The invention provides a magnetic steel sheet and a processing method thereof, a rotor, a motor, and an electric vehicle. The contour of the cross section of the magnetic steel sheet comprises a first contour line and a second contour line which are connected end to end. The first contour line comprises a first edge, a second edge and a third edge which are connected in sequence, wherein the first edge, the second edge and the second contour line are on the same side of the second edge, an obtuse angle is formed between the connection line of the two endpoints of the first edge and the connection line of the two endpoints of the second edge, and an obtuse angle is formed between the connection line of the two endpoints of the third edge and the connection line of the two endpoints of the second edge. According to the magnetic steel sheet provided by the invention, by changing the shape of the magnetic steel sheet, the contact area between adjacent magnetic steel sheets in a motor is reduced, the inter-electrode leakage flux of motors is reduced, and the utilization rate of the magnetic steel sheet is improved. The air gap flux density of motors is improved, the torque ripple and noise of motors are reduced, and users feel more comfortable in use. Moreover, the cost of the magnetic steel sheet is reduced, and rare earth resources are saved.