The invention discloses a
graphite composite material as well as a preparation method and application thereof. The material comprises
graphite and a composite
porous carbon layer
coating the
graphite, the composite
porous carbon layer contains hard carbon and graphitized carbon, the
graphite composite material is prepared from the raw materials of the composite
porous carbon layer, the graphite and an
oxygen-containing pore-forming agent, the raw materials of the composite porous
carbon layer comprise a hard carbon precursor and a graphitized carbon precursor, and the
oxygen-containing pore-forming agent is prepared from the hard carbon precursor and the graphitized carbon precursor. The
mass ratio of the graphite to the total
mass of the raw materials of the composite porous
carbon layer is less than 28: 1, and the
mass ratio of the graphitized carbon precursor to the hard carbon precursor is more than 1: 1; the ratio of the total mass of the raw materials of the composite porous
carbon layer to the mass of the
oxygen-containing pore-forming agent is more than 10: 1. When the
graphite composite material disclosed by the invention is prepared into a negative
electrode material of a secondary battery, the
graphite composite material has excellent quick charging performance and good
cycling stability, and a new possibility is developed for high-performance battery application in multiple fields of electric automobiles, portable
electronic equipment,
energy storage systems and the like.