The invention relates to an electrode, in particular to a chemically modified bismuth membrane electrode. The bismuth membrane electrode is prepared by the following steps: mixing Nafion and ionophore according to the volume fraction of 1:1-1:1.5, and conducting ultrasound on the mixture for 20-40min to be uniform, then dripping the mixture to the surface of glassy carbon electrode polished cleanly, drying the mixture at room temperature, subsequently hardening the mixture by blowing hot air to the mixture, after the mixture cools to room temperature, putting the glassy carbon electrode to acetic acid-sodium acetate buffer solution which contains 100-1, 500mug/L Bi(III) and has the pH being 4.5, and applying -1.2V electric potential under stirring situation for 180s of deposition and enrichment. The electrode is simple in making, small, exquisite and nimble, wherein the sensitivity is up to 31.38nA/Nm, the detection limit can be up to 4.4 multiplied by 10-11M. The electrode can be used in the application fields such as environmental monitoring, food security and clinical detection and the like with simple operation and short test process, and can also be used for detecting the content of heavy metal in seawater, fresh water, blood, urine samples and vegetables.