The invention discloses a reaction apparatus of a microwave pyrolysis biomass. The reaction apparatus comprises a microwave pyrolysis unit, the microwave pyrolysis unit comprises a microwave thermal decomposition furnace, and at least a feed inlet arranged outside the microwave thermal decomposition furnace, the microwave thermal decomposition furnace comprises a solid-phase pyrolysis part and a gas-phase pyrolysis part connected in order from down to up, the solid-phase pyrolysis part comprises a solid-phase hollow circular column composed of metal mesh, and the solid-phase hollow circular column is filled with a solid-phase microwave absorbent and a catalyst. The reaction apparatus increases the pyrolysis heating rate, reduces the generation amount of solid carbon residue, increases theproportion of pyrolysis gas in products, and optimizes the pyrolysis reaction process, has the advantages of simple equipment, less land occupation, and convenient operation, can complete operation ofcontinuous feeding and deslagging, and is convenient for operation and management.