The invention belongs to the field of preparation of
propellant oxidant materials, and relates to a method for preparing ADN-based composite microspheres through layer-by-layer
assembly, preparation of a binder
oil phase containing
solid particles, preparation of an ADN water phase, preparation of a homogeneous
emulsion, preparation of the ADN-based composite microspheres through layer-by-layer
assembly of the binder /
solid particles and application of the ADN-based composite microspheres in a
solid propellant. The hydroscopicity of the prepared microspheres is reduced by 80% or above compared with that of the
raw material ADN, the obtained ADN-based composite
microsphere particles are added into a solid composite propulsion formula, a
combustion test is carried out under the same
humidity condition, and if the
raw material ADN
propellant is not ignited, the ADN-based composite
microsphere propellant has obvious flames and is stable in
combustion. The homogeneous
emulsion is simple in preparation process, mild in reaction condition and simple and safe to operate, a
high polymer bonding
system in the oil-phase
solvent can be selected from various types, and the method for reducing the hygroscopicity of the ADN by
coating a layer of hydrophobic material on the basis of introducing an active
coating into the homogeneous
emulsion has a remarkable anti-hygroscopicity effect.