The invention belongs to the technical field of production of electronic materials, and concretely relates to a membrane process preparation method of electronic-grade 1,3-propanesultone. The method comprises the following steps: standing 1,3-propanesultone in a reactor provided with a molecular sieve, carrying out reduced pressure distillation, removing impurities through a nanofiltration device, concentrating the obtained 1,3-propanesultone through a disc tube type reverse osmosis device, and allowing the obtained 1,3-propanesultone to pass through the glass column of the molecular sieve. The acid value of the prepared 1,3-propanesultone is stably controlled in a required range, all indexes of the prepared 1,3-propanesultone are qualified, the quality of the prepared 1,3-propanesultone is stable, the water content and the sodium content of the prepared 1,3-propanesultone are further reduced and are better than electronic grade standards, and the indexes of the prepared 1,3-propanesultone exceed those of most existing electronic-grade 1,3-propanesultone.