The invention discloses an inner salt type high-
energy density insensitive explosive and a preparation method thereof, 9-amino-2, 6-dinitro-bis [1, 2, 4] triazolo [1, 3, 5]
triazine, namely ZDTT, is prepared, and the ZDTT has the performance advantages of
high energy density and insensitivity and also has the
advantage of simple synthesis process; zDTT has a unique inner salt type condensed ring structure and is insoluble in water and conventional organic solvents. The ZDTT actual measurement density is 1.881 g.cm <-3 >, the
detonation velocity is 8757 m.s <-1 >, the
detonation pressure is 31.7 GPa, the initial
thermal decomposition temperature is 330 DEG C, the
impact sensitivity is larger than 40 J, the
friction sensitivity is larger than 360 N, and the high-energy-density insensitive explosive has huge application potential in the field of high-energy-density insensitive explosives.