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114results about How to "Improve voltage efficiency" patented technology

Mono-trapezoid flow battery, poly-trapezoid flow battery and electric pile thereof

The invention provides a mono-trapezoid flow battery, a poly-trapezoid flow battery and an electric pile thereof. Both a cathode porous electrode and an anode porous electrode in the mono-trapezoid flow battery are trapezoidal plate electrodes and are respectively arranged inside a cathode electrolyte flow frame and an anode electrolyte flow frame. On the cathode electrolyte flow frame and the anode electrolyte flow frame, two electrolyte inlet flow paths are arranged nearby the lower bottom edges respectively of the cathode porous electrode and the anode porous electrode, and two electrolyte outlet flow paths are arranged nearby the upper bottom edges respectively of the cathode porous electrode and the anode porous electrode. The electrolyte flows into the cathode porous electrode through the lower bottom edges of the cathode porous electrode and the anode porous electrode and then flows out from the upper bottom edges of the cathode porous electrode and the anode porous electrode. The trapezoid flow battery is reduced in concentration polarization at certain degree and further is reduced in voltage loss, and meanwhile, is improved in utilization efficiency of the electrolyte and is increased in total efficiency.
Owner:DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI

Modified electrode for full-vanadium flow battery and preparation method thereof

The invention belongs to the technical field of electrode material surface treatment and especially relates to a modified electrode for a full-vanadium flow battery and a preparation method thereof. A carbon paper or a carbon felt is used as a modified electrode base material. An antimonic stannic oxide nanometer particle is attached to the surface of the carbon paper or the carbon felt fiber. The preparation method for the modified electrode is characterized by comprising the following steps: utilizing stannic chloride, antimony chloride and isopropyl alcohol to prepare a precursor solution; stirring for 30min at 80 DEG C and ageing for 24h; soaking the carbon paper or the carbon felt into the solution; adopting a pulling method for attaching the nanometer particle from the related solution to the surface of the carbon paper or the carbon felt fiber; drying at 80-150 DEG C; and finally, putting the dried carbon paper into a tube furnace, and calcining for 90min at 450-550 DEG C, thereby completing the preparation of the modified electrode. The invention provides the modified electrode which has a simple structure and is convenient in preparation method. After the modified electrode is applied to the full-vanadium flow battery, the problems of insufficient anode activity and oxygen evolution side reaction of the full-vanadium flow battery can be solved.
Owner:BEIHANG UNIV

Method for modifying carbon porous material

The invention provides a method for modifying a carbon porous material, characterized in that by applying a high pressure pulse voltage on two opposite plate electrodes and inserting an electrolyte plate which has a high dielectric constant and a compact structure and has an area that is slightly larger than the size of the plate electrodes between the two opposite plate electrodes, a uniform discharge plasma reaction zone is formed between the plate electrodes; mixed gasses containing oxygen are uniformly mixed at normal temperatures and pressures, the mixed gasses are subject to ionization activation by the plasma reaction zone to generate a plurality of oxygen-containing plasma gasses, after gas distribution is carried out, the gasses vertically flow through a pre-cleaned carbon porous material in the thickness direction to react to obtain the activated carbon porous material. The method has the advantages of environmental protection, low cost, mild treatment conditions, easy control of function group quantity, and outstanding improvement of the activity of the electrode material, and the method can realize gradient treatment, can reduce the area resistance of the contacting surface of the porous material and the bipolar plate, so as to increase the battery efficiency. The method uses devices, thus the method is easy for industrialized operation.
Owner:DONGFANG TURBINE CO LTD

Method for chemically plating Ni-W-P on carbon felt electrode material of modified redox flow battery

The invention discloses a method for chemically plating Ni-W-P on a carbon felt electrode material of a modified redox flow battery. The method comprises the steps of carrying out cleaning and impurity removal on a PAN (Polyacrylonitrile) carbon fiber felt material; preparing a roughening solution from nitric Acid and sulfate, and soaking the PAN carbon fiber felt material in the roughening solution for increasing the surface area of the PAN carbon fiber felt material; preparing a sensitized-activated solution, and soaking the PAN carbon fiber felt material in the sensitized-activated solution; soaking the PAN carbon fiber felt material after sensitization-activation treatment in deionized water, and cleaning to be neutral; drying; chemically plating the dried PAN carbon fiber felt material in a plating solution to enable the surface to be plated with a uniform Ni-W-P alloy layer; cleaning the plated PAN carbon fiber felt material in the deionized water to be neutral; and drying for 8-10h at the temperature of 100-200 DEG C. The method for chemically plating Ni-W-P on the carbon felt electrode material of the modified redox flow battery is simple and feasible, is easy to operate and is low in the cost; with the adoption of the method, the whole performance, including the energy efficiency, the coulombic efficiency and the voltage efficiency, of the Fe / Cr redox flow battery are all improved by about 5 percent.
Owner:DALIAN UNIV OF TECH

Novel bipolar plate for vanadium battery and preparation method of novel bipolar plate

The invention relates to the field of the manufacture of vanadium batteries, in particular to a novel bipolar plate for a vanadium battery and a preparation method of the novel bipolar plate and solves the problems of great physical internal resistance, low voltage efficiency, uneven voltage of a single piece and the like of the battery in the prior art. The bipolar plate disclosed by the invention consists of four parts, namely a carbon material, a grid-shaped two-side through-hole resin plate, a conductive filler and a carbon material. The grid-shaped two-side through-hole resin plate and the conductive filler are used as a framework layer to be firstly manufactured into a low conductive plastic plate through a hot-press method. Then, the composite carbon materials on both sides of the low conductive plastic plate are subjected to hot press molding again so as to obtain the novel high conductive bipolar plate for the vanadium battery. According to the working requirements of the vanadium battery, for most of the existing bipolar plates, the process of using multiple steps of mixing or stirring and the like is simplified, the preparation process is simple, and only the production device namely a hot press is adopted to complete processing. The bipolar plate disclosed by the invention has high electric conductivity, the contact resistance between electrodes and the bipolar plate is very little, the physical internal resistance of the vanadium battery can be greatly reduced, the energy capacity of the vanadium battery can be increased, and therefore, the cost of the vanadium battery is reduced.
Owner:INST OF METAL RESEARCH - CHINESE ACAD OF SCI

Method and device for removing heavy metal ions in wastewater by virtue of photoelectrocatalysis

The invention relates to a method and a device for removing heavy metal ions in wastewater by virtue of photoelectrocatalysis. According to the method, a metal material is used as a photo-anode, an organic substance contained in a reaction solution is used as a reducing agent, the organic substance is excited by virtue of ultraviolet illumination to generate free electrons and active free radicals, the active free radicals move to the photo-anode and are oxidized under the action of an external electric field, and the free electrons reduce the heavy metal ions in the solution. The device comprises a metal photo-anode, a counter electrode, a direct-current power supply, an ultraviolet source and a reaction vessel. Under an experimental condition, the rate of reducing Cr (VI) in the wastewater by virtue of titanium mesh photo-anode photoelectrocatalysis is 5.5 times that of typical TiO2 film semiconductor catalyst under the same reaction condition, and the repeatability is very good. The method and the device provided by the invention overcome certain defects of a photoelectrocatalysis technology and an electrocatalysis technology, and a new method capable of efficiently degrading the heavy metal ions in the wastewater is put forward, and the method is very high in practical value and application prospect, and is easy to popularize and use.
Owner:PEKING UNIV
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