The invention relates to nuclear stainless steel electroslag remelting slag used for high-level radioactive waste curing container and a method adopting electroslag remelting. The slag comprises, by weight part, 55 to 70 parts of CaF2, 8 to 15 parts of CaO, 8 to 15 parts of Al2O3, 5 to 15 parts of MgO, 1 to 5 parts of SiO2 and 1 to 5 parts of CeO2, a slag remelting method is adopted, rare earth inthe stainless steel can be stably controlled, harmful impurities can be greatly reduced, the structure is uniform and compact, the alloy machining performance can be greatly improved, the yield rateis improved, the good mechanical property, and good properties of high temperature resistance, corrosion resistance, oxidation resistance and the like are achieved, good hot and cold machining performance, welding performance and machining performance are achieved, and the method has the wide application prospect in the nuclear waste treatment field.