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30results about How to "Does not dissolve" patented technology

Lithium cobaltate positive electrode material and preparation method thereof, and lithium ion secondary battery

ActiveCN108123109AWithout sacrificing gram capacityWithout sacrificing energy densityCell electrodesSecondary cellsLithiumCompound structure
The present invention provides a high-voltage lithium cobaltate positive electrode material, which is a compound structure of a doped lithium cobaltate substrate and a surface coating layer, wherein the general formula of the doped lithium cobaltate substrate is Li1+zCo1-x-yMaxMbyO2, x is more than or equal to 0 and is less than or equal to 0.01, y is more than or equal to 0 and is less than or equal to 0.01, z is more than or equal to -0.05 and is less than or equal to 0.08, Ma is a doped element with unchanged valence, and is at least one selected from Al, Ga, Hf, Mg, Sn, Zn and Zr, Mb is adoped valence-changing element, and is at least one selected from Ni, Mn, V, Mo, Nb, Cu, Fe, In, W and Cr, and the surface coating layer is a high-voltage (more than 4.5 V) positive electrode material. According to the present invention, the element with unchanged valence is doped through substitution, such that the layered structure distortion caused by lithium removing can be minimized; the valence-changing element is subjected to gap doping, such that the Co<3+> oxidation is blended and delayed during the charging; and the surface coating layer has the stable structure at the voltage of more than 4.5 V, can separate the electrolytic solution from the lithium cobaltate substrate, can reduce the side reaction between the electrolytic solution and the lithium cobaltate substrate, can suppress the dissolution of the transition metal, and further can provide electrochemical energy.
Owner:HUAWEI TECH CO LTD

Preparation method of electromagnetic composite hollow microspheres

The invention provides a preparation method of electromagnetic composite hollow microspheres, relates to a preparation method of a composite hollow material and aims to solve the problems of poor conductivity, high density and high falling possibility of magnetic particles of the existing composite hollow material. The preparation method comprises the following steps: 1, preparing polystyrene microspheres; 2, dispersing the polystyrene microspheres in concentrated sulfuric acid, and sulfonating; 3, preparing a magnetic Fe3O4 nano particle suspension; 4, adding the sulfonic-group-containing SPS microspheres and the Fe3O4 nano particle suspension into a water solution; 5, adding ethanol and ammonia water, and dropwisely adding ethyl orthosilicate; 6, adding into a PVP-containing ethanol solution, and stirring; and 7, mixing an aniline solution with the PVP modified magnetic microspheres, dropwisely adding ammonium persulfate, drying, adding N,N-dimethylformamide, and soaking. For the prepared hollow microspheres, the conductivity is 0.01-1.0 S/cm, the density is low, and the magnetic particles are less prone to fall; and the hollow microspheres are mainly used in the fields of light-weight electromagnetic materials, photonic crystals, wave-absorbing materials and the like.
Owner:HARBIN INST OF TECH

Preparation method of hard alloy with orientational distribution of featured crystal surfaces of WC crystal grains

The invention discloses a preparation method of hard alloy with orientational distribution of featured crystal surfaces of WC crystal grains and belongs to the technical field of hard-alloy metallurgy. The preparation method comprises the following steps of: by adopting a mixture of tungsten oxide, cobalt oxide and carbon material as a raw material, carrying out mixed ball grinding; carrying out cold pressing on ball-ground mixed powder to form a blank, and putting the blank in a vacuum reaction furnace to carry out in-situ reduction and carbonization reaction to obtain WC-Co composite powder containing carbon-deficient phase components under lower temperature; and finally, putting the prepared composite powder in a sintering system which can apply sintering pressure to carry out in-situ reaction sintering densification on the powder to obtain the hard-alloy block material with orientational distribution of the featured crystal surfaces of the WC crystal grains. The preparation method has the advantages of simple process step, short preparation period and low sintering temperature and the like in the aspects of preparing the composite powder and sintering the hard-alloy block material; and the hard-alloy block prepared by sintering has controllable size of the WC crystal grains, obvious anisotropy of structures and mechanical properties and strong repeatability.
Owner:BEIJING UNIV OF TECH

Extraction agent for synchronous production of various functional components of cape jasmine, and extraction and separation method thereof

The invention specifically relates to a high-efficient extraction agent for synchronous extraction of four effective functional components from cape jasmine fruits, and an extraction, separation and purification process. The key of the invention is to innovate a new extraction agent, and a water extraction technology containing a certain of stabilizer and / or cosolvent is adopted for replacing a percolation extraction or alcohol extraction process which is commonly used in the current production process, so that the production period is greatly reduced and the production and processing cost is effectively lowered; and the invention further comprises a process technology integrating online membrane separation and concentration with double-column tandem column chromatography for purification and integration, which can realize high-efficient preparation of various functional components from cape jasmine. The extraction agent disclosed by the invention has the advantages of low cost, small using quantity and no residues, and can obviously improve the dissolution rate of terpenoid and phenol compounds in raw materials of the cape jasmine fruits and enable the product extraction rate to exceed 95%; and the method is also suitable for extraction, separation and preparation of the functional components in other parts of the raw materials in addition to the cape jasmine fruits.
Owner:WUHAN POLYTECHNIC UNIVERSITY

A kind of preparation method of cemented carbide with wc grain characteristic crystal plane orientation distribution

The invention discloses a preparation method of hard alloy with orientational distribution of featured crystal surfaces of WC crystal grains and belongs to the technical field of hard-alloy metallurgy. The preparation method comprises the following steps of: by adopting a mixture of tungsten oxide, cobalt oxide and carbon material as a raw material, carrying out mixed ball grinding; carrying out cold pressing on ball-ground mixed powder to form a blank, and putting the blank in a vacuum reaction furnace to carry out in-situ reduction and carbonization reaction to obtain WC-Co composite powder containing carbon-deficient phase components under lower temperature; and finally, putting the prepared composite powder in a sintering system which can apply sintering pressure to carry out in-situ reaction sintering densification on the powder to obtain the hard-alloy block material with orientational distribution of the featured crystal surfaces of the WC crystal grains. The preparation method has the advantages of simple process step, short preparation period and low sintering temperature and the like in the aspects of preparing the composite powder and sintering the hard-alloy block material; and the hard-alloy block prepared by sintering has controllable size of the WC crystal grains, obvious anisotropy of structures and mechanical properties and strong repeatability.
Owner:BEIJING UNIV OF TECH

Simultaneous production of extractant and its extraction and separation method for multiple functional components of Gardenia jasminoides

The invention specifically relates to a high-efficient extraction agent for synchronous extraction of four effective functional components from cape jasmine fruits, and an extraction, separation and purification process. The key of the invention is to innovate a new extraction agent, and a water extraction technology containing a certain of stabilizer and / or cosolvent is adopted for replacing a percolation extraction or alcohol extraction process which is commonly used in the current production process, so that the production period is greatly reduced and the production and processing cost is effectively lowered; and the invention further comprises a process technology integrating online membrane separation and concentration with double-column tandem column chromatography for purification and integration, which can realize high-efficient preparation of various functional components from cape jasmine. The extraction agent disclosed by the invention has the advantages of low cost, small using quantity and no residues, and can obviously improve the dissolution rate of terpenoid and phenol compounds in raw materials of the cape jasmine fruits and enable the product extraction rate to exceed 95%; and the method is also suitable for extraction, separation and preparation of the functional components in other parts of the raw materials in addition to the cape jasmine fruits.
Owner:WUHAN POLYTECHNIC UNIVERSITY

A method for extracting and separating natural saffron and its preparation for reducing blood lipid

The present invention particularly relates to a nature crocin extraction separation method and preparation for a crocin blood fat reduction drug. The extraction separation method comprises: carrying out cleaning and impurity removing on dried cape jasmi fruits, extracting with deionized water, filtering to removing residue, carrying out online membrane separation and concentration fusion and macroporous absorption resin chromatography purification, and finally carrying out low-temperature spray drying to prepare the crocin. According to the present invention, the key of the invention is to create the extraction agent, and the water containing a certain auxiliary solvent is adopted to extract the crocin, wherein the extraction rate can be more than 95%; the online membrane separation and concentration fusion and the macroporous absorption resin chromatography purification are integrated; the high purity crocin production method has a characteristic of low cost and is suitable for industrial expansion production; and the compounded pharmaceutical preparation has effects of significant blood fat reduction, no side effect, effective cardiovascular and cerebrovascular related disease prevention, and blood circulation promotion, and is the preferred health care drug for crowds with high blood pressure, high blood fat and high blood sugar.
Owner:WUHAN NEW GUOFENG TECH DEV

High corrosion resistance zinc-aluminum-magnesium hot-dip galvanized steel sheet and production method thereof

The invention discloses a high-corrosion-resistant zinc-aluminum-magnesium hot-dipped steel plate and a production method thereof, which includes a substrate and a coating coated on the substrate, and is characterized in that the mass percentage of the chemical composition of the coating is: Al 1.8~2.3%, Mg 1.2~1.8%, RE 0.01~0.08%, Cu 0.003~0.008%, the balance is Zn and other unavoidable impurities; Cu is added to the plating solution in nanometer form when the plating solution melts . Cu in the coating of this steel plate is added in the form of nano-copper when the plating solution melts. Since the temperature of the zinc solution is low when it is added, the morphology of Cu particles can be guaranteed, and its fine and dispersed characteristics can play a role in precipitation strengthening, thereby Improve the hardness of the coating; the addition of rare earth RE can refine the coating structure and improve the fluidity of the plating solution, thereby more effectively improving the corrosion resistance of the coating. The structure in the coating of the product gained by this method is: primary Zn, Zn / MgZn 2 Binary eutectic, Zn / Al / MgZn 2 Ternary eutectic and nano-copper; the corrosion resistance is equivalent to 10 to 15 times that of pure zinc plates of the same thickness.
Owner:HEBEI IRON AND STEEL

Lithium cobalt oxide positive electrode material, preparation method thereof, and lithium ion secondary battery

ActiveCN108123109BWithout sacrificing gram capacityWithout sacrificing energy densityCell electrodesSecondary cellsElectrolytic agentElectrical battery
Provided is a lithium cobalt oxide positive-electrode material, said material being a composite structure having a doped lithium-cobalt-oxide substrate and surface coating; the general formula of said doped lithium-cobalt-oxide substrate is Li 1+zCo 1-x-yMa xMb yO 2, wherein 0≤x≤0.01, 0≤y≤0.01 and -0.05≤z≤0.08; said Ma is a doped invariable-valence element, at least one of Al, Ga, Hf, Mg, Sn, Zn, and Zr; said Mb is a doped variable-valence element, at least one of Ni, Mn, V, Mo, Nb, Cu, Fe, In, W, and Cr; the surface coating layer is a high-voltage (>4.5 V) positive-electrode material. By means of substitution doping of the variable-valence element, distortion resulting from delithiation of the layered structure is reduced by the maximum extent; the variable-valence element is doped by means of gaps, and during the process of charging, the oxidation of Co 3+is reconciled and delayed. The surface coating layer of the high-voltage positive-electrode material has a stable structure at voltages of 4.5 V or higher, and is capable of isolating an electrolyte solution and a lithium-cobalt-oxide substrate, thus reducing side reactions between the two and inhibiting the dissolution of transition metals; it also provides electrochemical energy.
Owner:HUAWEI TECH CO LTD
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