The invention discloses a
composite film with high electrochemical performance and a preparation method of the
composite film, and belongs to the field of
composite material preparation. The
composite film is formed by alternately self-assembling amphipathic
ruthenium complex molecular films and symmetrical
ruthenium complex molecular films, a
highly oriented pyrolytic graphite(
Highly Oriented Pyrolytic Graphite, HOPG) is used as a base, wherein an amphipathic
ruthenium complex is [Ru(Py2G1MeBip)(XPOH)](PF6)2, and a symmetrical ruthenium complex is [Ru(XPOH)2](PF6)2. The composite film obtained by the preparation method disclosed by the invention is uniformly and sufficiently modified on the electric conduction base, so that the composite film has favorable
mechanical stability and
chemical stability. The composite film unifies the respective advantages of two kinds of materials, so that compared with a single self-
assembly film, the electrochemical performance and the stability of the composite film are obviously improved. The composite film can be operated by using a simple container under a
room temperature without special conditions or complex costly instruments. Compared with other layered
assembly techniques, the composite film disclosed by the invention is simple and convenient to operate, is short in
assembly time, is high in
bond strength with the base, and has better popularization and application values.