The invention relates to a Raman spectrometer, and particularly discloses an optical fiber microprobe of a tip-enhanced Raman spectrometer, which includes a box body and a circuit part, wherein the circuit part is arranged in the box body; a white light imaging optical path, a laser optical path and a signal collecting optical path are arranged on the circuit part; all the white light imaging optical path, the laser optical path and the signal collecting optical path adopt optical fiber conduction; an optical fiber, a first beam splitter, a second beam splitter, a microlens, a lens, a reflector, a camera and a pull rod are arranged on the white light imaging optical path; a laser, a single mode polarization maintaining optical fiber, a optical fiber coupler, a laser-line bandpass filter plate and a 45 DEG edge filter plate are arranged on the laser optical path; and a 0 DEG edge filter plate, optical fiber coupler, a multimode fiber and a spectrometric detector are arranged on the signal collecting optical path. The invention has the advantages that the optical fiber microprobe of the tip-enhanced Raman spectrometer has simple optical path and small volume, can conveniently replace laser wave length and polarization direction, is highly stable, can be combined with any scanning probe microscope, can conveniently switch the excitation mode, and can improve the integral stability and the operation convenience of the TERS instrument.