The invention discloses a coating material used for preventing the air leakage of a laneway, an application method and a special spray gun thereof. The components of the coating material are clay, cement, sodium silicate, glass fiber and water which are mixed, stirred and made into clay cement slurry according to certain proportion and processes. The clay cement slurry is transported to an underground spraying area by a slurry pump through a grouting pipe, and sprayed to a coal roadway wall by the special spray gun to prevent the air leakage of the laneway. The clay cement slurry has strong suspension property, short initial concreting time, certain strength after solidification, rinse-resistance, not easy craze, excellent air partition performance, strong flame-retardant property, ideal effect of preventing the air leakage of the laneway, quick shotcreting process operations, safety and simplicity, is applicable to the spraying to the coal roadway walls of mines with serious hazards, and prevents the air leakage of the laneway so as to reduce the possibility of the occurrence of spontaneous combustion.