prior art, the extracting solvent containing tertiary amine is adopted in a breakthrough manner for extracting thallium under a sulfuric acid system, the thallium extracting rate is increased by controlling a specific technology, and therefore thallium can be thoroughly separated. In addition, by means of the separating and recycling method, pollution is avoided, the cost is low, and great economic benefits are achieved for comprehensive recycling of thallium.
Owner:清远先导材料有限公司

Conical extraction element with double flow channels and flow-through extraction method

The invention discloses a conical extraction element with double flow channels and a flow-through extraction method. The extraction element consists of three parts including an upper-layer conical cover plate, a middle-layer conical baffle plate and a lower-layer conical flow guiding plate having the same central axis, a vertically-arranged round connection pipe and a horizontally-arranged annularsupport plate, wherein an annular gap flow channel is formed between the cover plate and the baffle plate; the bottom part of the flow channel, close to the upper side wall of the round connection pipe, is sealed; a dispersion phase fluid flows through the flow channel and then penetrates through distribution holes formed in the cover plate and then undergoes contact mass transfer with an external continuous phase; an annular gap flow channel is also formed between the baffle plate and the flow guiding plate; flow limiting holes formed in a part where the bottom part of the flow channel is close to lower side walls of the round connection pipe are communicated with the outside of the extraction element; the outer continuous phase fluid penetrates through the flow limiting holes, then flows through the flow channel and enters into the extraction element. The conical extraction element with the double flow channels disclosed by the invention has the advantages of wide operation elasticity, high space utilization ratio, large mass transfer velocity and the like.
Owner:ZHEJIANG UNIV

Method for extracting copper ions through ultrasonic wave channelization

The invention relates to a method for extracting copper ions through ultrasonic wave channelization, and belongs to the technical field of hydrometallurgy. Feed liquid containing the copper ions and the organic phase of an extraction agent are pumped into extraction pipelines of extraction pipeline reactors for obtaining the loaded organic phase, and the extraction pipeline reactors are connected in series for carrying out multi-stage counter current extraction in the extraction process; after extraction is completed, the obtained loaded organic phase and a back extraction solution are pumped into the extraction pipelines of the extraction pipeline reactors for obtaining copper-bearing pregnant solutions through back extraction, and the extraction pipeline reactors are connected in series for carrying out multi-stage counter current back extraction in the back extraction process. According to the method, the feed liquid and the organic phase have the advantages that the contact area is large in a small pipeline and the mass transfer velocity is high, the strong cavitation effect, the mechanical vibration effect and the disturbance effect of ultrasonic waves are fully utilized, and therefore the mass transfer efficiency is improved, the extraction time and the back extraction time are shortened, the production cost is lowered, and the safety of the extraction process is improved.
Owner:KUNMING UNIV OF SCI & TECH

Extraction method and extraction agent for denitration procedure in H acid production process

The invention relates to an extraction method and an extraction agent for a denitration procedure in an H acid production process, and belongs to the technical field of the organic chemical industry.The extraction method comprises the following steps: firstly, preparing the extraction agent which comprises a solvent, a diluting agent and a co-solvent, wherein the co-solvent is 2-ethylhexylphosphoric acid mono-2-ethylhexyl ester, the solvent is a tertiary amine type solvent, and the diluting agent is one or more of sulfonated kerosene, benzene and toluene; then, extracting denitration substances by adopting the extraction agent, and forming a complexation layer and an inorganic acid aqueous layer after extracting; and applying the inorganic acid aqueous layer to an H acid segregation procedure, performing back extraction on the complexation layer, adding a back extraction agent until the pH of an organic aqueous phase formed by back extraction is 7-9, forming trisodium salt from the denitration substances, standing the trisodium salt to be layered to obtain an organic layer, and applying a solvent layer. The extraction agent does not react with the denitration substances, so that the complexation effect is good, the layering is easy, and the loss of the extraction agent is greatly reduced; and by applying the extraction method and the extraction agent to H acid production, generation of a large amount of wastewater is avoided, a large amount of ammonia is saved, and thus the production cost is lowered.
Owner:湖北丽康源化工有限公司

Microcapsule slow-release pungent litse fruit essential oil capable of being applied to fresh keeping of meat products

The invention relates to a method for extracting microcapsule slow-release pungent litse fruit essential oil capable of being applied to fresh keeping of meat products. The crushing particle size of dried pungent litse fruits is 40 meshes, the one-time feeding amount is 800 g, and the optimal technological parameters of supercritical CO2 extraction are as follows: the extraction pressure is 26 MPa, the extraction temperature is 46 DEG C, the extraction time is 148 min, and the extraction yield of the essential oil is up to 38.65%. Through analysis of physical and chemical indexes of the essential oil, it is found that the color L* value is 41.10, the a* value is 16.17, the b* value is 21.43, the relative density is 0.924, the saponification value is 195.29 mgKOH/g, the refractive index is 1.473, the peroxide value is 0.14 g/100 g, the acid value is 2.31 mgKOH/g, and all the indexes meet the requirements of the national standard. The optimal technological parameters for embedding the pungent litse fruit essential oil microcapsule are as follows: the ratio of a composite wall material is 1:1 (g/g), the ratio of a core material to a wall material is 1:5 (g/g), the solid content is 15%, the content of an emulsifier is 3%, the ratio of an emulsifier is 1:4 (g/g), the emulsification temperature is 40-50 DEG C, and the embedding rate of the pungent litse fruit essential oil microcapsule prepared under the conditions can reach 84.68%. The water content, the solubility and the bulk density are 3.05%, 91.04% and 0.35 g/cm<3> respectively.
Owner:云南省农业科学院农产品加工研究所 +1
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