The invention discloses a laminated aluminum alloy template and preparation method thereof. The laminated aluminum alloy template comprises an aluminum alloy template base material and a coating formed on the surface of the aluminum alloy template base material, the coating is formed by curing paint, the paint is prepared from the following raw materials in parts by weight: 50 to 80 parts of titanium-based/nickel-clad aluminum powder, 20 to 30 parts of silica powder, 50 to 80 parts of glycerinum, 100 to 150 parts of polyurethane acrylate, 50 to 100 parts of fluorocarbon resin, 5 to 10 parts ofa fluorine surfactant, 10 to 15 parts of hydrophobic powder, 5 to 7 parts of a dispersant, 2 to 5 parts of a defoamer, 7 to 15 parts of a curing agent, the thickness of the coating is 20 to 30 mu m,the laminated aluminum alloy template prepared by the invention can be used without a mold discharging agent, the surface is smooth after demolding, no concrete is stuck and no reaction with the concrete exists, the laminated coating is tightly adhered to the aluminum alloy template, is not easy to fall off, flake, and is more in aluminum alloy template turnover times, and high in wear resistance.