The application relates to the technical field of piezoelectric photocatalytic materials, in particular to a Na,Sm-CaBi2Nb2O9 / O V -BiOBr piezoelectric photocatalytic material, a preparation method and application thereof. The method comprises the following steps: firstly, preparing Na,Sm-CaBi2Nb2O9 by a
molten salt method and dispersing the Na,Sm-CaBi2Nb2O9 in a
mannitol solution; then, adding PVP and Bi(NO3)3.5H2O in sequence; and finally, adding a saturated NaBr solution drop by drop and performing
hydrothermal treatment; through accurate control of a hydrothermal temperature and a reaction time, a Na,Sm-CaBi2Nb2O9 / O 2+ -BiOBr S-type
heterojunction piezoelectric photocatalyst which is rich in
oxygen vacancies and has a shared (Bi2O2) V interface is finally obtained. The catalyst realizes the transfer of carrier recombination centers through the
electron capture effect of
oxygen vacancies, optimizes the local
dipole state distribution and the interface non-
centrosymmetry, effectively controls the carrier recombination path, significantly enhances the
piezoelectric polarization strength, successfully inhibits the self-reduction behavior of the interface Bi 3+ , and greatly improves the piezoelectric photocatalytic activity. The application effectively solves the problems of high
crystal face mismatch degree, insufficient stability and low piezoelectric photocatalytic activity of traditional
bismuth-based
heterojunction materials by constructing structure-matched
heterojunction materials, and opens up a new way for the application of layered
bismuth-based
perovskite materials in the field of piezoelectric
photocatalytic water splitting.