The invention relates to a linear conjugated 
polymer derivate material with a 9-pyrenyl 
fluorine structure and a preparation method thereof. The material can be applied in the plastic electronic fields such as 
polymer electroluminescent materials, 
polymer integrated circuits, polymer solar batteries, polymer thin-film transistors, polymer dye lasers, polymer 
nonlinear optical materials, fluorescent probes and so on. The polymer combines two high-performance systems of 
pyrene and 
fluorine together by non-conjugated means, and has the advantages that: firstly, the raw materials are low-price, and the synthetic method is simple and convenient; and secondly, the material also has obviously improved hole injection capacity, hole transmitting capacity and electronic transmitting capacity besides good 
solubility, 
thermal stability and rheologic property, and a 
hole injection layer, a hole transmitting layer and an electronic transmitting layer can be not required in an electroluminescent device, thereby the technique of the device is simplified. The electroluminescent device prepared by utilization of the material is satisfactory in the aspects of brightness, luminous efficiency, 
voltage-resistant stability and so on.