This application relates to the field of
sodium-
ion batteries, specifically to an outdoor low-temperature
sodium-
ion battery and its preparation method. The preparation method of the positive
electrode active material of this
sodium-
ion battery is as follows: Preparation of a
mixed solution: soluble salts of
nickel,
manganese, and
niobium are dissolved and mixed to obtain a
mixed solution; Co-
precipitation: under an
inert atmosphere, the
mixed solution is mixed with a precipitant and heated for co-
precipitation, then filtered and dried to obtain a precursor; Mixed
calcination: the precursor, sodium source, and
acetylene black are mixed, pre-sintered at 450-550℃, then sintered at 850-900℃, and after crushing and
grinding, the positive
electrode active material is obtained; the sodium source includes at least one of
sodium carbonate and
sodium acetate. This application uses a
nickel-
manganese-
niobium ternary
metal synergistic preparation of the positive
electrode active material, utilizing pre-
sintering and high-temperature
sintering to form a stable O3-type layered
oxide structure, in which the tightly packed
oxygen atom
layers are Na. + It provides continuous
diffusion channels, and the paths are not easily blocked by lattice contraction at low temperatures.