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47results about How to "Reduce quenching effect" patented technology

Fluorescent microsphere marker and preparation method thereof

The invention relates to a fluorescent microsphere marker and a preparation method thereof. The invention aims to provide a fluorescent microsphere marker. Compared with the traditional fluorescent marker, the fluorescent microsphere marker disclosed by the invention has the advantages of higher fluorescence intensity and higher stability, is easier to mark and is simpler to prepare. The technical scheme of the fluorescent microsphere marker is to provide the fluorescent microsphere marker. The fluorescent microsphere marker comprises a carrier, wherein the carrier is a microsphere polymerized by a styrene monomer, and the microsphere is connected with a fluorescence complex. The fluorescent microsphere marker disclosed by the invention has the beneficial effects that the preparation method is simpler and easier because the microsphere polymerized by the styrene monomer is used as the carrier. The microsphere disclosed by the invention not only can be used for marking the rare earth fluorescence complex but also can be used for marking common fluorescence substance, such as FITC (fluorescein isothiocyanate), the microsphere with various fluorescence properties can be manufactured, and the requirement of multiple detection can be satisfied.
Owner:福州泰普生物科学有限公司

Composite microsphere marker for conducting fluorescent marking on rear earth and preparation method of composite microsphere marker

The invention provides a composite microsphere marker for conducting fluorescent marking on rear earth and a preparation method of the composite microsphere marker and relates to the technical field of functional polymer biomaterials. The preparation method includes the steps that polyvinylpyrrolidone, potassium persulfate / persulphate and styrene are added to an ethyl alcohol medium or a water medium to be dissolved and then placed into an ultrasonic-wave reactor, a polymerization reaction is generated under protection of nitrogen gas, and polystyrene nanometer microsphere dispersion liquid is obtained; then rare earth fluorescence complex 4, 7-dichloro sulfo benzene-1, 10 phenanthroline-2, 9 dicarboxylic acid-europium or 4, 4-di (1, 1, 1, 2, 2, 3, 3, -heptafluoride-4,6,-adipic ketone group) chlorine sulfo-adjacent-terphenyl- europium is fixed to the surface of a silicon dioxide microsphere in a chemical bonding mode, and finally the composite microsphere marker for conducting fluorescent marking on rear earth is prepared. The composite microsphere marker has the advantages of being long in fluorescent lifetime, good in stability, easy to synthesize, low in cost and easy to mark.
Owner:JIANGSU YINUOWAN CELL CLINIC CO LTD

High-efficient anti-quenching neodymium-doped rare earth infrared fluorescent probe and synthetic method thereof

The invention belongs to the technical field of nano-biomaterials and particularly provides a high-efficient anti-quenching neodymium-doped rare earth infrared fluorescent probe and a synthetic method thereof. The fluorescent probe is a nano-crystal in a core-shell structure and includes two parts: a down-conversion luminescent core and an inert shell layer, wherein the down-conversion luminescent core is a neodymium-doped rare earth nano-crystal and is totally coated with the inert shell layer for enhancing a luminescent stability and a luminescent efficiency of the nano-crystal. In the invention, a high-boiling-point solution and a sodium/potassium/lithium/barium trifluoroacetate solution are employed as precursors and a shell-layer precursor solution is introduced at a high temperature in a continuously alternate manner for achieving layer-by-layer coating of the neodymium-doped nano-crystal nucleus. By means of control of the amount of the shell-layer precursor dropwisely added every time, continuous adjustment of thickness of the shell layer is achieved. In the invention, the synthetic method can improve down-conversion luminescent quantum yield and the luminescent stability of neodymium and can reduce a quenching effect of down-conversion luminescence doped by neodymium ions due to environment.
Owner:FUDAN UNIV

Phosphine-oxygen red/orange thermally activated delayed fluoresce material as well as synthesis method and application thereof

The invention discloses a phosphine-oxygen red / orange thermally activated delayed fluoresce material as well as a synthesis method and application thereof, relates to the thermally activated delayed fluoresce material as well as the synthesis method and the application thereof, and aims to solve the problems that a conventional red / orange TADF (Thermally Activated Delayed Fluoresce) material is slightly low in concentration quenching and electroluminescent device efficiency and rapid in attenuation because of high molecular polarity. The structural formula of the material is as shown in the specification. The synthesis method comprises the following steps: preparing 9-(2-bromine-4-(1,3-dioxolane-2-yl) phenyl-9H-carbazole or 9-(2-bromine-4-(1,3-dioxolane-2-yl) phenyl)-3,6-ditert-butyl-9H-carbazole, preparing 4-(9H-carbazole-9-yl)-3-(diphenylphosphine oxide) benzaldehyde or 4-(3,6-ditert-butyl-9H-carbazole-9-yl)-3-(diphenylphosphine oxide) benzaldehyde, and preparing a final product. By adopting the material disclosed by the invention, the efficiency of an electroluminescent device is remarkably improved, the quenching effect is reduced, and the efficiency stability of the electroluminescent device is improved. The material belongs to the field of fluorescence material preparation.
Owner:JIANGSU FUXIN ELECTRONICS LIGHTING TECH

Hollow white composite quantum dot preparation method, display panel and display device

The embodiments of the invention disclose a hollow white composite quantum dot preparation method, a display panel and a display device. In the preparation method, unicolor quantum dots of different colors are prepared into corresponding unicolor quantum dot emulsions through an emulsion polymerization technique, dissolved silicon dioxide nano particles are used as a seed solution, the individual unicolor quantum dot emulsions are dropped in the seed solution in sequence, such that the surfaces of the silicon dioxide nano particles are coated with the unicolor quantum dots in the individual unicolor quantum dot emulsions in sequence according to the dropping order so as to obtain white composite quantum dots, and finally, the silicon dioxide nano particles in the white composite quantum dots are removed to obtain hollow white composite quantum dots. The hollow white composite quantum dot particles obtained by the preparation method are controllable in particle size and uniform in size, and the problems of low quantum efficiency, poor stability of quantum dots, and the like are solved; besides, the color gamut of the hollow white composite quantum dots can be adjusted, so that the applicability is high, and the application range is wide; in addition, the preparation method is simple, and a batch production is facilitated.
Owner:BOE TECH GRP CO LTD

Dipyridine phenazinyl red/orange photothermal excitation delayed fluorescence material as well as synthesis method and application thereof

The invention discloses a dipyridine phenazinyl red/orange photothermal excitation delayed fluorescence material as well as a synthesis method and the application thereof. The invention relates to a fluorescence material as well as the synthesis method and the application thereof. The invention aims at solving the problems of concentration quenching, extremely-low efficiency and fast attenuation of electroluminescent devices due to high molecular polarity in an existing red/orange light TADF material. The structure of the material is as shown in the specification. The synthesis method comprises the following steps: preparing (6-(4-(diphenyl amino) phenyl) benzo[c][1,2,5] thiadiazole-5-yl) diphenylphosphine oxide or (7-(4-(diphenyl amino) phenyl) benzo[c][1,2,5]thiadiazole-4-yl) diphenylphosphine oxide; preparing the required donor; and obtaining a final product. The material disclosed by the invention has the advantages that the efficiency of an electroluminescent device is obviously improved, the quenching effect is reduced and the efficiency stability of the electroluminescent device is enhanced. The invention belongs to the preparation field of fluorescent materials.
Owner:HEILONGJIANG UNIV

Phosphonooxy-modified dipyridophenazine-based red/near-infrared thermally excited delayed fluorescent material, and synthesis method and application thereof

The invention relates to a thermally excited delayed fluorescent material, and a synthesis method and an application thereof, and concretely relates to a phosphonooxy-modified dipyridophenazine-based red/near-infrared thermally excited delayed fluorescent material, and a synthesis method and an application thereof. The purpose of the invention is to solve the problem of concentration quenching caused by large molecular polarity of existing problems of red/near-infrared TADF materials and the problems of low efficiency and fast attenuation of electroluminescent devices. The structural formula of the material is shown in the description. The synthesis method comprises the following steps: 1, preparing an intermediate; 2, taking and mixing the intermediate, palladium acetate, sodium acetate, diphenylphosphine and N,N-dimethylformamide, reacting the obtained mixture at 150 DEG C for 48 h, oxidizing the obtained reaction product, extracting the oxidized reaction product with water and dichloromethane, mixing obtained organic layers, drying the organic layer mixture to remove the organic solvent, and purifying the obtained product to obtain the phosphonooxy-modified dipyridophenazine-based red/near-infrared thermally excited delayed fluorescent material. The material of the invention significantly improves the efficiency of electroluminescent devices, reduces the quenching effect, and enhances the efficiency stability of the electroluminescent devices. The invention belongs to the field of preparation of fluorescent materials.
Owner:HEILONGJIANG UNIV

Processing method of aluminum profile for passenger vehicle

The invention provides a processing method of an aluminum profile for a passenger vehicle. The processing method comprises the following steps: selecting an Al-Mg-Si series aluminum alloy ingot with the weight percentage of Mg being 0.5-1.1%, the weight percentage of Si being 0.4-0.8% and the weight percentage of Fe being less than 0.6% as an extrusion raw material of the aluminum profile; raw material selection and provided extrusion parameters are reasonable, during extrusion, metal flow is uniform, efficient and rapid, the machining range is wide, the aluminum profile extrusion device can be suitable for machining aluminum profiles of passenger vehicles with various sections and sizes, and the extruded aluminum profiles are fine in crystal grain, high in straightness, good in strength, stable in performance and high in rate of finished products. According to the provided combined online quenching method, accurate cooling control can be carried out according to the temperature and the structure state of the profile, quenching cooling is uniform, the quenching requirements of aluminum profiles with different thicknesses and complex section structures can be met, the cooling range is wide, the application range is wide, the cooling efficiency of some aluminum profiles not suitable for online quenching can also meet the online quenching requirement, and the service life of the aluminum profiles is prolonged. And the process of independent quenching can be omitted, so that the equipment investment is reduced, and the production cost is reduced.
Owner:江阴协宏金属制品有限公司

Hollow white composite quantum dot preparation method, display panel and display device

The embodiments of the invention disclose a hollow white composite quantum dot preparation method, a display panel and a display device. In the preparation method, unicolor quantum dots of different colors are prepared into corresponding unicolor quantum dot emulsions through an emulsion polymerization technique, dissolved silicon dioxide nano particles are used as a seed solution, the individual unicolor quantum dot emulsions are dropped in the seed solution in sequence, such that the surfaces of the silicon dioxide nano particles are coated with the unicolor quantum dots in the individual unicolor quantum dot emulsions in sequence according to the dropping order so as to obtain white composite quantum dots, and finally, the silicon dioxide nano particles in the white composite quantum dots are removed to obtain hollow white composite quantum dots. The hollow white composite quantum dot particles obtained by the preparation method are controllable in particle size and uniform in size, and the problems of low quantum efficiency, poor stability of quantum dots, and the like are solved; besides, the color gamut of the hollow white composite quantum dots can be adjusted, so that the applicability is high, and the application range is wide; in addition, the preparation method is simple, and a batch production is facilitated.
Owner:BOE TECH GRP CO LTD
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