The invention mainly introduces a method for fast synthesizing high-
crystallinity and high-yield
fluoride-free AlPO4-34 through a mixed
solvent hot process under the condition without
hydrofluoric acid by using common organic amine
morpholine as template agents and mixing isopropanol or
ethylene glycol and water according to certain proportions. In the method, firstly, aluminum sources,
phosphor sources, water, sopropanol or
ethylene glycol and organic template agents are uniformly mixed in a certain sequence according to a certain mol rate that Al2O3 / P2O5 /
morpholine / H2O / R (isopropanol or
ethylene glycol)=1.0 / 0.8 to 1.2 / 2.0 to 8.0 / 12.5 to 75 / 4.0 to 24, the stirring and the
ageing are carried out, the mixture is transferred into a stainless steel reaction kettle for being crystallized for 1 to 6 days at 170 to 200 DEG C at self generated pressure, then, sudden cooling, collection, filtering, washing and natural
drying are carried out, and AlPO4-34
molecular sieve raw
powder is obtained. The method has the advantages that green effect, environment protection and economy are realized, the implementation condition is simple, and wide application prospects are realized.