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30results about How to "Hydrophobic performance is stable" patented technology

Preparation method of modified silicon dioxide obtained via super-hydrophobic modification

The invention discloses a preparation method of modified silicon dioxide obtained via super-hydrophobic modification. The preparation method comprises following steps: 1) a raw material A (a silicon dioxide base material, dry powder) is delivered into a mixer, a mixed state is maintained, a raw material C (a super-hydrophobic modification accessory ingredient prepared via mixing of 1.5% acetic acid aqueous solution and isopropanol at a mass ratio of 1-3:4-10) is atomized, and is sprayed into the mixed uniformly, and stirring is kept; 2) a raw material B (a hydrophobic modification agent organic silane coupling agent) is atomized, and is sprayed into the mixer uniformly, and stirring is kept; 3) aging is carried out; and 4) ultrafine grinding is carried out so as to obtain a finished product. Fewer processing steps are needed; energy consumption is low; requirements of industrialized large-scale production can be satisfied; particle size distribution of the modified silicon dioxide obtained via super-hydrophobic modification is uniform; pore structures are stable; and hydrophobic performance is stable. The prepared super-hydrophobic silicon dioxide prepared via the preparation method is taken as a flatting agent, and can be used for providing paint with super hydrophobic performance; film forming coating particle arrangement is uniform; and luster is soft.
Owner:北京航天赛德科技发展有限公司

Hydrophobic fumed silica

A hydrophobic fumed silica treated with a cyclic dimethylsiloxane, the hydrophobic fumed silica having an M-value representing an oleophilic degree in a range of 48 to 65, a tapping bulk density of not smaller than 80 g / L but not larger than 130 g / L, and an n-value representing the dispersion of 3.0 to 3.5 as measured in toluene. The hydrophobic fumed silica features a high bulk density while exhibiting a high hydrophobic property, the powder thereof capable of being favorably handled, being easily mixed in a matrix such as of a resin within short periods of time, and, further, being dispersed in the matrix to a high degree.
Owner:TOKUYAMA CORP

Hydrophobization modification method for ramie nano cellulose

The invention provides a hydrophobization modification method for ramie nano cellulose. The method comprises the steps of preprocessing ramie nano cellulose and xylan, then carrying out modification reaction on the ramie nano cellulose and xylan, adding the soaked and wetted ramie nano cellulose into a hardwood xylan solution, putting into ultrasonic and dispersing, stirring by a machine, layering the mixture by centrifuging, transferring the upper layer clear liquor, and molding the left concentrated ramie nano cellulose suspension liquid through liquid nitrogen vacuum freeze drying so as to obtain the dehydrated modified ramie nano cellulose. Dehydrated modification is carried out on the ramie nano cellulose by using the acetylation of the hardwood xylan, so that the polarity and hydrophilia of plant fiber are lowered, the agglomeration of nano cellulose is inhibited, and the interfacial compatibility and cohesiveness of the ramie nano cellulose and the hydrophobic resin are improved. The method is simple and efficient, has good repeatability, has environment-friendly processes, uses the environment-friendly modification reagents, and has great scientific significance and considerable application prospect.
Owner:DONGHUA UNIV

Super-hydrophobic chitosan oil-absorbing sponge and preparation method thereof

InactiveCN109485911ATightly boundCombined with automaticOther chemical processesAlcoholFreeze-drying
The invention relates to a preparation method for super-hydrophobic chitosan oil-absorbing sponge. The preparation method comprises the following steps: (1) preparing chitosan-based sponge with a three-dimensional porous structure by using a vacuum freeze-drying method; (2) preparing modified Fe3O4 particles, and enabling the modified Fe3O4 particles and nano zinc oxide particles to be loaded in the three-dimensional porous structure of the chitosan-based sponge; and (3) soaking the obtained chitosan-based sponge in octadecanethiol-absolute ethyl alcohol solution, and repeatedly compressing and expanding, after curing, to obtain a product. Compared with existing chitosan-based sponge, the product has excellent hydrophobic oil-absorbing properties, and a high repeated utilization ratio.
Owner:湖北彩砼新材料有限公司

Highway construction and maintenance method based on cement-based composite material

InactiveCN110700041AReduce interface strengthReduce chemical adhesionRoads maintainencePolyvinyl alcoholGraphene flake
The invention discloses a highway construction and maintenance method based on a cement-based composite material. The method comprises the following steps: 1) modifying polyvinyl alcohol fibers; 2) material preparation: firstly, carrying out dry mixing on cement, fly ash and sand for 1-6 minutes; adding water and a water reducing agent, then adding a nano graphene sheet or graphene oxide dispersion liquid, stirring at a low speed for 5-10 minutes, adding modified polyvinyl alcohol fibers while stirring after uniformly flowing cement mortar is obtained, and stirring at a high speed for 5-10 minutes after all the modified polyvinyl alcohol fibers are added; carrying out a flow table fluidity experiment on the slurry in the stirring process until the fluidity of the slurry reaches 200 mm or above and the fibers are uniformly dispersed; 3) precasting cement-based composite material components; and 4) carrying out paving; according to the invention, the construction performance is good, theconstruction cost is low, and construction is convenient.
Owner:维特国际新材料(武汉)有限公司

Method for modifying polyvinyl alcohol fiber for high-ductility cement-based composite material

The invention provides a method for modifying polyvinyl alcohol fiber for a high-ductility cement-based composite material. The surface of the polyvinyl alcohol fiber contains a large amount of hydroxyl groups, the hydroxyl groups on the surface of the polyvinyl alcohol fiber react with a cement matrix to form a relatively strong chemical bonding force, and the strong chemical bonding force causesfiber breakage in the pull-out process, so that the ductility is affected. The method comprises the following steps: with the polyvinyl alcohol fiber as a raw material, firstly coating the surface ofthe polyvinyl alcohol fiber with a layer of epoxy resin, and then coating the surface of epoxy resin coating with a layer of fumed silica powder. Due to surface hydrophobicity of the modified polyvinyl alcohol fiber, the interfacial strength between the polyvinyl alcohol fiber and the cement matrix can be effectively weakened and the chemical bonding force can be reduced, so that the polyvinyl alcohol fiber is pulled out of the cement matrix in the stretching process, without breakage; the hydrophobicity and the wear-resistant slip property of a product are more stable, and the coating is more wear-resistant and the original physical and mechanical properties of the PVA fiber are not affected.
Owner:SOUTHEAST UNIV

Fluoride-free durable super-hydrophobic cotton cloth and preparation method and application thereof

The invention discloses fluoride-free durable super-hydrophobic cotton cloth and a preparation method and application thereof, and belongs to the field of super-hydrophobic materials. The preparationmethod comprises the following steps that hydrolysis reaction is carried out on 3-methacryloxypropyltrimethoxy silane and silicon dioxide to obtain modified silicon dioxide; secondly, cotton cloth fibers are modified by using 3-mercaptopropyltriethoxysilane, so that mercapto groups on the surfaces of the fibers are functionalized; and finally, under the action of a photoinitiator and illuminationof a mercury lamp, sulfydryl-alkene click chemical reaction is carried out on sulfhydrylation cotton cloth, methacryloyloxy polydimethylsiloxane and the modified silicon dioxide to prepare the super-hydrophobic cotton cloth. The super-hydrophobic cotton cloth prepared by the method has self-cleaning property and an oil-water separation function. Raw materials are cheap, easy to obtain and environmentally friendly, and the prepared material is stable in hydrophobicity and has good wear resistance. Meanwhile, the preparation method is simple, mild in preparation condition and convenient for large-scale production, and has huge industrial application potential.
Owner:EAST CHINA NORMAL UNIV

Product with coating and preparation method thereof

The invention discloses a product with a coating and a preparation method thereof. The coating comprises a fluorosilane compound with reactive terminal groups. The reactive terminal groups are groups capable of reacting with a base layer of the product. The coating is connected to the base layer of the product by a chemical bond. The coating has good endurance and stable hydrophobicity and can resist a wet environment and external force-caused sliding friction.
Owner:SIEMENS SHANGHAI MEDICAL EQUIP LTD

A kind of preparation method of superhydrophobic modified silicon dioxide

The invention discloses a preparation method of modified silicon dioxide obtained via super-hydrophobic modification. The preparation method comprises following steps: 1) a raw material A (a silicon dioxide base material, dry powder) is delivered into a mixer, a mixed state is maintained, a raw material C (a super-hydrophobic modification accessory ingredient prepared via mixing of 1.5% acetic acid aqueous solution and isopropanol at a mass ratio of 1-3:4-10) is atomized, and is sprayed into the mixed uniformly, and stirring is kept; 2) a raw material B (a hydrophobic modification agent organic silane coupling agent) is atomized, and is sprayed into the mixer uniformly, and stirring is kept; 3) aging is carried out; and 4) ultrafine grinding is carried out so as to obtain a finished product. Fewer processing steps are needed; energy consumption is low; requirements of industrialized large-scale production can be satisfied; particle size distribution of the modified silicon dioxide obtained via super-hydrophobic modification is uniform; pore structures are stable; and hydrophobic performance is stable. The prepared super-hydrophobic silicon dioxide prepared via the preparation method is taken as a flatting agent, and can be used for providing paint with super hydrophobic performance; film forming coating particle arrangement is uniform; and luster is soft.
Owner:北京航天赛德科技发展有限公司

Preparation method of polysiloxane modified super-hydrophobic sponge for oil-water separation

The invention discloses a preparation method of polysiloxane modified super-hydrophobic sponge for oil-water separation, and belongs to the technical field of functional material preparation and application. According to the preparation method, a proper amount of hydrophobic gas-phase nano SiO2 is dispersed into a solution of hydroxyl-terminated polydimethylsiloxane and tetraethoxysilane, and the super-hydrophobic melamine sponge is prepared by a dipping method and has a good porous structure and hydrophobic and oleophylic characteristics. When being used for oil-water separation, the oil-water separator has excellent anti-compression performance and recycling performance. The process is simple and convenient, the cost is low, the main raw materials are non-toxic, harmless, green and environment-friendly, all the raw materials are commercially available industrial products, large-scale production is easy to achieve, and the method has wide application prospects in separation and recovery of oil-containing or organic solvent and water mixtures.
Owner:CANGZHOU NORMAL UNIV

High-strength flame-retardant ABS alloy material and preparation method thereof

The invention relates to the technical field of polymer materials, and discloses a high-strength flame-retardant ABS alloy material and a preparation method of the high-strength flame-retardant ABS alloy material. The ABS alloy material comprises the following raw materials in parts by weight: 20 to 80 parts of an ABS copolymer, 10 to 70 parts of polycarbonate, 3 to 10 parts of a compatibilizer, and 0.1 to 0.5 part of an antioxidant; the components are mixed, subjected to melt blending, extruded, air-dried and granulated to obtain the ABS alloy material. The alloy material disclosed by the invention has high strength and excellent fire resistance.
Owner:杭州金州高分子科技有限公司

Heating cup

The invention relates to the technical field of daily articles, and discloses a heating cup. The heating cup comprises a cup body, a cup cap, a temperature sensor, a controller, a control display screen and a heating assembly; the cup body is composed by compactly connecting a heat insulation layer and a cup main body from outside to inside, and a cavity is formed in the middle between the heat insulation layer and the cup main body; a cup opening of the cup main body is in threaded connection with the cup cap; the temperature sensor is arranged in the middle of the inner wall of the cup mainbody, and is electrically connected to the control display screen; the heating assembly is arranged in the cavity; the control display screen is arranged in the middle of the outer side of the heat insulation layer, and is electrically connected with the controller; the controller is arranged at the bottom of the heat insulation layer, and is connected with a power supply through an inserting hole; a processor is arranged in the controller, and receives electrical signals transmitted by the control display screen and tissues orders. According to the heating cup, by additionally arranging the heat insulation layer, the temperature sensor and the heating assembly, through an indirect heating mode, the suitable in-cup temperature is kept, temperature increasing and preservation of a heating object is achieved accordingly, and the using safety is improved.
Owner:广西驰胜农业科技有限公司

Super-hydrophobic covalent organic framework material as well as preparation method and application thereof

The invention belongs to the field of super-hydrophobic materials, and particularly relates to a super-hydrophobic covalent organic framework material and a preparation method and application thereof. The super-hydrophobic covalent organic framework material LNUs is obtained by taking 4-(tetramethyl-1,3,2-dioxaborolan-2-yl)-N,N-bis-[4-(tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl as a construction element and carrying out Suzuki coupling reaction on the 4-(tetramethyl-1,3,2-dioxaborolan-2-yl)-N,N-bis-[4-(tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl and a pi-conjugated dibromo carbazole monomer. The method provided by the invention has the advantages of easily available raw materials and simple preparation process, and can meet actual production requirements. The contact angle of the prepared super-hydrophobic material can reach 150 degrees or above, stable hydrophobic performance can be kept under severe conditions of strong acid, strong alkali, high temperature and the like, mixed liquid of multiple kinds of water and oil (or organic solvents) is separated, and the separation efficiency can reach 90% or above. After 10 times of recycling, the original separation effect can still be maintained, and the super-hydrophobic covalent organic framework material has good practicability in the field of oil-water separation treatment in environmental sewage.
Owner:LIAONING UNIVERSITY

Preparation method of hydrophobic mineralized waste fiber adsorption material

The invention provides a preparation method of a hydrophobic mineralized waste fiber adsorption material. The method specifically includes pretreatment of waste fibers, ozone treatment, alternative impregnation, hydrophobization modification of mineralized waste fibers, and other steps. This method uses one or more of waste paper, waste sweater, and waste cotton clothes as raw materials. The fibers are treated with ozone to enable grafting with polyacrylic acid and to provide calcium ion attachment points, and then calcium carbonate is added as a medium to realize hydrophobization modificationof the polymer material. The use of highly toxic chemical reagents in the production process is avoided so that the method has an advantage in constructing environmentally safe functional materials.The waste fibers obtained through modification have higher oil absorption and oil retention rates for a plurality of types of oil, and have better adsorption performance. The prepared oil-absorbing material is environment-friendly, cheap and simple to prepare and has potential application value in oil-water pollutant treatment.
Owner:广东海纳新材料科技有限公司

Paper protection method for improving surface hydrophobicity

The invention provides a paper protection method for improving surface hydrophobicity. The paper protection method comprises the following steps: 1) soaking paper with an alkaline solution; 2) applying a zinc acetate dehydrate solution to the paper, and reacting on the surface of the paper to generate a zinc oxide precursor; and 3) carrying out dehydration reaction on the treated paper at 70-85 DEG C to obtain the paper with flaky zinc oxide on the surface. According to the method, sheet-shaped zinc oxide crystals in a specific form are loaded on paper fibers to improve the hydrophobicity of the surface of the paper, so that the hydrophobicity of the surface of the paper can be improved under the condition that ink marks, pigments and paper bodies on the surface of the paper are not damaged.
Owner:HANGZHOU ZHONGCAI TECH CO LTD

Non-photosensitive siloxane coating for processing hydrophobic photoimageable nozzle plate

A method of forming a patterned photoresist layer having a hydrophobic surface is provided. The method includes forming a photoresist layer on a substrate and image patterning. The photoresist layer may comprise a polymeric material. The imaged photoresist layer may then undergo a two-stage post-exposure bake. A surface treatment may be performed on the photoresist layer in between the two-stage post-exposure bake. The surface treatment may include applying a siloxane solution on a partially post-exposure baked photoresist layer. The post-exposure baked photoresist layer may then be developed to form the patterned photoresist layer. The method may be used to form a hydrophobic photoimageable nozzle plate of a micro-fluid ejection head having improved mechanical properties and stable hydrophobic properties.
Owner:FUNAI ELECTRIC CO LTD

Preparation method and application of biomimetic superhydrophobic membrane based on copper foam

The invention belongs to the field of a composite material, relates to a copper foam film material and especially relates to a preparation method for a bionic super-hydrophobic film taking copper foam as a substrate and an application thereof. The method comprises the following steps: firstly, pre-treating the copper foam and removing surface impurities; soaking in an aqueous solution containing ammonium persulfate and phosphate, thereby forming a hierarchy structure on the surface thereof; modifying the surface with the hot steam of silane coupling agent aqueous solution, thereby acquiring the bionic super-hydrophobic film taking the copper foam as the substrate. The prepared hydrophobic film is subjected to bionic in-situ growth and chemical steam modification on the copper foam surface; the papillary micro-nano scale dual roughness is formed by the nanosheet on the surface; the prepared hydrophobic film can be used for separating oil from water; the acquired super-hydrophobic film inherits the advantages of developed pore structure, excellent mechanical properties, stable surface rough structure and hydrophobic property, high reusability and high operability of the copper foam; the soil-water separation efficiency is obviously increased; the continuous efficient soil-water separation is realized; the bionic super-hydrophobic film is an oil-water separating material with prospects.
Owner:JIANGSU SAFELY ENVIRONMENT ENG

Hydrophobic mesoporous nano material and preparation method thereof

The preparation method comprises the following steps: (1) reacting a mixed solution containing zirconium chloride, terephthalic acid, inorganic acid, aromatic monocarboxylic acid and N, N-dimethylformamide to obtain a metal organic framework material; (2) dispersing the metal organic framework material in a monocarboxylic acid solution for reaction to obtain a mesoporous metal organic framework material; and (3) dispersing the mesoporous metal organic framework material in n-heptane, adding low-molecular-weight polysiloxane, and curing to obtain the hydrophobic mesoporous material. Aromatic monocarboxylic acid benzoic acid is added in the process of synthesizing UIO-66 to cause defects at coordination sites, then monocarboxylic acid is used for carrying out ligand exchange on the coordination sites of UIO-66 and terephthalic acid at high temperature and high pressure, the defects are expanded, pore channels of several nanometers to dozens of nanometers are formed, and the UIO-66 is synthesized. And finally, carrying out cross-linking curing on the surface of the nano material by using low-molecular-weight polysiloxane under a vacuum condition to form a layer of hydrophobic membrane.
Owner:NANJING UNIV OF TECH +1

A method for hydrophobizing modification of ramie nanocellulose

The invention provides a hydrophobization modification method for ramie nano cellulose. The method comprises the steps of preprocessing ramie nano cellulose and xylan, then carrying out modification reaction on the ramie nano cellulose and xylan, adding the soaked and wetted ramie nano cellulose into a hardwood xylan solution, putting into ultrasonic and dispersing, stirring by a machine, layering the mixture by centrifuging, transferring the upper layer clear liquor, and molding the left concentrated ramie nano cellulose suspension liquid through liquid nitrogen vacuum freeze drying so as to obtain the dehydrated modified ramie nano cellulose. Dehydrated modification is carried out on the ramie nano cellulose by using the acetylation of the hardwood xylan, so that the polarity and hydrophilia of plant fiber are lowered, the agglomeration of nano cellulose is inhibited, and the interfacial compatibility and cohesiveness of the ramie nano cellulose and the hydrophobic resin are improved. The method is simple and efficient, has good repeatability, has environment-friendly processes, uses the environment-friendly modification reagents, and has great scientific significance and considerable application prospect.
Owner:DONGHUA UNIV

Method for improving desalination stability of porous ceramic membrane by constructing hydrophobic protective layer

ActiveCN113731187AStable hydrophobicityObvious hydrophobic protectionMembranesDistillationCeramic membraneNano silicon dioxide
The invention provides a method for improving the desalination stability of a porous ceramic membrane by constructing a hydrophobic protective layer. The method comprises the following steps: firstly, carrying out hydrophobic modification on the surface of a porous ceramic membrane by using a hydrophobic modifier, then spraying a pore-forming agent solution on the surface of the porous ceramic membrane, and drying to crystallize the porous ceramic membrane into pore-forming agent particles; then, diluting PDMS with an organic matter, and adding a certain proportion of hydrophobic nano silicon dioxide particles; uniformly spraying a PDMS solution containing SiO2 onto the surface of the ceramic membrane on which the pore-forming agent particles are fully distributed, and curing; and soaking the cured ceramic membrane in water to dissolve the pore-forming agent particles, and drying to obtain the porous ceramic membrane with a porous PDMS protective layer constructed on the surface. The obtained ceramic membrane has the advantages of being good in air permeability, high in hydrophobic stability, stable in chemical property, low in cost, simple in method and the like, when the ceramic membrane is applied to membrane distillation desalination, the desalination rate is kept 100%, and continuous experimental operation can be conducted for 300 h or above.
Owner:BEIJING UNIV OF TECH

A method for modifying polyvinyl alcohol fibers used in high ductility cement-based composites

The invention provides a method for modifying polyvinyl alcohol fiber for a high-ductility cement-based composite material. The surface of the polyvinyl alcohol fiber contains a large amount of hydroxyl groups, the hydroxyl groups on the surface of the polyvinyl alcohol fiber react with a cement matrix to form a relatively strong chemical bonding force, and the strong chemical bonding force causesfiber breakage in the pull-out process, so that the ductility is affected. The method comprises the following steps: with the polyvinyl alcohol fiber as a raw material, firstly coating the surface ofthe polyvinyl alcohol fiber with a layer of epoxy resin, and then coating the surface of epoxy resin coating with a layer of fumed silica powder. Due to surface hydrophobicity of the modified polyvinyl alcohol fiber, the interfacial strength between the polyvinyl alcohol fiber and the cement matrix can be effectively weakened and the chemical bonding force can be reduced, so that the polyvinyl alcohol fiber is pulled out of the cement matrix in the stretching process, without breakage; the hydrophobicity and the wear-resistant slip property of a product are more stable, and the coating is more wear-resistant and the original physical and mechanical properties of the PVA fiber are not affected.
Owner:SOUTHEAST UNIV

Preparation method of durable hydrophobic fabric

The invention provides a preparation method of a durable hydrophobic fabric. The preparation method of the durable hydrophobic fabric comprises the steps of, firstly, preparing hydrophobic cross-linked polystyrene microspheres; secondly, performing surface modification on the prepared hydrophobic cross-linked polystyrene microspheres to form reaction-active -NCO functional groups on the surface of the hydrophobic cross-linked polystyrene microspheres; thirdly, grafting the modified hydrophobic cross-linked polystyrene microspheres onto the surface of a fabric to obtain the durable hydrophobic fabric. The prepared hydrophobic cross-linked polystyrene microspheres are stable in performance, simple in technical processes, low in raw material cost and easy to produce; by structuring a hydrophobic structure on the surface of the fabric through the surface-modified hydrophobic cross-linked polystyrene microspheres, significant hydrophobic effects can be achieved and maintained for a relatively long term; the processing temperature is mild and can effectively reduce influence on the original performance of the fabric; through a chemical bonding mode, the surface-modified hydrophobic cross-linked polystyrene microspheres are grafted to the surface of the fabric, so that the fabric can keep good hydrophobic effects after being washed for a number of times.
Owner:DONGHUA UNIV +1
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