The invention relates to the technical field of
tungsten recovery, in particular to a method for recovering
tungsten and
ammonia from
ammonium tungstate feed liquid sulfuration
impurity removal
slag. The method comprises the following steps: (1) adding a stripping
tower discharge material liquid into the sulfuration
impurity removal
slag for size mixing to obtain a size mixing material liquid, the temperature of the stripping
tower discharge material liquid is more than 80 DEG C, the
alkalinity is 4-5g / l, and the
ammonia nitrogen content is less than or equal to 10ppm; (2) adding alkali into the
slurry mixing liquid at a preset temperature, and maintaining the
alkalinity of the solution within a first range to obtain a
solid-liquid mixture; (3) filtering the
solid-liquid mixture to obtain primary filtrate and primary filter residues, and performing steam stripping
deamination on the primary filtrate; (4) adding an acid solution into the primary filter residue and maintaining the acidity of the solution within a second range to obtain a dissolved solution; and (5) adsorbing the dissolved solution by using anion resin, and analyzing to obtain the
tungsten recovery solution. By adopting the method provided by the invention, the tungsten
recovery rate can be improved, the process is few, and the consumption of steam and caustic soda flakes is greatly reduced; the amount of
slag after
acid treatment is small, and secondary slag treatment is reduced; and the cost effect is obviously reduced.