The invention relates to the field of spectrochemistry, and relates to a device for studying a macromolecular
ion photoelectron spectrum. The device comprises a vacuum cavity, a droplet ejector, an
ion buncher, a
quadrupole mass filter, an
ion trap, an air inlet, an exit lens, a shield cover, a speed imaging disk, a
laser, a multi-channel disk, a
detector, a computer, an input / output module, fieldprogrammable logic device, a digital-to-analog conversion module, a high-
voltage power supply, a drive circuit and a
vacuum pump set. A method of
resonance of a drive unit and liquid is utilized to eject droplets; a vibration direction of the drive unit is parallel to a droplet ejecting direction, so that the device can form uniform droplets with relatively small size, has no special requirementfor a
solvent, does not need to apply a
high voltage to the solution during ejection, is applicable to a wider range of macromolecular species, utilizes a digital trapezoidal waveform
voltage to drivethe
quadrupole mass filter, obtains a charge-to-
mass ratio spectrum by scanning the frequency, can measure particles with a relatively large charge-to-
mass ratio, can minimize
harmonics in the
voltage, and obtains a relatively high
signal resolution.