The invention discloses tea vinegar capable of clearing away heat and toxic materials. The tea vinegar is prepared from the following ingredients in parts by weight: 25-30 parts of peony flowers, 5-8parts of moutan bark, 10-15 parts of green tea, 12-16 parts of flos chrysanthemi, 7-10 parts of honeysuckle flowers, 6-10 parts of fructus forsythia, 3-7 parts of radix geutianae, 5-9 parts of radix trichosanthis, 7-11 parts of honey, 5-10 parts of lemon vinegar, 3-6 parts of vitamin, and 90-110 parts of purified water. The invention further discloses a preparation method of the tea vinegar capable of clearing away heat and toxic materials. For the tea vinegar and the preparation method, the raw materials are easily available, the preparation method is simple, and the industrial production canbe easily realized; the tea vinegar is rich in nutrition, has the palatable sweet and sour taste, has the rich tea aroma, is special in mouthfeel, and belongs to the novel health tea vinegar. The teavinegar has the efficacies of clearing away heat and toxic materials, helping producing saliva and slaking thirst, resisting bacteria and diminishing inflammation, and improving the body immunity.