The invention belongs to the technical field of 
fuel cells and provides an in-situ preparation method of a carbonized film on the surface of a Fe-Ni-Cr bipolar plate. The in-situ preparation method is characterized by comprising the following steps of: (1) 
alloy component selecting and melting, namely, mixing the components based on that the atomic percentage content of the component Fe is x, the atomic percentage content of the component Ni is y and the atomic percentage content of the component Cr is z and carrying out 
vacuum induction melting on the FexNiyCrz 
alloy, wherein x is equal to 37-39%, y is equal to 32-34%, z is equal to 28-30% and the sum of x, y and z is 100%; (2) 
metal plate forming 
processing, namely, 
processing the FexNiyCrz 
alloy into a 
metal plate with a flow field according to the conventional method; and (3) in-situ surface treatment, namely, carrying out surface 
acid treatment (a), low-temperature heating treatment (b) and electrochemical treatment (c) on the 
metal plate with the flow field obtained in the step (2) in sequence, thus obtaining the Fe-Ni-Cr alloy bipolar plate of a fuel 
cell. The bipolar plate of the fuel 
cell, prepared by using the method, has excellent 
corrosion resistance and electrical 
conductivity, and is simple in manufacturing process, low in cost, not easy to deform and suitable for assembling fuel 
cell stacks.