The invention relates to a preparation method of a composite decoloring flocculant for printing and
dyeing wastewater treatment. The preparation method comprises the following steps: firstly dissolving aluminum-containing waste residues by using acid-washing
wastewater and
sulfuric acid, adding Mg<2+>, Zn<2+> and Mn<2+>, adding
chlorate to oxidize Fe<2+> and consume acid, so as to enable Fe<3+>, Al<3+> and the like to be subjected to hydrolytic
polymerization; then adding a
silane coupling agent for ydrolysis and
telomerization, adding a dicyandiamide-triethylene
tetramine condensation polymer, and performing heat preservation and curing to obtain the composite decoloring flocculant. The composite decoloring flocculant obtained by the preparation method comprises a variety of components facilitating the action with
wastewater pollutants, is larger in molecular aggregate and excellent in decoloring, COD-removing and
turbidity-removing effects on printing and
dyeing wastewater under the synergistic effect of all the components and does not introduce new
pollution; generally, the GB4287-2012 emission standards can be met only through one-step
flocculation, so that the process is simplified, and the cost is reduced. According to the preparation method provided by the invention, the steel and iron
acid washing wastewater as well as aluminum-containing waste residues from aluminum
processing can be simultaneously treated, so that the
resource utilization is realized; the preparation method is simple in process, easy for realization of industrialization and broad in application prospect.