The invention provides a variable-concentration directly-heated type heat pump water heater with flash evaporators and a working method thereof. The variable-concentration directly-heated type heat pump water heater with the flash evaporators comprises a main circulation loop, an air supplementing branch and a concentration adjusting branch, and the main circulation loop is formed by connecting acompressor, a condenser, a high-pressure liquid storage device, a subcooler, a first expansion valve, the flash evaporator, a first stop valve, a third stop valve, a second expansion valve and an evaporator; the air supplementing branch is provided with the flash evaporator and a second stop valve which are connected in sequence; and the concentration adjusting branch is formed by connecting a working medium supplementing expansion valve, a component separation and working medium storage tank, an air supplementing concentration adjusting valve and a liquid supplementing concentration adjustingvalve. According to the variable-concentration directly-heated type heat pump water heater, based on the principle of advantage complementation, enhanced vapor injection and working medium concentration adjusting technologies are comprehensively applied to the heat pump water heater, the low-temperature performance and annual comprehensive energy efficiency of the heat pump water heater can be remarkably improved, meanwhile, the applicable temperature range of the heat pump water heater is obviously widened, and the heat pump water heater further has the advantages of being simple in rectification structure, high in component separation efficiency, safe, reliable and the like.