The invention provides a three-dimensional ordered macroporous
titanate and an in-situ self-sacrificial preparation method thereof. The preparation method comprises the following steps: step 1, preparing a monodisperse
microsphere colloidal crystal template; step 2, preparing a
titanium dioxide precursor; step 3, adding the
colloidal crystal template into the
titanium dioxide precursor, placing the
titanium dioxide precursor filled with the
colloidal crystal template under a vacuum condition for dipping, taking out the
titanium dioxide precursor filled with the colloidal
crystal template, andcarrying out filtering and standing; step 4, calcining the colloidal
crystal template filled with the
titanium dioxide precursor in an
air atmosphere to obtain three-dimensional ordered macroporous
titanium dioxide; and step 5, placing the three-dimensional ordered macroporous titanium dioxide in a
metal ion solution which shows
alkalinity, and carrying out a
hydrothermal reaction to obtain the three-dimensional ordered macroporous
titanate. According to the invention, firstly, the three-dimensional ordered macroporous titanium dioxide is prepared, and then the three-dimensional ordered macroporous titanium dioxide is converted into the three-dimensional ordered macroporous
titanate, so that a process of synthesizing a titanate precursor solution is avoided, and the disadvantages of low
filling rate, incomplete pore structure of a material, large product shrinkage ratio and the like caused by low
viscosity of the titanate precursor solution are overcome.