A compound of rubidium sodium chloroborate and rubidium sodium chloroborate optical crystal, its preparation method and application. The compound rubidium sodium chloroborate has a chemical formula of RbNa2B6O10Cl and a molecular weight of 391.76. It is synthesized by a solid-state reaction method. The chemical formula of the rubidium sodium chloroborate optical crystal is RbNa2B6O10Cl. Molecular weight 391.76, belongs to orthorhombic crystal system, space group P212121, unit cell parameters are a=8.3251(3)Å, b=9.6543(3)Å, c=12.7544(4)Å, Z=4, V=1025.11(6 )Å3, the light transmission band is between 190nm and 2600nm, and the crystal is grown by the high-temperature melt method. The rubidium sodium chloroborate optical crystal has moderate mechanical hardness, is easy to cut, polish, process and store, is insoluble in water, does not deliquesce, and is insoluble in air. Medium stability, suitable for making optical devices such as windows, lenses and prisms. For example: windows, hoods or fairings used in infrared detectors and aircraft; convex lenses used in microscopes and telescopes; prisms used in periscopes, binoculars and other instruments to change the direction of light.