The invention belongs to the technical field of oxygen ion-electron mixed conductor oxygen-permeable membranes and particularly relates to a titanium-based perovskite ceramic oxygen-permeable membranewith no cobalt or iron and a preparation method and application thereof. The titanium-based perovskite ceramic oxygen-permeable membrane herein is made from materials with no cobalt or iron and has achemical composition expression of A1-xTi1-yByO3-delta, wherein A is selected from one or any of La, Y, Pr, Gd, Sm, Ba, Sr and Ca, and B is selected from one or any of Mg, Al, Er, Y, Gd and Zr, with0< / =x< / =0.2 and 0< / =y< / =0.2. The titanium-based perovskite ceramic oxygen-permeable membrane with no cobalt or iron provided herein is excellently stable in the strict working conditions, such as hightemperature, vapor, hydrogen and methane, is suitable for long-term stable operation under reaction conditions, is suitable for preparing high-purity hydrogen by hydrolysis of oxygen-permeable membranes, and is also suitable for producing hydrogen by coupling hydrolysis of a membrane reactor and producing synthetic gas from methane.