The invention discloses a microwave high-power material and a preparation process thereof. The preparation process includes: preparing aluminum oxide ceramic powder, industrial silicon, water and dextrin according to proportion, adding the aluminum oxide ceramic powder, the industrial silicon and the dextrin into a grinder, grinding for 20-40 minutes, adding the water, grinding for 20-40 minutes,taking out, and aging for 70-75 hours; placing the powder material into a mould, applying pressure of 8-12MPa, maintaining the pressure for 8-15 seconds, demoulding to take out a formed wave-absorbingmaterial green body, and placing at normal temperature for 70-75 hours; placing the wave-absorbing material green body into an electric kiln, and sintering according to the corresponding relation between sintering set temperature and sintering set time; cutting the wave-absorbing material green body into a required product shape, performing fine grinding, heating to 150 DEG C in a drying oven, keeping the temperature for 20 minutes, taking out, and cooling to room temperature to obtain the microwave high-power material. The microwave high-power material and the preparation process has the advantages that when the prepared microwave high-power material is applied to high frequency, material size is increased evidently, and processing difficulty is lowered evidently; the actually measured indexes of the material can satisfy use requirements, and the power of the material is increased greatly.