The invention relates to
high voltage resistant and high temperature resistant safety type
electrolyte for a
lithium ion battery adopting a
manganese material as an
anode, and a use thereof, specifically to
high voltage resistant and high temperature resistant safety type
electrolyte for a
lithium ion battery adopting a
manganese material as an
anode. The
electrolyte comprises a non-aqueous
organic solvent, a
lithium salt, a film forming additive and a stabilizing additive. The electrolyte further comprises: a
high voltage resistant and high temperature resistant additive, wherein the high
voltage resistant and high temperature resistant additive comprises one selected from Li2B12F12-XHX ( the X is an integer more than or equal to zero and less than or equal to 11), Li2B12Cl12-XHX (the X is an integer more than or equal to zero and less than or equal to 11), or a mixture formed through mixing the Li2B12F12-XHX and the Li2B12Cl12-XHX according to any ratio, the use amount of the high
voltage resistant and high temperature resistant additive is 1-15% of the total
mass of the electrolyte; a high
voltage resistant
overcharge-proof additive, wherein the high voltage resistant
overcharge-proof additive comprises fluorinated
anisole, fluorinated
diphenyl sulfide or a mixture formed through mixing the fluorinated
anisole and the fluorinated
diphenyl sulfide according to any ratio, the use amount of the high voltage resistant
overcharge-proof additive is 1-10% of the total
mass of the electrolyte. With the present invention, the
lithium ion battery adopting the
manganese material has performances of high
temperature resistance, safety and high voltage resistance, the charging voltage of the manganese material can be increased to more than 4.5 V.