The invention provides an ionization degree detecting sampling device for an electrolyte solution for hemofiltration. The device includes a movable cover, the bottom of the movable cover is fixedly installed on the top end of a hollow column, a center column penetrates an inner axis of the movable cover, and the upper end side wall of the center column is movably installed in the middle of a guiderod; and a rotating rod is movably installed at the part, located at the right side of the center column, of the guide rod, the top end of the rotating rod penetrates the top end of the movable coverand is movably connected to the upper end of a flow pipe, and the lower side of the bottom end of the flow pipe is movably connected to the upper side of a through groove. When a center shaft moves towards the right side, a pipe in the center column can be straightened, the pipe is in a straightened state in the center column, so that a period of dialysis time can be reserved for blood in the curved pipe to ensure the filtration effect, the pipe is straightened, the activity of the blood can be accelerated through shaking of the pipe, a dialysate can be promoted to balance impurities in the blood, the efficiency can be improved, and the time of triggering ischemia risk during patient dialysis can be reduced.