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50results about How to "High arsenic removal rate" patented technology

Method for recovering copper from copper dust and immobilizing arsenic from copper dust into scorodite

The invention discloses a method for recovering copper from copper dust and immobilizing arsenic from copper dust into scorodite. The method comprises the following steps: subjecting the copper dust to acid leaching under the conditions that a sulfuric acid concentration is 14 to 30 g / L and reaction time is 2 to 3 h so as to obtain acidic leaching liquid; carrying out oxygen-pressure arsenic precipitation on acidic leaching liquid under the conditions that oxygen partial pressure is 0.6 to 1.3 MPa and reaction time is 2 to 3 h so as to obtain scorodite and a post-arsenic-precipitation solution; and adding iron powder into the post-arsenic-precipitation solution and carrying out a reaction for 25 to 40 min so as to displace copper slag and obtain post-displacement liquid. The method provided by the invention carries out oxidative arsenic precipitation at a high temperature, so sulfuric acid in waste acidic leaching liquid is made full use of; a high arsenic removal rate is realized, eventually produced iron arsenate has stable properties, and the post-arsenic-precipitation solution has low arsenic content; and the method has the advantages of high heavy metal recovery rate, low recovery cost, environment-friendly treatment process and small pollution to the environment.
Owner:云南云铜锌业股份有限公司

Method for treating poor-tin middling ore and recovering iron-making raw material

InactiveCN102242253AHigh extraction rateImprove efficiency of arsenic removalMixed materialsMaterials science
The invention provides a method for treating poor-tin middling ore and recovering an iron-making raw material. The method comprises the following steps: adding an alkalinity modifier, a reducing agent and a chlorinating agent in the ore material for mixing so as to form a mixed material, and then pelletizing, wherein the alkalinity modifier is silicon-rich ore or quartziferous ore, the mass ratio of CaO/SiO2 in the mixed material is controlled to not more than 0.65, and the mass percentage of total SiO2 is not more than 10%; carrying out high temperature chloridizing roasting on pelletized aggregate pellets, wherein chloridizing roasting conditions are as follows: the addition amount of the chlorinating agent accounts for 4-8% of that of the aggregate pellets, and the addition amount of the reducing agent accounts for 3-5% of that of the aggregate pellets, and roasting temperature is 950-1100 DEG C; controlling the volume ratio of CO2/CO in the atmosphere to 1.0-3.0 in the roasting process; and carrying out cooling and dust collection on high-temperature smoke generated by chloridizing roasting, and then capturing and recovering valuable metals. By using the method in the invention, tin and other valuable metals are economically and efficiently extracted from the poor-tin middling ore and the iron-making raw material is recovered so as to finally achieve good effects as follows: (1) the extraction rate of the valuable meals in the poor-tin middling ore is improved; (2) the efficiencies of arsenic removal and iron-making material recovery are improved; (3) production capacity of equipment is improved, and energy is saved; and the like.
Owner:CENT SOUTH UNIV

Arsenic-removing device and method for gallium arsenide wafer production and processing waste water

The invention relates to an arsenic-removing device and method for gallium arsenide wafer production and processing waste water and belongs to the technical field of waste water treatment. The arsenic-removing method comprises conveying raw water to a primary arsenic-removing tank, performing sequencing batch flocculation and sedimentation to remove arsenic, and enabling the basic process to comprise water inflow, flocculation, sedimentation and water outflow; enabling treated supernatant to enter a secondary arsenic-removing tank, first performing oxidation reactions, then performing sequencing batch flocculation and sedimentation to remove arsenic, and enabling the basic process to comprise water inflow, oxidation, flocculation, sedimentation and water outflow; first enabling the treated supernatant to flow into an intermediate tank, conveying the supernatant to a sand filter through a three-level lift pump to perform gravity filtration, enabling final outflow water to enter a clean water pond after filtration, and discharging the effluent finally; utilizing a backflushing pump to perform back flush on the sand filter at a fixed period, and taking backflushing water from the clean water pond. The arsenic-removing device and the arsenic-removing method are high in arsenic-removing rate, enable concentration of arsenic in the outflow water to be controlled to be below 0.02mg/L, are easy to operate, run stably, and are suitable for treating the gallium arsenide wafer production and processing waste water and arsenic-containing waste water of related industries.
Owner:BEIJING MUNICIPAL RES INST OF ENVIRONMENT PROTECTION

Method for treating high-arsenic polluted acid by utilizing zinc slag

The invention relates to a method for treating high-arsenic polluted acid by utilizing zinc slag, and belongs to the technical field of heavy metal pollution treatment. The method comprises the following steps: adding hydrogen peroxide into high-arsenic polluted acid, uniformly mixing to obtain a mixed solution A, adding zinc slag powder into the mixed solution A, and regulating the pH value of the system to 1.5-4 to obtain a mixed solution B; introducing air into the mixed solution B under the stirring condition at the temperature of 90-95 DEG C, reacting for 12-24 hours, carrying out solid-liquid separation to obtain an arsenic-containing solid substance and filtrate, drying the arsenic-containing solid substance, stacking, and carrying out deep arsenic removal treatment on the filtrate.According to the method, the zinc slag is used for removing arsenic in the acid and generating a stable arsenic-containing compound, diffusion and harm of arsenic in the environment are reduced, andsecondary pollution is avoided.
Owner:KUNMING UNIV OF SCI & TECH

Method for separating arsenic and recycling copper from arsenious high-copper dross

A method for separating arsenic and recycling copper from arsenious high-copper dross comprises the following steps that (1) pretreatment, wherein the arsenious high-copper dross is screened, fine products and crude products are obtained, and the fine products are ground to be fine; (2) oxygen pressing acid leaching, wherein the fine products obtained in the step 1 are subjected to oxygen pressingacid leaching, and leachate and leaching residues are obtained; (3) oxygen pressing arsenic fixing, wherein siderite is added into the leachate obtained in the step 2 under the condition of oxygen pressure, and arsenic fixing after liquid and arsenic sedimentation residues are obtained; (4), cyclone electrodeposition, wherein the arsenic fixing after liquid is subjected to cyclone electrodeposition, electrodeposition after liquid and black copper residues are obtained, and after the black copper residues are cast through a pyrogenic process, crude copper is obtained. According to the method for separating arsenic and recycling copper from the arsenious high-copper dross, the siderite is used for arsenic removal, the acidity of a solution can be reduced, cost is low, and generation of ferric sulfate can be promoted; the solubility of iron arsenate can be reduced, the arsenic removal rate is high, no hydrogen is generated in the reaction process, and potential safety hazards caused by explosions are eliminated.
Owner:HUNAN SHUI KOU SHAN NONFERROUS METALS GRP

Arsenic removal method in nickel electrolysis mixed acid system

ActiveCN106757147ASolve the problem of excessive arsenic in electrolysisStable chemical qualityElectrolysis componentsPhotography auxillary processesElectrolysisSlag
The invention discloses an arsenic removal method in a nickel electrolysis mixed acid system. According to the method, the iron-arsenic ratio of anodic electrolyte is reasonably controlled through iron supplementation, and meanwhile, the temperature and pH value of an iron removal process are controlled, so that 80% or more of arsenic is separated out in an iron arsenate or adsorption form in the iron removal process; then, in the cobalt removal stage, the cobalt removal oxidation potential, reaction time and pre-cobalt-removal liquor pH value are controlled, and remaining arsenic in iron removal and arsenic removal filtered liquor is removed with cobaltous hydroxide at the cobalt removal stage in a coprecipitation manner. Besides, iron removal and arsenic removal filtered slag generated by purification and cobalt removal and arsenic removal filtered slag are subjected to nickel removal treatment and then filtered, filtered liquor returns to liquor making for treatment, part of arsenic is brought to the liquor making process, and arsenic removal is induced by controlling solution copper ions and electric current density in the liquor making process. By means of the method, the problem that arsenic contained in nickel electrolysis exceeds standards is well solved, the arsenic contained in electrolysis new liquor is smaller than 0.0002 g / l, the arsenic contained in electrolytic nickel is smaller than 0.0005%, and the arsenic removal rate in a solution of a whole system reaches 98% or above.
Owner:JINCHUAN GROUP LIMITED

Preparation method of gel entrapped type efficient arsenic removing material

The invention discloses a preparation method of a gel entrapped type efficient arsenic removing material. The preparation method includes: adding nanoscale iron oxide particles into an alginate aqueous solution, evenly stirring and mixing, using a syringe to suck the mixed solution, using an injection pump to dropwise inject the mixed solution in the syringe into solidification liquid so as to form microspheres, placing the microspheres into curing liquid for curing, and using deionized water to wash the cured microspheres to obtain the gel entrapped type efficient arsenic removing material. The prepared gel entrapped type efficient arsenic removing material is controllable in particle size, wide in application range, high in arsenic removing efficiency during the treatment of high-concentration arsenic-containing wastewater, large in total arsenic removing quantity, fast in treatment, capable of lowering the total arsenic content of the high-concentration arsenic-containing wastewaterto allow the total arsenic content to be below national discharge standards and the like.
Owner:EAST CHINA UNIV OF SCI & TECH

A method for removing arsenic in nickel electrolytic mixed acid system

ActiveCN106757147BSolve the problem of excessive arsenic in electrolysisStable chemical qualityPhotography auxillary processesElectrolysis componentsElectrolysisSlag
The invention discloses an arsenic removal method in a nickel electrolysis mixed acid system. According to the method, the iron-arsenic ratio of anodic electrolyte is reasonably controlled through iron supplementation, and meanwhile, the temperature and pH value of an iron removal process are controlled, so that 80% or more of arsenic is separated out in an iron arsenate or adsorption form in the iron removal process; then, in the cobalt removal stage, the cobalt removal oxidation potential, reaction time and pre-cobalt-removal liquor pH value are controlled, and remaining arsenic in iron removal and arsenic removal filtered liquor is removed with cobaltous hydroxide at the cobalt removal stage in a coprecipitation manner. Besides, iron removal and arsenic removal filtered slag generated by purification and cobalt removal and arsenic removal filtered slag are subjected to nickel removal treatment and then filtered, filtered liquor returns to liquor making for treatment, part of arsenic is brought to the liquor making process, and arsenic removal is induced by controlling solution copper ions and electric current density in the liquor making process. By means of the method, the problem that arsenic contained in nickel electrolysis exceeds standards is well solved, the arsenic contained in electrolysis new liquor is smaller than 0.0002 g / l, the arsenic contained in electrolytic nickel is smaller than 0.0005%, and the arsenic removal rate in a solution of a whole system reaches 98% or above.
Owner:JINCHUAN GROUP LIMITED

Method for producing feed-grade bluestone by using cupreous etching waste liquor of circuit board

The invention relates to a method for producing feed-grade bluestone by using cupreous etching waste liquor of a circuit board, which is characterized by comprising the following steps of: adding an oxidizing agent or airing air and / or oxygen by mixing cupreous etching waste liquor and / or bluestone mother liquor of an acidic circuit board until the solution is transparent; adding a ferric iron solution while stirring, wherein the adding quantity is metered by the total quantity of the solution obtained in the step (1) and the cupreous etching waste liquor and / or ammonia of the acidic circuit board, and amount of Fe3+ is 2-4kg / m3; adding the cupreous etching waste liquor and / or the ammonia of the acidic circuit board while stirring until the pH value of the solution is 8.-8.5; then, adding2-10kg of active carbon into the obtained solution of each cubic meter; continuously stirring for 30 minutes; then; pressing and filtering; adding sulphuric acid into the filter liquor until the pH value is 4.7-5.7 to obtain alkali type copper chloride or copper hydroxide; and filtering, and dissolving a filter mass by sulphuric acid to obtain a bluestone solution. The needed device of the invention is easy to obtain, and the method of the invention has convenient operation, high arsenic removing rate and low cost.
Owner:广州康瑞德农牧科技股份有限公司

PH value method for removing arsenicum from acidic etching liquid of printed circuit board

The invention discloses a pH value method for removing arsenicum from the acidic etching liquid of a printed circuit board. The pH value method comprises the steps of: adjusting the pH value of the waste acidic etching liquid to be treated of the printed circuit board to 2.0-3.0; settling flocculent: (1) taking 0.8-1.5kg of flocculating agent in terms of the waste acidic etching liquid to be treated per cubic meter of the printed circuit board, (2) diluting the flocculating agent with water, and stirring to prepare into a viscous solution, and (3) adding the flocculating agent solution into the waste acidic etching liquid subjected to pH value regulation, stirring for 3-20 min, and then standing for 3-6 h; filtering to remove precipitates to obtain the waste arsenicum-removed acidic etching liquid of the printed circuit board. According to the pH value method for removing the arsenicum in the invention, a pH value regulation method and a flocculent settling method are jointly used, the arsenicum removal treatment of the waste acidic etching liquid of the printed circuit board is realized under the condition of low cost, and the pH value method has the advantages of low treatment cost, simplicity in operation, small equipment investment and the like, and is suitable for the arsenicum removal treatment of a large amount of waste acidic etching liquid of the printed circuit board.
Owner:深圳市东江饲料添加剂有限公司
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