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41 results about "Catatonic reaction" patented technology

Method for membrane electrolysis of mineralized CO2 co-produced strong acid

The invention discloses a method for membrane electrolysis of mineralized CO2 co-produced strong acid. The method comprises the following steps of: placing an anion-exchange membrane in an electrolytic bath to ensure that the electrolytic bath is separated into a positive area and a negative area; adding a mineralized raw material and a negative electrode solution into the negative area, charging carbon dioxide gas into the negative area at the same time; adding a positive electrode solution into the positive area; and applying a direct current supply between a positive electrode and a negative electrode, wherein the negative electrode reduces hydrogen ions in the negative electrode solution into hydrogen gas to ensure that the carbon dioxide in the solution is transformed into carbonate radicals or bicarbonate radicals which react with positive ions in the mineralized raw material to realize the mineralization of the CO2 and obtain a mineralized product, and negative ions in the mineralized raw material permeate through the anion-exchange membrane and enter the positive area under the action of current to combine with the hydrogen ions generated by the positive electrode so as to generate the strong acid. The method has the characteristics operation at normal temperature and pressure, simple process, low energy consumption and suitability for industrial production.
Owner:SICHUAN UNIV

Cationic reactive Gemini polyurethane surfactant and preparation method thereof

The invention discloses a cationic reactive Gemini polyurethane surfactant and a preparation method thereof and belongs to the technical field of fine chemicals. The cationic reactive Gemini polyurethane surfactant is obtained by enabling excess diisocyanate to sequentially react with fatty amine polyoxyethylene ether and a chain extender, further adding a blocking agent to block remaining isocyanate groups, then neutralizing and dispersing in water. A series of surfactants with different performances, uses and unblocking temperatures can be obtained by selecting the types of fatty amine polyoxyethylene ether, the chain extender and the blocking agent. The cationic reactive Gemini polyurethane surfactant disclosed by the invention can solve the problem that the traditional surfactant is easy to migrate and precipitate on the one hand, and improve the compatibility of the cationic reactive Gemini polyurethane surfactant and the traditional surfactant, as well as water resistance, dielectricity, optical transparency and other performances on the other hand; furthermore, the cationic reactive Gemini polyurethane surfactant can realize the effects of strengthening, toughening, reducing surface tension and the like for a matrix, and shows broad application prospects in the fields of preparation of polymer emulsions, finishing of leather and synthetic leather, textile coating and the like.
Owner:SICHUAN UNIV

Antitumor platinum (II) compound using camphor acid radical as ligand

The present invention discloses platinum (II) complexes with effective anticancer activity, characterized in that the new platinum (II) complexes are formed by reacting the anionic ligand of Camphoric radicals with the cationic ligand of amine platinum. The preparation process of these complexes and the in vitro inhibition effect of leukemic cell, oophoroma cell, hepatoma cell and pulmonary carcinoma cell with the typical compounds of the present invention are also disclosed. The structures of the present complexes are represented by the following formulas: (1), (2) and (3), wherein the Camphoric radicals in formula (l), (2) and (3) can be DL type raceme, D type optical isomer [1R, 3S) - (+) -Camphoric radical] or L type optical isomer [(1S, 3R)-(-)-Camphoric radical]. In formula (1) R is the same, representing hydrogen atom, C1-5alkyl or Cl-8oxaalkyl; In formula (2) the cyclohexanediamine is 1,2-t­rans-cyclohexanediamine, wherein both of the two chiral carbon atoms (marked with *) have the absolute configuration of R or S; In formula (3) R1 and R2 linked to the 4, 5-bis (aminomethyl) -2-alkyl-1, 3-­dioxolane, same or different, independently represent hydrogen atoms or C1-5 alkyl, or link to one carbon to form a cycle, wherein both of the two chiral carbon atoms(marked with *) have the absolute configuration of R or S. The platinum complexes of the present invention include all stereomers and mixtures of compounds represented by above formulas.
Owner:NANJING UNIV
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