36 results about "Exciton dissociation" patented technology

Efficient photovoltaic devices with quantum dots are provided. Quantum dots have numerous desirable properties that can be used in solar cells, including an easily selected bandgap and Fermi level. In particular, the size and composition of a quantum dot can determine its bandgap and Fermi level. By precise deposition of quantum dots in the active layer of a solar cell, bandgap gradients can be present for efficient sunlight absorption, exciton dissociation, and charge transport. Mismatching Fermi levels are also present between adjacent quantum dots, allowing for built-in electric fields to form and aid in charge transport and the prevention of exciton recombination.

The invention relates to a solar cell with a small organic molecule mixture heterojunction, which comprises a transparent insulating layer, wherein a transparent electrode layer, a first buffer layer, a first photosensitive layer, a second photosensitive layer, a third photosensitive layer, a second buffer layer and a high-reflectivity electrode layer are sequentially laminated at one side of the transparent insulating layer; and a lower transition layer is formed at the other side of the transparent insulating layer. The mixture heterojunction and the lower transition layer are combined together, so that the solar spectrum utilization ratio of the organic solar cell and exciton dissociation efficiency can be improved; meanwhile, the high-reflectivity electrode is reasonable utilized, the optical field distribution in the device can be adjusted, therefore, the solar cell can work at an optimum state. The invention also relates to a preparation method of the solar cell.

The present invention relates to an organic photoelectric detector with high external quantum efficiency and a broad spectral response. The organic photoelectric detector provided by the invention comprises the followings connecting in order: a lower conversion layer, a substrate, an anode, an electron injection barrier layer, an electron-transporting layer, an active layer and a cathode. The thickness of the electron injection barrier layer is from 1 nm to 10 nm, the thickness of the electron-transporting layer is from 5 nm to 60 nm, the thickness of the active layer is from 5 nm to 200 nm, and the thickness of the cathode is from 50 nm to 1000 nm. According to the invention, a relatively high photoelectric multiplication effect (EQE>15000%) is realized as well by means of improving the electron tunneling injection at electrodes through employing holes after exciton dissociation, and the structure provided by the invention is fully beneficial to an organic photoelectric detection device realizing a broad spectral response.

Systems, methods and devices for the efficient photocurrent generation in single- or multi-walled carbon nanotubes, which includes (SWNTs) / poly [3-hexylthiophene-2,5-diyl] (P3HT) hybrid photovoltaics, and exhibit the following features: photocurrent measurement at individual SWNT / P3HT heterojunctions indicate that both semiconducting (s-) and metallic (m-) SWNTs function as excellent hole acceptors; electrical transport and gate voltage dependent photocurrent indicate that P3HT p-dopes both s-SWNT and m-SWNT, and exciton dissociation is driven by a built-in voltage at the heterojunction. Some embodiments include a mm2 scale SWNT / P3HT bilayer hybrid photovoltaics using horizontally aligned SWNT arrays, which exhibit greater than 90% effective external quantum efficiency, among other things, which advantageously provide carbon nanomaterial based low cost and high efficiency hybrid photovoltaics.

The present invention, in one embodiment, provides a method of forming an organic electric device that includes providing a plurality of carbon nanostructures; and dispersing the plurality of carbon nanostructures in a polymeric matrix to provide a polymeric composite, wherein when the plurality of carbon nanostructures are present at a first concentration an interface of the plurality of carbon nanostructures and the polymeric matrix is characterized by charge transport when an external energy is applied, and when the plurality of carbon nanostructures are present at a second concentration the interface of the plurality of carbon nanostructures and the polymeric matrix are characterized by exciton dissociation when an external energy is applied, wherein the first concentration is less than the second concentration.

The invention relates to a polymer solar battery and a preparation method of the polymer solar battery. The polymer solar battery comprises an anode substrate, a cavity buffer layer, an active layer and a metal cathode which are sequentially stacked, and also comprises an inorganic layer arranged between the active layer and the metallic cathode.\The polymer solar battery comprises the active layer / inorganic layer structure, the distribution of an optical field in the active layer can be improved, so that a generating region of a carrier is changed, a good place is provided for exciton dissociation, and meanwhile, the transmission efficiency of the carrier is improved; and a contacting interface of the active layer and the cathode is separated, so that metal atoms are prevented from diffusing to the active layer to further destroy the structure of the active layer, the role of a buffering layer is played, and the collection efficiency of electrons at the position of the electrode is improved.

The invention discloses an ordered heterojunction photovoltaic device and a preparation method thereof. the ordered heterojunction photovoltaic devices includes a negative layer, an interface modification layer, a photovoltaic active layer, a hole barrier layer, a positive electrode layer and a substrate from top to bottom, wherein the photovoltaic active layer comprises an organic layer and an inorganic layer, wherein the inorganic layer is an ordered nanorod array perpendicular to the substrate, the organic layer fills and covers the nanorod array, the top surface of the organic layer is parallel to the substrate, and the nanorod height in the nanorod array is 300-500 nm, and the diameter is 50-100 nm, and the distance between the nanorods is 60-80nm, the nanorod array and the organic layer of the invention intersect each other to form an ordered network structure, The photogenerated exciton dissociation surface can be ensured to be large, and the electrons and holes generated by thedissociation can be transported in the two transmission channels respectively, so that the hopping transmission of the carriers between the donor material particles and the acceptor material particles is avoided, the charge recombination probability is effectively reduced, and higher photoelectric conversion efficiency can be obtained.

The invention belongs to the technical field of organic photovoltaic devices or organic semiconductor film solar cells, and particularly relates to an active layer used for a ternary blending solar cell and application of the active layer. In the active layer, high-crystallinity P3HT serves as a donor, micromolecular DPP4T-Cz serves as a second donor, and a fullerene derivate PC61BM serves as an acceptor. Under the condition that the active layer is relatively thick, a good carrier transport capacity of the cell is ensured, the carrier recombination efficiency is reduced, a good exciton dissociation efficiency is obtained, and the optical absorption range is enpanded.

The invention discloses a non-fullerene electron acceptor material and a preparation method and application thereof. The star-shaped non-fullerene electron acceptor material is obtained by taking an electron donating structure as a central core unit and a five-membered fused ring as an arm unit, and blocking a terminal group by using electron withdrawing groups such as 3-(dicyanomethylene) indanone and derivatives thereof. The material not only maintains the advantages of a linear non-fullerene electron acceptor material, but also has high electron mobility and isotropic charge transfer characteristics of a fullerene electron acceptor material, and the multidimensional geometric structure of the material is beneficial to intramolecular charge transfer, so that the energy gap is reduced and the absorption range is expanded, and the star-shaped multi-dimensional structure can effectively inhibit excessive aggregation and is beneficial to exciton dissociation. The material can be used as an electron acceptor material of an active layer to be widely applied to preparation of organic solar cells, and excellent material film stability and excellent photoelectric conversion characteristics can be obtained.

The invention discloses a fluorine and rubidium doped perovskite solar cell and a preparation method thereof. The solar cell comprises a substrate, a conductive layer, a TiO2 dense layer, a TiO2 mesoporous layer, a fluorine and rubidium doped perovskite light absorbing layer, a hole transport layer and a counter electrode from bottom to top, wherein the material of the fluorine and rubidium dopedperovskite light absorbing layer is Cs1-xRbxPbBrI2-yFy, x is 0-0.05, y is 0-0.3, and the thickness is 300-500nm. The preparation method includes the following steps of: A, preparation of the conductive layer; B, preparation of the TiO2 dense layer and the TiO2 mesoporous layer; C, preparation of the fluorine and rubidium doped perovskite light absorbing layer; D, preparation of the hole transportlayer; and E, preparation of the counter electrode. According to the scheme of the invention, the spectral absorption performance of the light absorbing layer and the overall efficiency of a battery can be improved; the battery performance attenuation speed can be greatly reduced; the exciton dissociation and charge transfer can be facilitated, and can be relatively stable in the later battery attenuation; and without packaging, the solar cell can be used in higher water oxygen content and has good intrinsic stability.

The present disclosure generally relates to organic photosensitive optoelectronic devices and polaron pair recombination dynamics to impact efficiency and open circuit voltages of organic solar cells. The present disclosure also relates, in part, to methods of making organic photosensitive optoelectronic devices comprising the same.

The invention belongs to the field of organic photovoltaic cells, and particularly relates to an organic small-molecule photovoltaic device based on a three-terminal electrode structure. The organic small-molecule photovoltaic device comprises an ITO layer serving as a first electrode layer, an organic small-molecule donor connected with a conductive face of the ITO layer, an organic small-molecule receptor connected with the other face of the organic small-molecule donor, a second electrode layer connected with the other face of the organic small-molecule receptor, a dielectric layer connected with the other face of the second electrode layer, and a third electrode layer connected with the other face of the dielectric layer, the first electrode layer is connected with a negative electrode of a direct-current voltage source, the third electrode layer is connected to a positive electrode of the direct-current voltage source, and the first electrode layer and the second electrode layer serve as output ends. According to the device, due to the fact that a potential is applied to the two ends of the organic small-molecule photovoltaic device, a strong electric field can be formed in the organic small-molecule photovoltaic device, the exciton disassociation efficiency is improved, and the energy conversion benefit of the organic small-molecule photovoltaic device is improved.

The invention belongs to the organic photoelectric material and organic ultraviolet light detector field and relates to an organic ultraviolet light detector taking HATCN and a Cu (I) complex prepared by the HATCN as an anode buffer layer. A structure of the detector sequentially comprises an ITO anode, an anode buffer layer, an electron donor layer, a mixed donor and acceptor layer, an electron acceptor layer, an electron injecting layer and a cathode. The detector is characterized in that the HATCN and the Cu (I) complex prepared by the HATCN have relatively high electron mobility and relatively good film forming ability and stability, electrons are facilitated through quite low LUMO energy level to shuttle among HOMO energy levels of the anode and the donor, so the electrons and excitons can realize rapid dissociation to form cavity composition, cavity transmission is further facilitated by charge composition mechanism, and thereby performance of the detector is improved. According to the detector, by employing the material of the anode buffer layer, performance of the organic ultraviolet light detector is greatly improved, aging of the organic ultraviolet light detector is slowed down, and stability of the organic ultraviolet light detector is improved.

The invention relates to a preparation method of a two-dimensional transverse polymer heterojunction visible-light response catalytic hydrogen production material and application thereof. A phenanthrene polymer semiconductor plane is grafted to a graphite phase carbon nitride plane through a high-temperature thermo-polymerization method; as a phenanthrene polymer semiconductor is matched with a graphite phase carbon nitride semiconductor energy band to form a heterojunction structure, and a built-in field is formed at a boundary of heterojunctions to promote dissociation of light excitons, thephotocatalytic performance of a graphite phase carbon nitride material is improved; meanwhile, both the phenanthrene polymer semiconductor and graphite phase carbon nitride are visible-light responsecatalysts and are polymer conjugate materials; a pi-pi conjugate exists along a heterojunction plane, so that photon-generated carriers can be transmitted faster in a pi-pi conjugate system, and thetwo-dimensional polymer heterojunction material achieves higher light exciton dissociation efficiency and carrier transmission rate. The method has the advantages of a simple process, low cost, shortperiod, visible-light response and the like, and the finally formed two-dimensional transverse polymer heterojunction photocatalytic material is excellent in photocatalytic hydrogen production performance.

The invention belongs to the field of semiconductor photoelectronic devices, and particularly relates to a perovskite solar cell based on a nano grass-shaped mesoporous layer and a preparation methodthereofl. The structure of the solar cell comprises a transparent substrate, a first electrode layer, a functional layer and a second electrode layer. the functional layer comprises an electron transport layer, a perovskite light absorption layer and a hole transport layer. The preparation method disclosed by the invention comprises the following steps: growing a metal oxide with a sheet-shaped single crystal nano grass structure in the vertical direction of a transparent conductive glass substrate by adopting a liquid phase deposition method, and taking the metal oxide as an electron or holetransport layer material of the solar cell, wherein the surface of the sheet-shaped single crystal nano grass-shaped metal oxide is composed of an atomic structure, the chemical energy is high and surface coordination of the transmission layer and the perovskite can be promoted to form optimal interface coupling, thereby providing a large-area interface and a high energy potential for exciton dissociation, carrier injection and transportation, improving the carrier interface dynamic process and improving the photoelectric conversion efficiency of the perovskite solar cell.

The present invention discloses a quantum dot light-emitting diode device and a preparation method thereof. The device comprises a substrate, a bottom electrode, a hole injection layer, a hole transmission layer, a quantum dot luminescent layer, an electron transfer layer, an electron injection layer and a top electrode in order. The quantum dot luminescent layer at least has one surface provided with a plurality of periodically distributed grooves. Periodically distributed grooves are arranged in the luminescent layer to add the contact areas between the carrier transportation layer and the quantum dot luminescent layer materials so as to improve the efficiency of the carrier injection quantum dot luminescent layer; the transmission obstruction of the between the carriers between the quantum dots to allow more excitons to perform direct injection through the carriers or perform migration formation between short quantum dot; the quantum dot light-emitting diode device and the preparation method thereof can reduce the effect of exciton dissociation between the quantum dots; the quantum dot light-emitting diode device and the preparation method thereof can reduce the formation of lots of exciton-carrier three-body structure caused by carrier injection and imbalance transmission and reduce the exciton quenching; and moreover, the quantum dot light-emitting diode device and the preparation method thereof can employ the raster coupling principle to add the optical coupling of the diode and the emission efficiency.

The invention discloses an amphipathic conjugated polymer and a production method and application thereof. The polymer is a naphthalene diimide polymer derivative which is obtained through copolymerization of naphthalene diimide (NDI), dibenthiophene and amphipathic group-substituted dibromonaphthalene diimide. By introducing an amphipathic group, without having large effects on spectral absorption and energy level alignment, the polymer is applied as an organic solar cell material active layer material or an adding component, a donor-acceptor ratio of an active layer does not need to be changed, the micro-phase separation state can be effectively adjusted, the exciton dissociation efficiency can be improved, and molecular orientation can be enhanced, so that the photoelectric conversion efficiency of an organic photovoltaic device is significantly improved.

The invention provides a lorentz force based novel polymer solar cell preparation method. The preparation method comprises the following steps of sputtering an indium-tin oxide positive electrode (2) on a glass substrate (1), and performing spin-coating on a hole transport layer (3); enabling a layer of 40-60nm neodymium-iron-boron magnetic materials (4-1) to be grown in a strong magnetic field, and performing photoetching to form strip-shaped patterns (4-1), wherein the strip-shaped direction is perpendicular to the magnetic field direction; enabling polymer light-sensitive layer materials (4-2) which are formed by co-mixing of a donor and a receptor to be dispensed or printed between the strip-shaped patterns (4-1) which are formed by photoetching, and forming a lorentz force light-sensitive layer (4) based on alternative growth of the magnetic materials and the strip-shaped light-sensitive materials; and performing spin-coating on an electron transport layer (5) and evaporating an aluminum negative electrode (6). According to the preparation method, the mutual alternative growth mode of the magnetic materials and the strip-shaped light-sensitive materials is established; the directions of the magnetic fields formed by every two strip-shaped magnetic materials are consistent, so that the movement of electrons to the direction of the negative electrode, and the movement of holes to the direction of the positive electrode are reinforced; therefore, the transport of electrons and holes to the transport layer after exciton dissociation can be promoted; the exciton recombination is reduced; the thickness of the light-sensitive layer is increased; and the improvement of the photoelectric conversion efficiency of the polymer solar cell is facilitated.

The invention relates to a diphenylamino-truxene-BODIPY derivative ternary system organic dye as well as a preparation method and application thereof. A 3-site and 5-site modified BODIPY derivative and a diphenylamine derivative are respectively connected to 2, 7 and 12 sites of truxene through covalent bonds through a chemical reaction to construct a D-A-pi-D molecular system, introduction of diphenylamine is beneficial to pi electron delocalization, intramolecular charge transfer is promoted, so that the photoelectric conversion efficiency of organic dye molecules is improved; the organic dye provided by the invention has strong light absorption capability, and can effectively perform exciton dissociation; the synthesis method provided by the invention is simple, mild in reaction condition, relatively good in selectivity and small in environmental pollution; when the organic dye is used in an organic solar cell, a good effect is obtained, and the photoelectric conversion efficiency can reach 13.32%; and the organic dye can be used in the field of solar cells.

The invention relates to a multi-exciton dissociation heterojunction based on a perovskite nanocrystalline-acene organic molecule hybrid material. According to the heterojunction, perovskite nanocrystalline is used as a light absorption layer material, and acene molecules are used as a multi-exciton dissociation layer material. High extinction coefficient of perovskite nanocrystals is utilized toabsorb light efficiently, and benzene molecules quickly extract holes in perovskite to realize exciton dissociation. The size of the perovskite nanocrystals is 1-50 nanometers, and the perovskite nanocrystals can be all-inorganic perovskite or organic-inorganic hybrid perovskite. Through a time-resolved spectrum detection technology, it is observed that the hole transfer time from CsPbBr2. 625Cl <0.375 > to TCA molecules is 7.6 picoseconds, and the service life of a charge separation state is as long as 5.1 microseconds. The super-long charge separation state enables the heterojunction to dissociate six photo-induced excitons.

The present invention relates to a class of diphenylamino-tripolyindene-BODIPY derivative ternary system organic dyes and a preparation method and application thereof. The BODIPY derivatives modified at positions 3 and 5 are covalently bonded with diphenylamine derivatives through chemical reactions. They are respectively connected to the 2, 7, and 12 positions of trisindene to form a D-A-π-D molecular system. The introduction of diphenylamine is conducive to the delocalization of π electrons, and promotes intramolecular charge transfer, thereby improving the photoelectric conversion of organic dye molecules. Efficiency; the organic dye provided by the invention has strong light absorption ability and can effectively dissociate excitons; the synthesis method provided by the invention is simple, the reaction conditions are mild, the selectivity is good, and the environmental pollution is small; it can be used in organic solar energy Good results have been obtained in batteries, and the photoelectric conversion efficiency can reach 13.32%. The organic dye can be used in the field of solar batteries.

The invention discloses a bipolar organic field effect transistor with a vertical lamination structure, which belongs to the field of microelectronic organic devices. At this stage, the carrier mobility of bipolar organic field effect transistors with horizontal structure is not ideal, and it is far from meeting the requirements of modern integrated circuit technology. The present invention proposes a bipolar organic field effect transistor with a vertical stacked structure. A structure in which an N-type active layer and a P-type active layer are vertically stacked is formed by a photolithography method, and consists of a substrate, a gate electrode, a gate dielectric layer, The active layer and the source and drain electrodes are composed and stacked in sequence. This structure increases the interface between N-type and P-type active layers, increases the dissociation rate of excitons at the interface, and thus increases carrier mobility. A bipolar organic field effect transistor with a vertical stacked structure can provide a new idea for preparing high-performance bipolar field effect transistors, which may have a significant impact on the development of organic discrete devices.

The invention discloses a method for improving the performance and stability of organic solar batteries based on thiophene additives. The method is to add a certain proportion of thiophene additives when configuring the organic active layer solution. The general structural formula is as formula (I), wherein n=4-10; X is selected from any one of H, F, Cl, Br, I. The invention regulates the morphology of the donor-acceptor blend film by adding thiophene additives to the active layer solution, so that the active layer forms a suitable nano-phase-separated structure and orderly aggregation of the donor-acceptor, which is conducive to improving the exciton dissociation efficiency and photogenerated carrier mobility, thereby improving battery performance and lifetime. Therefore, organic solar cells based on thiophene compounds as solvent additives have the advantages of high photoelectric conversion efficiency, long life, simple preparation process and low cost.

The invention discloses an organic field effect transistor with a composite channel, which belongs to the field of microelectronic organic devices. At this stage, the field effect characteristics of the horizontally superimposed organic field effect transistors are not ideal, and they are far from the requirements of modern integrated circuit technology. The present invention provides an organic field effect transistor with a compound channel. By adopting a photolithography method and a mask method, a horizontal and longitudinally superimposed compound active layer is formed. The drain electrodes are composed and stacked in sequence. The structure increases the number of interfaces between the N-type active layer and the P-type active layer, and increases the number of carriers generated by exciton dissociation, thereby improving the field effect characteristics of the organic field effect transistor. A composite channel organic field effect transistor can provide a new idea for the preparation of organic field effect transistors with good field effect characteristics, which has an important impact on the commercial application of organic field effect transistors.

The invention belongs to the field of organic solar cells, and in particular relates to an asymmetric cyanomethylene indone acceptor material and its preparation method and application. The present invention obtains an "accept-give-accept" ("A-D-A") type cyanomethylene indone electron acceptor material with an asymmetric structure by introducing an asymmetric donor unit. The asymmetric cyanomethylene indone acceptor material of the present invention weakens the electron donating property of the donor unit by appropriately reducing the conjugation length of the donor unit, thereby appropriately reducing its highest occupied energy level (HOMO), and obtaining After obtaining a suitable energy level structure, the asymmetric cyanomethylene indotone acceptor material is blended with three commonly used polymer donor materials PTB7-Th, PBDB-T, and FTAZ to achieve good energy level matching , so as to obtain high-efficiency exciton dissociation and charge transfer, and ensure better solar cell device performance, thereby expanding the use range of non-fullerene acceptors.

The invention relates to a bipolar organic field effect transistor. The bipolar organic field effect transistor comprises a substrate, a gate, a gate dielectric layer, an N-type active layer, a P-typeactive layer, a source and a drain, wherein the N-type active layer and the P-type active layer are arranged side by side in a cross mode among the source, the drain and gate dielectric layer to forma vertical laminated structure. The vertical laminated structure can make exciton dissociation at the interface between the N-type active layer and the P-type active layer sufficient so as to improvethe carrier mobility of electrons and holes in the organic bipolar field effect transistor. Therefore, the bipolar organic field effect transistor effectively improves the performances of the bipolarorganic field effect transistor.

The invention relates to a preparation method and application of a two-dimensional lateral polymer heterojunction visible light responsive catalytic hydrogen production material. The phenanthrene polymer semiconductor plane is grafted to the graphite phase carbon nitride plane using a high-temperature thermal polymerization method. Since the phenanthrene polymer The energy bands of the semiconductor and the graphite-phase carbon nitride semiconductor are matched to form a heterojunction structure, and a built-in field is formed at the junction of the heterojunction to promote the dissociation of photo-generated excitons, thereby improving the optical properties of the graphite-phase carbon nitride material. Catalytic performance, while both phenanthrene polymer semiconductor and graphite phase carbon nitride are visible light response catalysts and are polymer conjugated materials. There is π-π conjugation along the heterojunction plane, allowing photogenerated carriers to Faster transfer occurs in the π conjugated system, allowing the two-dimensional polymer heterojunction material to obtain higher photogenerated exciton dissociation efficiency and carrier transfer rate. This method has the advantages of simple process, low cost, short cycle, and visible light response. The two-dimensional lateral polymer heterojunction photocatalytic material finally formed has excellent photocatalytic hydrogen production performance.

The invention discloses an organic field-effect tube of a composite channel, and belongs to the field of microelectronic organic devices. The field effect characteristic of horizontal stacking organic field-effect tubes at the present stage is unsatisfactory, and cannot reach the requirement of modern integrated circuit technology. According to the organic field-effect tube of the composite channel provided by the invention, horizontal and longitudinal stacking composite active layers are formed by adopting photolithography and mask method, and the organic field-effect tube consists of a substrate, a gate electrode, a gate dielectric layer, the active layers, source and drain electrodes which are stacked in sequence. According to the structure, the interface amount of N-type active layers and P-type active layers is increased, the amount of current carriers generated through exciton dissociation is increased, and thus the field effect characteristic of the organic field-effect tube is improved. The organic field-effect tube of the composite channel can provide a novel idea for preparing the organic field-effect tube with good field effect characteristic, and has an important influence on commercialization application of the organic field-effect tube.

The invention discloses a narrow-band gap conjugated polymer based on benzobithiophene diazole and tellurophene and application of the narrow-band gap conjugated polymer in a self-driven short-wave infrared response organic photoelectric synapse flexible device. The narrow-band-gap polymer is good in solubility, the spectral absorption range covers a visible light area, a near-infrared band and a part of short-wave infrared bands, close packing of molecules is promoted through tellurium-tellurium interaction between polymer chains, and therefore the narrow-band-gap polymer has a high dielectric constant and is beneficial to photogenerated exciton dissociation. And meanwhile, due to the extremely unbalanced hole and electron transmission capability of the polymer, electrons which are relatively slowly transmitted become trap centers, so that holes of an external circuit continuously tunnel and are injected into a device, and a photoconductive effect is generated. The short-wave infrared response organic photoelectric synapse two-end flexible device prepared on the basis of the mechanism can work without external bias voltage, simulates multiple nerve synapse behaviors, and achieves a good effect.