The invention discloses a high-temperature resistant wave-absorbing coating and a preparation method and application thereof. The high-temperature resistant wave-absorbing coating mainly comprises a high-temperature resistant wave-absorbing filler, silica sol, nano-silica dispersion, an acidic medium, glass powder, ethylene glycol, a dispersant, an anti-settling agent, siloxane and the like, wherein the high-temperature resistant wave-absorbing filler comprises Fe3O4-graphene- SiO2 composite nanoparticles. The high-temperature resistant wave-absorbing coating can be naturally dried at room temperature, and can resist high temperature of 100-400 DEG C for a long time, and a formed coating layer has good adhesion with a substrate, high hardness, wide wave-absorbing frequency band, and excellent corrosion resistance and salt fog resistance.