The invention relates to 
high voltage resistant and high temperature resistant safety type 
electrolyte for a 
lithium ion battery adopting a 
manganese material as an 
anode, and a use thereof, specifically to 
high voltage resistant and high temperature resistant safety type 
electrolyte for a 
lithium ion battery adopting a 
manganese material as an 
anode. The 
electrolyte comprises a non-aqueous 
organic solvent, a 
lithium salt, a film forming additive and a stabilizing additive. The electrolyte further comprises: a 
high voltage resistant and high temperature resistant additive, wherein the high 
voltage resistant and high temperature resistant additive comprises one selected from Li2B12F12-XHX ( the X is an integer more than or equal to zero and less than or equal to 11), Li2B12Cl12-XHX (the X is an integer more than or equal to zero and less than or equal to 11), or a mixture formed through mixing the Li2B12F12-XHX and the Li2B12Cl12-XHX according to any ratio, the use amount of the high 
voltage resistant and high temperature resistant additive is 1-15% of the total 
mass of the electrolyte; a high 
voltage resistant 
overcharge-proof additive, wherein the high voltage resistant 
overcharge-proof additive comprises fluorinated 
anisole, fluorinated 
diphenyl sulfide or a mixture formed through mixing the fluorinated 
anisole and the fluorinated 
diphenyl sulfide according to any ratio, the use amount of the high voltage resistant 
overcharge-proof additive is 1-10% of the total 
mass of the electrolyte. With the present invention, the 
lithium ion battery adopting the 
manganese material has performances of high 
temperature resistance, safety and high voltage resistance, the charging voltage of the manganese material can be increased to more than 4.5 V.