The technical scheme of the invention discloses a steam turbine set of a power station and a power generation method of the steam turbine set. The steam turbine set comprises a solar heat exchanger set, a steam brayton cycle and a steam rankine cycle, the solar heat exchanger set comprises a first superheater, a first reheater, a second superheater and a second reheater, the steam brayton cycle comprises a compressor, a heat regenerator, a high-pressure turbine, a middle heat exchanger and a first power generator, and the steam rankine cycle comprises a condensation water pump, a low-pressureheater, a deaerator, a water feeding pump, a high-pressure heater, a medium-pressure turbine, a low-pressure turbine, a condenser and a second generator. According to the steam turbine set, the steamturbine set organically combines the brayton cycle with the rankine cycle, on one hand, the heat efficiency of the rankine cycle can be remarkably improved, on the other hand, the working medium flowpassing through the high-pressure turbine is very large, the internal efficiency of the high-pressure turbine is improved, the heat efficiency of the brayton cycle is ensured, and finally the heat efficiency of the whole unit is remarkably improved.