The invention relates to a high-temperature brazing filler as well as a preparation method and a brazing process thereof, in particular to a high-temperature Ti-Zr-based brazing filler for a TiAl-based alloy as well as a preparation method and a brazing process of the high-temperature Ti-Zr-based brazing filler, and solves the problems that after a conventional brazing filler is adopted for brazing, the joint mechanical properties and the high-temperature properties are poor, the brazing filler melting point is low, as well as the brazing filler preparation process and the brazing process are complex. The high-temperature brazing filler provided by the invention comprises the following raw materials in percentage by weight: 10.0-40.0% of Zr, 10-30% of Fe, 10-30% of Mn, 0-5% of one or more of Al, B, Co, Cr, Mg, Ag, Nb and Zn, and the balance of Ti. The preparation method comprises the following steps: 1, weighing raw materials; 2, loading melting equipment with the raw materials, carrying out vacuum pumping, injecting argon gas, carrying out melting for several times, and cooling; and 3, subjecting a mother alloy obtained after the melting to quenching and melt spinning, so as to obtain the high-temperature brazing filler. Then, a brazing filler foil obtained after the quenching is adopted for brazing according to the brazing process of which the temperature and the cycle reach 1100-1250 DEG C and 0-120 min correspondingly. Compared with the conventional brazing filler, the prepared high-temperature brazing filler has the advantages that the melting point is high, the wettability is high, the mechanical properties are excellent, as well as the brazing filler preparation process and the brazing process are simple.