The application discloses a
perovskite solar cell based on electronic interception stable surface
passivation layer and a preparation method thereof, and belongs to the technical field of solar cells. The
solar cell comprises a transparent conductive substrate, a
hole transport layer, a
perovskite layer, a surface
passivation layer, an
electron transport layer and an
electrode which are arranged in a stack. The surface
passivation layer is made of 3-carbamoyl-2,2,5,5-tetramethylpyrrolin-1-oxyl radical (CTPL) and phenethylammonium
chloride. The application introduces CTPL into the phenethylammonium
chloride passivation
system, captures the photo-generated electrons on the
perovskite surface, prevents the photo-generated electrons from generating
superoxide radicals with
oxygen, thereby inhibits the
deprotonation process of the phenethylammonium salt passivation layer, and significantly improves the stability of the passivation layer. Meanwhile, the application avoids the carrier transport obstruction caused by the discontinuous
electron capture or interface charge accumulation, maintains the continuity of the charge transport between the
absorption layer and the
transport layer and the interface matching, and keeps a high
photoelectric conversion efficiency and photo-
thermal stability in long-term operation.