The invention relates to high voltage resistant and high temperature resistant safety type electrolyte for a lithium ion battery adopting a manganese material as an anode, and a use thereof, specifically to high voltage resistant and high temperature resistant safety type electrolyte for a lithium ion battery adopting a manganese material as an anode. The electrolyte comprises a non-aqueous organic solvent, a lithium salt, a film forming additive and a stabilizing additive. The electrolyte further comprises: a high voltage resistant and high temperature resistant additive, wherein the high voltage resistant and high temperature resistant additive comprises one selected from Li2B12F12-XHX ( the X is an integer more than or equal to zero and less than or equal to 11), Li2B12Cl12-XHX (the X is an integer more than or equal to zero and less than or equal to 11), or a mixture formed through mixing the Li2B12F12-XHX and the Li2B12Cl12-XHX according to any ratio, the use amount of the high voltage resistant and high temperature resistant additive is 1-15% of the total mass of the electrolyte; a high voltage resistant overcharge-proof additive, wherein the high voltage resistant overcharge-proof additive comprises fluorinated anisole, fluorinated diphenyl sulfide or a mixture formed through mixing the fluorinated anisole and the fluorinated diphenyl sulfide according to any ratio, the use amount of the high voltage resistant overcharge-proof additive is 1-10% of the total mass of the electrolyte. With the present invention, the lithium ion battery adopting the manganese material has performances of high temperature resistance, safety and high voltage resistance, the charging voltage of the manganese material can be increased to more than 4.5 V.