66 results about "5-Aminotetrazole" patented technology

A CMP composition containing 5-aminotetrazole, e.g., in combination with oxidizing agent, chelating agent, abrasive and solvent. Such CMP composition advantageously is devoid of BTA, and is useful for polishing surfaces of copper elements on semiconductor substrates, without the occurrence of dishing or other adverse planarization deficiencies in the polished copper, even in the presence of substantial levels of copper ions, e.g., Cu<2+>, in the bulk CMP composition at the copper / CMP composition interface during CMP processing.

The present invention is an electrically controlled propellant comprising a binder, an oxidizer, and a cross-linking agent. The boric acid (the cross-linking agent) has been found to function as a cross-linking agent for the high molecular binder used to make the propellant, thereby improving the composition's ability to withstand combustion without melting. The present invention also may include 5-aminotetrazole (5-ATZ) as a stability-enhancing additive. The binder of the present invention may include polyvinylalcohol (PVA) and / or the co-polymer of polyvinylalcohol / polyvinylamine nitrate (PVA / PVAN).

A CMP composition containing 5-aminotetrazole, e.g., in combination with oxidizing agent, chelating agent, abrasive and solvent and a method of use. Such CMP composition may be diluted during the CMP polish to minimize the occurrence of dishing or other adverse planarization deficiencies in the polished copper, even in the presence of substantial levels of copper ions in the CMP composition and at the copper / CMP composition interface during CMP processing.

A fire suppressing gas generator composition which has a low burn temperature which provides an adjustable mass flow rate, which provides high inert gas yields upon combustion, which generates flame suppressing gasses during composition, which provides exhaust gas with low particulate content, and which is suitable for use in pellet form. The gas generator composition of the invention generally comprises a high nitrogen content solid, preferably 5-amino tetrazole, and potassium perchlorate or other oxidizer salt in an amount sufficient to allow flameless deflagration of the high nitrogen contant solid. The composition of the invention also preferably comprises a flame inhibitor precursor such as perbrominated aromatic compound, an elastomeric binder, a powder pressing modifier or enhancer such as mica, and an electrostatic charge suppressant such as graphite.

Ammonium perchlorate-containing gas generant compositions which, upon combustion, produce or result in an improved effluent and related methods for generating an inflation gas for use in an inflatable restraint system are provided. Such ammonium perchlorate-containing gas generant compositions include ammonium perchlorate present with a mean particle size in excess of 100 microns. Such ammonium perchlorate-containing gas generant compositions also include or contain a chlorine scavenger present in an amount effective to result in a gaseous effluent that is substantially free of hydrogen chloride when the gas generant is combusted, wherein at least about 98 weight percent of the chlorine scavenger is a copper-containing compound. Suitable copper-containing chlorine scavenger compounds include basic copper nitrate, cupric oxide, copper diammine dinitrate-ammonium nitrate mixture wherein ammonium nitrate is present in the mixture in a range of about 3 to about 90 weight percent, copper diammine bitetrazole, a copper-nitrate complex resulting from reaction of 5-aminotetrazole with basic copper nitrate and combinations thereof.

A gas generant composition is provided that contains a transitional metal salt of 5-aminotetrazole and phase stabilized ammonium nitrate. A gas generator incorporating the gas generant composition is also provided. The gas generator may be contained within a gas generating system such as an airbag inflator or seat belt assembly, or more broadly within a vehicle occupant protection system.

A gas generator 10 includes a composition that contains a metal chlorate such as potassium chlorate as an oxidizer, a carboxylic acid such as DL-tartaric acid as a primary fuel, a secondary oxidizer such as strontium nitrate, and if desired, a secondary fuel such as 5-aminotetrazole. Gas generating systems 180 such as vehicle occupant protection systems 180, containing the gas generator 10, are also provided.

A method of manufacture of the primary explosive material copper(I) 5-nitrotetazolate (DBX-1) by a synthesis starting with 5-aminotetrazolate (5-AT); wherein, the synthesis provides intermediates acid copper salt of 5-NT and sodium 5-nitrotetrazolate (NaNT) sodium 5-nitrotetrazolate (NaNT)—that are both, free of any 5-aminotetrazolate (5-AT) starting material—such that the subsequent production of the DBX-1 is not inhibited. Further, this method utilizes an internal filter within the reactor—to minimize handling of explosively dangerous intermediates.

The invention discloses a silver-amino tetrazole metal organic framework, a preparation method of the silver-amino tetrazole metal organic framework as well as application of the silver-amino tetrazole metal organic framework in organic dyestuff light degradation. The preparation method comprises the following steps: by utilizing a simple solvent diffusion method, reacting a metal silver salt and an organic amine, thereby preparing a stable metal solution; and enabling the metal solution to react with an organic solution of 5-amino tetrazole, thereby preparing the silver-amino tetrazole metal organic framework with the light degradation performance. The silver-amino tetrazole metal organic framework is simple in preparation process, is high in organic dyestuff photocatalytic degradation efficiency and is a potential light degradation organic pollutant material.

The present invention relates to a gas generator which is a core component of an inflator used for expanding an airbag for alleviating the impact on a passenger occuring during a vehicle collision, and provides the gas generator capable of generating a high combustion rate and a large quantity of gas. The present invention provides a gas generator having a combustion rate of 20 mm / sec or higher, a generated gas amount of 33 moles / kg or higher and a combustion temperature of 2300 K or lower by using: copper diamine dinitrate (CDD) as a principal oxidizing agent; basic copper nitrate (BCN) as an auxiliary oxidizing agent; guanidine nitrate (GN) as a principal fuel; 5-aminotetrazole (5-AT) as a combustion-rate-increasing fuel; metal oxide and a combustible catalyst as catalysts; and an additive. Also, the internal pressure of the inflator manufactured by using the gas generator is reduced to 100 bar, and thus the inflator is manufactured so as to weigh 250g which is a remarkable reduction in comparison with 440g of existing product A and 330g of existing product B.

A novel compound, tris (5-amino tetrazolo) triazine is used for example, as a gas generating fuel. A method of making the compound is also provided. A gas generating composition, containing the novel compound as a fuel, and an oxidizer is also provided. The novel compound may be contained within a gas generant composition 12, within a gas generator 10. The gas generator 10 may be contained within a gas generating system 200 such as an airbag inflator 10 or seat belt assembly 150, or more broadly within a vehicle occupant protection system 180.

The invention provides a chlorine-containing pyrotechnic composition which comprises a binder, an oxidator, a pyrotechnic fuel, and a colourant comprising a metal salt of 5-aminotetrazole. The invention further relates to a firework article comprising such a pyrotechnic composition. In addition, the invention provides a method for preparing said colourant.

Described are methods for preparing salts of 5-nitrotetrazolate by reacting 5-aminotetrazole, an acid, and sodium nitrite in water in a batch reaction at an elevated temperature. As examples, the acid is nitric acid, sulfuric acid, perchloric acid, or hydrochloric acid, and the elevated temperature is at or above 65° C.

The invention relates to a palygorskite clay based multifunctional assistant of macromolecular materials and a preparation method for the palygorskite clay based multifunctional assistant. The methodcomprises the steps: crushing palygorskite clay, adding a couplant, carrying out stirring treatment at normal temperature so as to obtain surface modified palygorskite clay, carrying out drying, and re-crushing the palygorskite clay; then, dispersing the surface modified palygorskite clay into ethyl acetate, sequentially adding a compound 1-propylphosphoric anhydride and a compound 5-aminotetrazole, carrying out ultrasonic treatment, and then, carrying out stirring for a period of time; and finally, carrying out air flow drying, recovering the ethyl acetate solvent, and grinding a dried powderproduct, thereby obtaining the palygorskite clay based multifunctional macromolecular assistant. Shown by experiments, the palygorskite clay based multifunctional assistant prepared by the method hasexcellent comprehensive properties, the thermal stability, cross-linking degree, flame retardance, tensile strength and impact strength of the materials can be comprehensively improved, and the smokedensity and combustion toxicity can be lowered, so that the multifunctional assistant of the macromolecular materials is relatively ideal and has very good prospects in the field modification of macromolecular composite materials.

The invention relates to a method for testing the particle size and the particle size distribution of 5-aminotetrazole, wherein the particle size and the particle size distribution of an organic synthesis intermediate 5-aminotetrazole are tested by a wet laser diffraction method. According to the method, 5-AT particle size test is performed by using a trichloromethane solution containing 0.2-0.4%of sodium dodecylbenzenesulfonate and 0.1-0.2% of ethylphenyl polyethylene glycol as a dispersion system at an ultrasonic dispersion time of 5-10 min. According to the present invention, the relativestandard deviation of the multiple median particle size measurement results is not more than 6%, the precision of the method is good, and the wet laser diffraction method for testing the particle sizeof 5-AT has good applicability and can be used for the test of the particle size of 5-AT so as to be used for the quality control of the product.

The invention discloses a preparation method of zinc 5, 5'-azotetrazole, a green primary explosive. The method comprises: taking 5-aminotetrazole as the starting material, which is oxidized into sodium 5, 5'-azotetrazole by an alkaline oxidation method, then adopting pure water as the base solution, using a metering pump to control the feeding speed of a zinc acetate solution and a sodium 5, 5'-azotetrazole solution, and adding them dropwisely into the base solution for a combination reaction, then carrying out heat preservation, cooling, pumping filtration, washing, dehydration, and drying, thus obtaining a finished product of zinc 5, 5'-azotetrazole. The zinc 5, 5'-azotetrazole of the invention has the advantages of simple and safe synthesis method, low toxicity or no toxicity raw materials, low cost, no black residue after explosive decomposition, and small residue amount, generation of nitrogen as general gas product, no environmental pollution, as well as good explosion performance, thus being a green primary explosive.

A gas generator 10 includes an auto-ignition / booster composition 212 that contains a metal chlorate such as potassium chlorate as an oxidizer, a carboxylic acid such as DL-tartaric acid as a primary fuel, a secondary oxidizer such as strontium nitrate, and if desired, a secondary fuel such as 5-aminotetrazole. The auto-ignition / booster composition 212 and a separate provision of ammonium nitrate or phase stabilized ammonium nitrate 228 are provided within a single combustion / decomposition chamber 222 for the production of gas, upon actuation of the gas generator 10. Vehicle occupant protection systems 180, containing the gas generator 10, are also provided.

The invention discloses a method for preparing green primary explosive Cu(NH3)4ATZ.2H2O. The preparation method comprises that 5-aminotetrazole as an initial raw material is oxidized into sodium 5,5'-azotetrazolate by a basic oxidation method, ammonium hydroxide is added into the sodium 5,5'-azotetrazolate as a base solution at an appropriate temperature, a copper sulphate solution is fast added into the solution, the mixed solution undergoes a combination reaction, the reaction product is subjected to temperature keeping, cooling and suction filtration, and the filter residue is washed by water, then is dehydrated by ethanol and then is dried so that Cu(NH3)4ATZ.2H2O is obtained. The preparation method has simple and safe processes and short synthesis time, adopts low-toxicity or toxicity-less raw materials and has a low cost. After explosion decomposition of Cu(NH3)4ATZ.2H2O, a small amount of black residue is obtained and the gas product mainly comprises nitrogen so that environmental pollution is avoided. Cu(NH3)4ATZ as a dehydrated product of Cu(NH3)4ATZ.2H2O has good explosion performances and is a green primary explosive.

Described are methods for preparing salts of 5-nitrotetrazolate that include reacting aqueous solutions of 5-aminotetrazole, an acid, and sodium nitrite in a continuous flow system at an elevated temperature.

Described are methods for preparing salts of 5-nitrotetrazolate that include reacting aqueous solutions of 5-aminotetrazole, an acid, and sodium nitrite in a continuous flow system at an ambient temperature.

The invention provides a gas generator ignition agent and a preparation method thereof, and a gas generator for a vehicle safety airbag. The gas generator ignition agent contains a fuel, an oxidant, abinder and an additive, wherein the additive is an oxazole-based energy-containing ionic compound. According to the present invention, by adding 5-aminotetrazole nitrate to a boron / potassium nitrateignition agent, on the basis of the ensuring of the combustion heat and the combustion temperature of the agent, the high-temperature and high-pressure gas amount can be increased, the output pressureof the ignition agent can be increased, and the output performance of the ignition pipe can be increased, such that the pressure starting time of the gas generator is advanced to less than 2 ms, andthe pressure value at 10 ms is increased by about 20 Kpa so as to improve the gas generating performance of the gas generator.

The invention discloses an environment-friendly gasoline additive. The gasoline addtive comprises the following components in parts by weight: 40-50 parts of solvent oil, 3-4 parts of 1,3,5,7-tetrakis(4-aminophenyl)adamantane, 1-2 parts of ascorbic acid, 3-5 parts of 5-aminotetrazole, 5-7 parts of an organic nano material, 1-3 parts of graphene, 2-4 parts of glycerol polyoxyethylene ether, 2-4 parts of PPG-1 trideceth-6, 2-5 parts of polyether amine and 1-2 parts of arylamine. The invention also discloses a preparation method of the environment-friendly gasoline additive. The preparation method comprises the following steps: sequentially adding each raw material into a reaction kettle according to a ratio, carrying out reflux condensation and stirring for 3-4 hours, and then carrying out standing for 5-8 hours. Compared with common gasoline or gasoline added with conventional gasoline additives in the prior art, the gasoline added with the gasoline additive disclosed by the invention has lower price and more complete combustion, is more beneficial to improving the lubricity, detergency and corrosion resistance, has a better reinforcing effect on the power of engines, and can effectively prolong the service life of the engine, reduce the exhaust of automobile tail gas, and reduce the pollution to the air and the environment.

The invention provides a preparation method of a temperature-resisting lead-free and barium-free primary explosive 5-nitramino tetrazole calcium. The method comprises the following steps of: mixing nitrosonitric acid and concentrated sulfuric acid by a ratio of 1:1, adding 5-amino tetrazole powder under a stirring condition, heating to 50-70 DEG C to react for 4-6 hours, cooling to room temperature and adding anhydrous Na2CO3 till pH value is neutral; extracting by absolute ethyl alcohol, spirally evaporating a filtrate, adding ethyl acetate to generate a white precipitate, filtering a solid product, and drying at 55-65 DEG C to obtain 5-nitramino tetrazole calcium; adding 5-nitramino tetrazole calcium and distilled water to a reaction bottle, stirring, adding solid powder Ca(OH)2 and heating to 75-85 DEG C to react for 1-2 hours, separating out white crystals, cooling to room temperature, filtering the solid product, washing by absolute ethyl alcohol, and drying at 55-65 DEG C to obtain CaNAT. In the synthesizing process, no toxic and harmful gases are generated, so that the primary explosive has very good thermal stability.

The invention relates to an ignition agent composition with reliable ignition performances and a preparation method thereof. The ignition agent composition comprises, by mass, 40% to 60% of strontiumnitrate, 25% to 40% of 5-aminotetrazole, 1% to 20% of potassium nitrate, 1% to 20% of mica powder, 0.5% to 10% of aluminum oxide, 0.1% to 10% of graphite and 0.1% to 10% of boron nitride. The ignitionagent composition does not stick to a mold in tabletting. The tablet can well retains the original gloss and shape, the phenomenon of ignition delay or large fluctuation of the ignition agent at thelow temperature of 40 DEG C is improved, the impact scope of the ignition agent working at -40 to 90 DEG C is wide, the fire is uniform while the gas generant is ignited, the consistency is good and the ignition performance is significantly improved.

The invention discloses a synthesis method of BNCP (cis-bis-(5-nitrotetrazolato)tetraminecobalt (III) perchlorate) as an initiating explosive. According to the method, NaNT (sodium 5-nitrotetrazolate) and CTCN (cobalt carbonatotetraamine nitrate) are prepared from 5-aminotetrazole and cobalt nitrate as raw materials, and BNCP is synthesized from NaNT and CTCN as raw materials. The yield of BNCP synthesized with the method can reach 60% or higher, and product purity is higher. The raw materials are simple and easily available, a synthesis route is simple, and industrial production is facilitated.

Gas generating compositions having a fuel preferably comprising a mixture of 5-aminotetrazole (5-AT), azodicarbonamide (ADCA), an oxidizer, and a superfine metal powder burn rate enhancer such as nano-aluminum, for use in automotive seatbelt pretensioners and other suitable applications requiring high impetus, high rate of gas generation. Also, methods of making these compositions, and devices incorporating them such as seatbelt pretensioners.

The invention discloses a method for preparing a 5-aminotetrazole compound. The method comprises the following steps: adding bis-substituted selenourea shown in the formula II in the description, ionic liquid loaded iodobenzene diacetate shown in the formula III in the description, sodium azide and alkali A into a solvent B, stirring at -10 to -80 DEG C and conducting cyclization reaction, and after the reaction is finished, conducting aftertreatment on the reaction liquid to prepare the 5-aminotetrazole compound shown in the formula I in the description. Compared with the conventional method, a green reagent, namely, ionic liquid loaded iodobenzene diacetate, is adopted, so that the use of heavy metal is avoided, the operation is simple and convenient, and the reaction yield is high.

The invention discloses a ferrocene high-nitrogen energetic eutectic. The ferrocene high-nitrogen energetic eutectic is an eutectic formed by using N,N-dimethylaminomethylferrocene and an energetic compound, wherein the energetic compound is tetrazole, picric acid, trinitrotoluene or 5-aminotetrazole. The ferrocene high-nitrogen energetic eutectic is synthesized through eutectic formation of the energetic compound and a ferrocene burning rate catalyst N,N-dimethylaminomethylferrocene through using an eutectic technology, so a synthetic method of the eutectic has the advantages of simplicity and low cost; and the synthesized ferrocene high-nitrogen energetic eutectic has the advantages of non-volatility and good heat stability under natural conditions, high formation heat and combustion heat, great reduction of the migration and the volatility of the catalyst, and improvement of the energy level of a propellant during decomposition due to energy containing of the eutectic.

The invention discloses an organic energetic potassium salt and a preparation method thereof, belonging to the technical field of energetic materials. Its molecular structural formula is as follows: it includes the following steps: adding potassium hydroxide to water, then adding 5-aminotetrazole, raising the temperature, adding potassium permanganate, and raising the temperature to boiling after the addition is completed. After the reaction, hot filter, wash the filter cake with hot water, combine the filtrate and washing liquid, concentrate under reduced pressure, and freeze to precipitate crystals to obtain potassium salt of azotetrazole. The potassium azotetrazole synthesized by the invention has a good flame-extinguishing effect and can be used to suppress the muzzle flame of barrel weapons.