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34results about How to "Reduce the content of heavy metal elements" patented technology

Preparation and application of special compound premix for fermented feed

The invention discloses a special compound premix for a fermented feed. The special compound premix is prepared from the following main components by weight percentage: 2-2.5 percent of fermented culture, 8-10 percent of enzyme preparation, 30-37.5 percent of fermentation promoter and 50-60 percent of feature pack aiming at different animals (piglets, middle and big pigs, sows, laying hens, dairy cows and fattening sheep). When the fermented feed is used in a large scale for a long time in daily ration of animals, the fermented feed is matched with the special compound premix to use, so that the normal supply of amino acids, vitamins and microelements for animal bodes can be ensured. Moreover, the premix does not contain hormones, antibacterial agents, antioxidants and flavoring agents, and the copper and zinc contents are lower than the national standard. The special compound premix has important meanings for providing safe meat, egg and milk foods, avoiding environmental pollution, realizing green no-antibiotic and hormone breeding, and ensuring the healthy and sustainable development of animal husbandry and aquaculture.
Owner:张列飞 +1

Soil improvement agent and processing method thereof

The invention relates to a soil improvement agent and a processing method thereof. The soil improvement agent comprises the following raw materials in parts by weight: 60-95 parts of desulfurized waste, 0.5-2.0 parts of inorganic accelerator, and 0.5-30 parts of organic accelerator. The soil improvement agent provided by the invention has the beneficial effects that calcium ions in the desulfurized waste are used to replace exchangeable sodium on the soil colloid, thus reducing the alkalization degree of the soil; at the same time, the excellent pore structure and physical property of the organic accelerator are used to improve the physical property of the soil and the granular structure of the soil, reduce the pH value of the soil, and improve the soil fertility; the inorganic accelerator can also improve the granular structure of the soil; in addition, with auxiliary inorganic fertilizer and organic fertilizer, the soil fertility of the soil can be further improved so as to provide nutrient contents for plant growth. To sum up, by adopting the scheme in the invention, unbalance of nutritive elements in the soil can be effectively overcome, the land capability is improved, the soil is loosened, and the fertilizer efficiency is increased, so that the soil salinization phenomenon is fundamentally harnessed step by step.
Owner:TSINGHUA UNIV

Conditioner for severely alkaline soil and processing method of conditioner

The invention relates to a conditioner for severely alkaline soil and a processing method of the conditioner. The conditioner for the severely alkaline soil comprises the following raw materials in parts by weight: 88-92 parts of desulfuration waste, 1-3 parts of inorganic accelerator and 5-11 parts of organic accelerator. According to the conditioner for the severely alkaline soil, calcium ions in the desulfuration waste are used for replacing exchangeable sodium on a soil colloid, so that the alkalisation degree of the soil is reduced; an excellent pore structure and physical properties of the organic accelerator are used for improving physical characteristics and a granular structure of the soil; the pH value of the soil is decreased; the soil fertility is increased; the inorganic accelerator also can improve the granular structure of the soil; an inorganic fertilizer and an organic fertilizer are additionally adopted to further increase the soil fertility; and nutritional ingredients are provided for crop growth. In a word, the conditioner can effectively overcome nutritional element unbalance in the soil, increase the soil fertility, loosen the soil, improve the fertilizer efficiency and fundamentality control soil salinization gradually.
Owner:华清农业开发有限公司

Novel rubber activator and preparation method thereof

The invention discloses a novel rubber activator and a preparation method thereof. The rubber activator particularly comprises 20 to 80 percent of aromatic group-containing formic acid type metal salt and 20 to 80 percent of zinc oxide, wherein the aromatic group-containing formic acid type metal salt is mixed with the zinc oxide at normal temperature and the two are stirred for 5 to 15 minutes at the rotation speed of between 2,000 and 3,500rpm. Compared with the prior art, the problems of high zinc content and high heavy metal element content in the zinc oxide can be effectively solved, density is reduced, dispersibility is improved, and the novel rubber activator improves rubber tensile property, broken chain elongation rate and rubber cross-linking effect.
Owner:江苏爱特恩高分子材料有限公司

Application of moderate alkaline soil modifier

The invention relates to an application of a moderate alkaline soil modifier to soil improvement. The moderate alkaline soil modifier comprises, by weight, 80 to 90 parts of desulfation wastes, 3 to 5 parts of inorganic accelerators and 8 to 15 parts of organic accelerators. According to the moderate alkaline soil modifier, calcium ions in the desulfation wastes are utilized to replace exchangeable sodium on soil colloid, so that the alkalinity of the soil is reduced; simultaneously excellent pore structures and physical properties of the organic accelerators are utilized, so that the physical properties and the granular structure of the soil can be improved, the potential of hydrogen (pH) value of the soil can be reduced, and the soil fertility is increased; the granular structure of the soil can be improved as well by the aid of the inorganic accelerators; and the soil fertility can be further improved by the aid of inorganic fertilizers and organic fertilizers, and nutritional ingredients can be provided for crop growth. In a word, the moderate alkaline soil modifier has the advantages that the unbalanced nutrition elements in the soil can be effectively avoided, the soil fertility can be improved, the soil can be loosened, the fertilizer efficiency is increased, and the soil salinization and alkalization can be gradually and radically treated.
Owner:华清农业开发有限公司

Bone meal containing fertilizer and preparation method therefor

The invention relates to a bone meal containing fertilizer and a preparation method therefor, and belongs to the technical field of fertilizer. The bone meal containing fertilizer is prepared from the following raw materials in parts by weight: 8-13 parts of bone meal, 6-10 parts of humic acid, 5-8 parts of distiller's grains, 7-12 parts of cassava residues, 5-10 parts of edible fungus residues, 47-55 parts of livestock manure, 3-5 parts of orange peel, 0.5-1 part of expanded vermiculite, 20-25 parts of crop stalk power, 3-5 parts of potassium chloride and 4-6 parts of superphosphate. The prepared fertilizer has comprehensive nutrients, and has stable and long-lasting fertilizer efficiency. By applying the fertilizer to crops, the crop production cost is reduced; the crops are promoted to mature early; the crop quality and the soil properties are improved; the formation of a soil granular structure is promoted; the soil is enabled to become soft; the soil structure is improved; and the soil fertility is also improved.
Owner:NANNING XIANGGUANGGAN LIVESTOCK PROD CO LTD

Conditioner for moderately alkaline soil and processing method of conditioner

The invention relates to a conditioner for moderately alkaline soil and a processing method of the conditioner. The conditioner for the moderately alkaline soil comprises the following raw materials in parts by weight: 80-90 parts of desulfuration waste, 3-5 parts of inorganic accelerator and 8-15 parts of organic accelerator. According to the conditioner for the moderately alkaline soil, calcium ions in the desulfuration waste are used for replacing exchangeable sodium on a soil colloid, so that the alkalisation degree of the soil is reduced; an excellent pore structure and physical properties of the organic accelerator are used for improving physical characteristics and a granular structure of the soil; the pH value of the soil is decreased; the soil fertility is increased; the inorganic accelerator also can improve the granular structure of the soil; an inorganic fertilizer and an organic fertilizer are additionally adopted to further increase the soil fertility; and nutritional ingredients are provided for crop growth. In a word, the conditioner can effectively overcome nutritional element unbalance in the soil, increase the soil fertility, loosen the soil, improve the fertilizer efficiency and fundamentality control soil salinization gradually.
Owner:TSINGHUA UNIV

Use of mild alkali-affected soil conditioner

The invention relates to use of mild alkali-affected soil conditioner in the aspect of improving soil. The mild alkali-affected soil conditioner comprises the following raw materials, by weight, 70-80 parts of desulfuration waste, 5-10 parts of inorganic accelerator and 10-20 parts of organic accelerator. The mild alkali-affected soil conditioner uses calcium ions in the desulfuration waste to substitute exchangeable sodium so as to reduce alkalization degree of the soil. Simultaneously, by means of a good pore structure and physical performance of the organic accelerator, a physical behavior of the soil and a granular structure of the soil are improved, a pH value of the soil is reduced, and soil fertility is improved. The inorganic accelerator can also improve the granular structure of the soil. The soil fertility can be further improved by combining inorganic fertilizer and organic fertilizer, and nutritious ingredients are provided for crop growth. The mild alkali-affected soil conditioner can effectively overcome the defect of unbalanced nutritious elements in the soil, improves soil fertility, loosens the soil, improves fertilizer efficiency, and enables a soil salinization phenomenon to be avoided fundamentally.
Owner:TSINGHUA UNIV

Special fertilizer for rice

The invention discloses special fertilizer for rice. The special fertilizer for the rice comprises urea, monoammonium phosphate, potassium chloride, compound sodium nitrophenolate, fermented animal manure, turf, silicon fertilizer, zinc fertilizer, attapulgite and decomposed stone powder according to a mass ratio of 250:150:80:0.12:250:120:5:10:100:35. The fertilizer provided by the invention increases content of protein, amino acids, vitamins and medium trace elements such as zinc, calcium and iron, and integrates organic fertilizer and inorganic fertilizer together. By adding trace elements of the silicon fertilizer and zinc fertilizer, the fertilizer is comprehensive in nutrients, reasonable in proportions, and mutually assistant in slow-fast action; and fertilizer efficiency is stable and long. Compared with conventional fertilizer, the fertilizer provided by the invention can increase the yield of the rice by over 8%.
Owner:SUQIAN WOLVBAO ORGANIC AGRI DEV

Low-oxygen dependent X-photodynamic nano photosensitizer as well as preparation method and application thereof

ActiveCN104353076AReduce tissue oxygen dependenceMake up for the defect of low penetration depthEnergy modified materialsPharmaceutical non-active ingredientsChemical reactionCancer cell
The invention relates to a low-oxygen dependent X-photodynamic nano photosensitizer as well as a preparation method and an application thereof. The low-oxygen dependent X-photodynamic nano photosensitizer comprises nano scintillation crystal particles capable of converting a high-energy radiation ray into an ultraviolet light, a silicon dioxide layer cladded on the surface of the nano scintillation crystal, zinc oxide nanoparticles loaded on the outer surface of the silicon dioxide layer, and polyethylene glycol grafted on the surfaces of the zinc oxide nanoparticles. The nano scintillation crystal capable of converting the high-energy radiation ray into the ultraviolet light is taken as a functional kernel; the nano scintillation crystal can emit a characteristic ultraviolet ray when being irradiated by an X ray; and the characteristic ultraviolet ray can be efficiently absorbed by shell ZnO semiconductor quantum dots, so as to generate electron hole pairs. A lot of high-activity hydroxyl radicals (.OH) and superoxide anions (.O2<->) are generated by complicated physical and chemical reaction, so as to damage cancer cells.
Owner:中国科学院上海硅酸盐研究所苏州研究院

Method for removing heavy metals in fly ash

The invention provides a method for removing heavy metals in fly ash. The method comprises the following steps of carrying out magnetic separation on pulverized coal ash to remove iron, then adding adispersing agent, uniformly stirring, dispersing by vibration, carrying out electrostatic separation, and screening to obtain fly ash particles with the particle size of 0.1-20 mu m; and enabling thescreened fly ash particles with the particle size ranging from 0.1 micrometer to 20 micrometers to enter a first classification chamber to be subjected to primary centrifugal separation, settling large particles into a second classification chamber, introducing secondary air into the second classification chamber, floating small particles in the large particles upwards to enter the first classification chamber, and screening out the fly ash particles with the average particle size smaller than 10 micrometers. After the fly ash is sequentially subjected to the steps of iron removal, scattering,electrostatic separation, centrifugal separation and the like, fine particles in the fly ash are completely separated out, and a large number of heavy metal elements are enriched in the fine particles, so that the content of the heavy metal elements in the fly ash can be effectively reduced.
Owner:杭州石炭纪环保科技有限公司

Preparation method and application of extractant for heavy metals in sludge

The invention discloses an extractant for heavy metals in sludge. The extractant comprises the following components by weight: 8-15% of poly aluminum chloride, 0.3-0.6% of polyacrylamide, 1.8-2.4% of ethylenediaminetetraacetic acid, 1-2% of sodium dodecyl sulfate and the balance of solvent distilled water, and the total weight of the components is 100%. The invention also discloses a preparation method of the extractant for the heavy metals in the sludge. The raw material components are dissolved to prepare three solutions, then the three solutions are mixed, and the solution preparation process and mixing process are carried out at a certain temperature and stirring speed. The invention also discloses a sludge treatment method by use of the extractant for the heavy metals in the sludge; the sludge is pre concentrated, then the extractant for the heavy metals in the sludge is added for hardening and tempering, and deep dehydration is performed after a period of time of reaction in a tempering and quenching tank to obtain the sludge with the heavy metals extracted. The sludge treatment method solves the problems that sludge treatment methods in the prior art are long in treatment time when used in heavy metal removal and dehydration of the sludge, high in operation cost, and not good in heavy metal removal efficiency.
Owner:XI'AN POLYTECHNIC UNIVERSITY +1

Interior wall water paint and preparation method thereof

The invention relates to the technical field of interior wall water paint. The invention provides an interior wall water paint and a preparation method thereof. A water-based special emulsion is used,and the inner wall water paint is prepared by matching a coalescing agent, an additive, a pigment filler, water and the like; the obtained interior wall water paint has excellent performances such asscrub resistance, freeze-thaw resistance, high contrast ratio, good water resistance and the like; the comprehensive performance is superior to that of a superior product of GB / T9756-2018 'syntheticresin emulsion coatings for interior wall'; meanwhile, the interior wall water paint provided by the invention has the advantages of ultralow VOC, zero formaldehyde and ultralow heavy metal element content, the content of dichloro-zinc-based isothiazolinone (DCOIT) is less than 50 mg / kg, and the total content of isothiazolinone is less than 400 mg / kg.
Owner:CHENGDU HONRE PAINT MAKING CO LTD

Method for treating sewage containing heavy metals

The invention relates to the field of sewage treatment, and discloses a method for treating sewage containing heavy metals. The method comprises the following steps of: step 1, adjusting the pH value of the sewage to 5.8-8.0; 2, adding L-cysteine, a starch modified high-molecular polymer, ferric salt and cationic polyacrylamide into a product obtained in the step 1, and carrying out a mixed reaction; 3, carrying out solid-liquid separation on the product obtained in the step 2 to obtain solid-phase floc and separated water, concentrating and filter-pressing the solid-phase floc, and returning the obtained concentrated supernatant liquid filter pressing effluent to the step 2; and 4, performing electrocatalytic oxidation treatment on the separated water to obtain discharged water. According to the method, the heavy metal elements in the sewage can be synchronously removed, and the COD value of the sewage is reduced, so that the content of the heavy metal elements in the discharged water reaches the standard, the COD value of the discharged water is reduced to 400 mg / L or below, and the water quality requirement of subsequent biochemical treatment of an enterprise is met.
Owner:CHINA PETROLEUM & CHEM CORP +1

Application of highly alkalized soil improvement agent

The invention relates to an application of a highly alkalized soil improvement agent in improving soil. The highly alkalized soil improvement agent comprises the following raw materials in parts by weight: 88-92 parts of desulfurized waste, 1-3 parts of inorganic accelerator, and 5-11 parts of organic accelerator. The highly alkalized soil improvement agent provided by the invention has the beneficial effects that calcium ions in the desulfurized waste are used to replace exchangeable sodium on the densityalkalized soil colloid, thus reducing the alkalization degree of the densityalkalized soil; at the same time, the excellent pore structure and physical property of the organic accelerator are used to improve the physical property of the soil and the granular structure of the soil, reduce the pH value of the soil, and improve the soil fertility; the inorganic accelerator can also improve the granular structure of the soil; in addition, with auxiliary inorganic fertilizer and organic fertilizer, the soil fertility of the soil can be further improved so as to provide nutrient contents for plant growth. To sum up, by adopting the scheme in the invention, unbalance of nutritive elements in the soil can be effectively overcome, the land capability is improved, the soil is loosened, and the fertilizer efficiency is increased, so that the soil salinization phenomenon is fundamentally harnessed step by step.
Owner:TSINGHUA UNIV

Special rich-molybdenum fertilizer for lilies and preparation method thereof

The invention provides a special rich-molybdenum fertilizer for lilies. A foliage top-dressing leaf spray application mode is used. Nitrogen, phosphorus, potassium and molybdenum elements are prepared into a water solution according to a specific proportion; then, the water solution is sprayed onto the lily leafs in the growth process; the fertilizer passes through leaf cuticle membranes, reaches the skin cell plasma membranes through ectodesmata and enters the plant bodies. After the application of the fertilizer, the content of lead and cadmium in the lily bulbs can be obviously reduced; the lead content is reduced by 0.17 to 2.43 ug / g; the reduction rate is 6.59 to 94.19 percent; the cadmium content is reduced by 0.49 to 1.17 ug / g; the reduction rate is 26.63 to 63.59 percent; the positive effect on effectively controlling the heavy metal element content in the product is achieved. The preparation process is simple; the equipment investment is low; the application and the use are convenient; the fertilizer is suitable for large-scale popularization.
Owner:SOUTHWEST UNIV

Environment-friendly interior wall putty powder and putty paste and preparation method thereof

The invention discloses an environment-friendly interior wall putty powder and putty paste and a preparation method thereof. The putty powder includes the following components in parts by weight: 45-72 parts of talcum powder, 18-30 parts of heavy calcium carbonate, 5-10 parts of calcium-based bentonite, 0.6-1.5 parts of sodium carboxymethyl cellulose, 1-5 parts of polyacrylamide, 0.3-1.7 parts of hydroxyethyl cellulose; 0-20 parts of building gypsum powder, carboxymethyl cellulose 0-0.8 parts, 0-8 parts of α-pregelatinized starch, 0-3 parts of hydroxypropyl methylcellulose, and 0-0.5 parts by weight of sodium dodecylbenzenesulfonate. The preparation method of the putty powder is to mix the above-mentioned components evenly, and then discharge after stirring for 10-15 minutes. Add 0.3 to 0.5 times the weight of the putty powder and water into the putty powder and stir evenly to obtain the putty paste. The putty powder / putty paste of the present invention does not contain or only contains a small amount of formaldehyde, and the content of heavy metal elements is extremely low, which belongs to the green environmental protection product; it has excellent impact resistance, excellent hydrophobicity and water resistance, high elasticity, and good crack resistance performance, storage stability and easy construction.
Owner:SOUTHWEAT UNIV OF SCI & TECH +1

Severe alkalized soil conditioner and processing method thereof

The invention relates to a conditioner for severely alkaline soil and a processing method of the conditioner. The conditioner for the severely alkaline soil comprises the following raw materials in parts by weight: 88-92 parts of desulfuration waste, 1-3 parts of inorganic accelerator and 5-11 parts of organic accelerator. According to the conditioner for the severely alkaline soil, calcium ions in the desulfuration waste are used for replacing exchangeable sodium on a soil colloid, so that the alkalisation degree of the soil is reduced; an excellent pore structure and physical properties of the organic accelerator are used for improving physical characteristics and a granular structure of the soil; the pH value of the soil is decreased; the soil fertility is increased; the inorganic accelerator also can improve the granular structure of the soil; an inorganic fertilizer and an organic fertilizer are additionally adopted to further increase the soil fertility; and nutritional ingredients are provided for crop growth. In a word, the conditioner can effectively overcome nutritional element unbalance in the soil, increase the soil fertility, loosen the soil, improve the fertilizer efficiency and fundamentality control soil salinization gradually.
Owner:华清农业开发有限公司

Active coke-based saline-alkali soil improver and preparation method thereof

PendingCN112876320AImprove fertilityImprove macroporous microporous structureSuperphosphatesExcrement fertilisersAlkali soilGlomus versiforme
The invention belongs to the field of soil improvement, and particularly relates to an active coke-based saline-alkali soil improver and a preparation method thereof. The improver is composed of a porous biological fertilizer and a strain inoculant which are independently packaged, wherein the porous biological fertilizer is obtained by mixing, aging and fermenting an active coke mixture, vinegar residues and chicken manure according to the weight ratio of 1: (0.2-5): (0.2-1); the active coke mixture is obtained by fully mixing active coke screen underflow subjected to homogenization pretreatment and acidification impurity removal with a calcium superphosphate saturated solution and a silicon fertilizer according to the solid weight ratio of 1: (0.5-5): (0.2-1) by utilizing alternating-frequency magnetic coupling ultrasonic grading mechanical stirring; and the strain fungicide is composed of mycorrhizal fungi and a water-retaining agent according to the weight ratio of (0.1-1): (1-5), the mycorrhizal fungi are obtained by compounding glomus mosseae, glomus intraradices and glomus versiforme according to the weight ratio of 1: (0.2-2): (0.5-5) and propagating in local soil, and the inoculated product is a rhizosphere mixture composed of spores, hyphae and mycorrhizal fragments.
Owner:SHANXI UNIV

Treatment method and application of high-COD high-phosphorus heavy metal-containing sewage

The invention relates to the field of sewage treatment, and discloses a treatment method of high-COD high-phosphorus heavy metal-containing sewage, which comprises the following steps: 1, regulating the pH value of the sewage to 5.6-7.6; step 2, adding ferric salt into the sewage obtained in the step 1 to carry out a first mixing reaction, and then adding zeolite modified cationic polyacrylamide to carry out a second mixing reaction; 3, carrying out solid-liquid separation on the mixed solution obtained in the step 2 to obtain solid-phase floc and separated water; concentrating the solid-phase floc, then carrying out filter pressing, and returning the obtained concentrated supernatant and filter-pressed effluent to the step 2; and 4, adsorbing the separated water by an organic titanium adsorbent, and discharging the adsorbed water. According to the method, heavy metals, phosphorus and COD in the sewage can be synchronously removed, so that the contents of the heavy metals, phosphorus and COD in the discharged water reach the standard.
Owner:CHINA PETROLEUM & CHEM CORP +1

Modifier for mildly alkalized soil and processing method thereof

The invention relates to a modifier for mildly alkalized soil and a processing method thereof. The modifier for mildly alkalized soil comprises the following raw materials in parts by weight: 70-80 parts of desulfurized waste, 5-10 parts of inorganic accelerator and 10-20 parts of organic accelerator. According to the modifier for mildly alkalized soil, exchangeable sodium on soil colloid is replaced by calcium ions in the desulfurized waste, thereby reducing the alkalization degree; because of the fine pore structure and physical property of the organic accelerator, the physical behavior of the soil and the crumb structure of the soil are improved, the pH value of the soil is reduced, and the fertility of the soil is increased; the inorganic accelerator can also improve the crumb structure of the soil; and an inorganic fertilizer and an organic fertilizer are added to further increase the fertility of the soil and provide nutrient contents for the growth of plants. In a word, the invention can effectively avoid the nutrient element unbalance in the soil, improve the productivity of the soil, loosen the soil, enhance the fertilizer efficiency and thoroughly control the soil salinization phenomenon step by step.
Owner:TSINGHUA UNIV

A method of dry distillation of oily sludge to prepare biochar

The invention discloses a method for preparing biochar through destructive distillation of oily sludge, and belongs to the technical field of biochar. The method has the advantages that the oily sludge and biomass materials are utilized as raw materials which are subjected to steps such as drying, activating, destructive distillation, hydrochloric acid soaking and modification to prepare the biochar; the prepared biochar has large specific surface area, high porosity, high fixed proportion of heavy metal and low content of polycyclic aromatic hydrocarbon, and can serve as a heavy-metal ion adsorbent and a soil conditioner.
Owner:SCI RES ACADEMY OF GUANGXI ENVIRONMENTAL PROTECTION

Application of moderate alkaline soil modifier

The invention relates to an application of a moderate alkaline soil modifier to soil improvement. The moderate alkaline soil modifier comprises, by weight, 80 to 90 parts of desulfation wastes, 3 to 5 parts of inorganic accelerators and 8 to 15 parts of organic accelerators. According to the moderate alkaline soil modifier, calcium ions in the desulfation wastes are utilized to replace exchangeable sodium on soil colloid, so that the alkalinity of the soil is reduced; simultaneously excellent pore structures and physical properties of the organic accelerators are utilized, so that the physical properties and the granular structure of the soil can be improved, the potential of hydrogen (pH) value of the soil can be reduced, and the soil fertility is increased; the granular structure of the soil can be improved as well by the aid of the inorganic accelerators; and the soil fertility can be further improved by the aid of inorganic fertilizers and organic fertilizers, and nutritional ingredients can be provided for crop growth. In a word, the moderate alkaline soil modifier has the advantages that the unbalanced nutrition elements in the soil can be effectively avoided, the soil fertility can be improved, the soil can be loosened, the fertilizer efficiency is increased, and the soil salinization and alkalization can be gradually and radically treated.
Owner:华清农业开发有限公司

Composite carrier heteropolyacid catalyst and method for synthesizing epoxysuccinic acid by using same

The invention discloses a composite carrier heteropolyacid catalyst and a method for synthesizing epoxysuccinic acid by using the same. The composite carrier heteropolyacid catalyst is composed of heteropolyacid and a carrier; the structural formula of the heteropolyacid is M3PX12O40.nH2O, wherein M is one of lithium, sodium, potassium ions and ammonium ions, X is tungsten and / or molybdenum, n is0-12; the carrier is one of titanium dioxide, silicon dioxide, a TS type titanium silicalite molecular sieve, aluminum oxide and activated carbon. The method for synthesizing epoxysuccinic acid by using the composite carrier heteropolyacid catalyst comprises the following steps of: mixing maleic anhydride, liquid caustic soda and water, stirring the mixture, heating the mixture to 55-60 DEG C; adding the heteropoly acid catalyst, continuously heating to 70 + / -5 DEG C; and dropwise adding a hydrogen peroxide solution, carrying out heat preservation reaction, cooling, and filtering to obtain theepoxysuccinic acid. The catalyst provided by the invention has high catalytic activity and enhanced surface activity after being immobilized and stronger adsorption capacity, improves the catalytic efficiency of epoxidation and the utilization rate of hydrogen peroxide, and is easy to recover; and the content of W and Mo heavy metal elements in the product is greatly reduced.
Owner:SHANDONG TAIHE WATER TREATMENT TECH CO LTD
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