The invention provides a novel high-performance hydrofluoric acid-resistance artificial functional composite plate and a preparation method thereof. The plate is mainly made of barite aggregate, resin and a serial of modified agents. According to the preparation method, the finished plate can be formed after a serial of processes of barite packing graduation, special resin and the serial of modified agents adding, mixing and stirring, organic combination reaction, plate blank forming, high-temperature and high-pressure reaction, high-frequency vibration, cure reaction (80-120 DEG C), thickness determining, polishing, bridge cutting, detection and the like. The composite plate has special anti-corrosion performance, excellent mechanical performance and durability, and is superior in product conveying, installation, maintenance and the like.