The invention provides a preparation method of CCK release paper. The method comprises the following process steps: respectively subjecting coniferous wood chemical pulp and broadleaf wood chemical pulp to pulping, pulp mixing, auxiliary material adding, wet paper making with pulp, pre-drying, coating in a machine, post-drying, calendaring, finishing and the like so as to obtain the CCK release paper. According to the invention, the raw paper is subjected to in-machine coating treatment, so that the waterproof and oil-proof performance and the high-temperature resistance of the CCK release paper are effectively improved, and the tensile strength, the surface smoothness, the covering property and the heat insulation property of the paper are further improved after the coating. The product prepared by the method provided by the invention has the characteristics of good barrier property, high smoothness, high internal binding force, stable peel strength, environmental friendliness and the like, is directly coated with silicon and does not need to be coated in release processing, has the characteristics of cost reduction and environmental protection, and is a typical product replacing plastic. The invention also provides the CCK release paper.