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34 results about "J-aggregate" patented technology

A J-aggregate is a type of dye with an absorption band that shifts to a longer wavelength (bathochromic shift) of increasing sharpness (higher absorption coefficient) when it aggregates under the influence of a solvent or additive or concentration as a result of supramolecular self-organisation. The dye can be characterized further by a small Stokes shift with a narrow band. The J in J-aggregate refers to E.E. Jelley who discovered the phenomenon in 1936. The dye is also called a Scheibe aggregate after G. Scheibe who also independently published on this topic in 1937.

Light-sensitive silver halide photographic film material and radiographic intensifying screen-film combination

A light-sensitive silver halide photographic film material has been provided, said film material comprising a transparent support and on both sides thereof at least one light-sensitive emulsion layer having spectrally and chemically sensitized tabular silver halide grains rich in silver bromide, further having silver iodide in an amount of less than 3 mole % based on silver, with two flat parallel {111} crystal faces, said grains accounting for a total projective surface of said parallel crystal faces in said emulsion of at least 50%, further having an average aspect ratio of at least 2:1, a grain thickness of from 0.05 up to 0.15 mum, a site-directing azacyanine compound satisfying the general formulae disclosed herein in an amount of not less than 1x10-4 mole per mole of silver halide coated and one or more J-aggregating spectrally sensitizing dye(s), wherein a molar ratio amount between said site directing compound and said J-aggregating spectrally sensitizing dye(s) is at least 1:6 for a grain coverage of said {111} tabular grains exceeding 50%.A radiographic screen / film combination has also been described comprising said light-sensitive silver halide photographic film material and two supporting or self-supporting X-ray intensifying screens) comprising luminescent phosphors, wherein by contacting the film material with a sandwich of a pair of said intensifying screens and exposing said combination to X-rays, emission of radiation by said luminescent phosphors in the wavelength range for which said material has been made spectrally sensitive provides a black-and-white diagnostic image after processing of said exposed radiographic film material.
Owner:AGFA NV

Mammography imaging method using high peak voltage and rhodium or tungsten anodes

A method of mammography imaging includes exposing a patient to a peak voltage greater than 29 kVp using X-radiation generating equipment comprising rhodium or tungsten anodes. The film used in this method comprises a cubic grain silver halide emulsion layer on one side of the support and a tabular grain silver halide emulsion layer on the other side. The cubic grain silver halide emulsion layer comprises a combination of first and second spectral sensitizing dyes that provides a combined maximum J-aggregate absorption on the cubic silver halide grains of from about 540 to about 560 nm. The first spectral sensitizing dye is an anionic benzimidazole-benzoxazole carbocyanine, the second spectral sensitizing dye is an anionic oxycarbocyanine. The cubic grain silver halide emulsion layer also includes a mixture of gelatin or a gelatin derivative and a second hydrophilic binder other than gelatin or a gelatin derivative. The cubic silver halide grains comprise from about 1 to about 20 mol % chloride and from about 0.25 to about 1.5 mol % iodide, both based on total silver in the cubic grain emulsion layer, which cubic silver halide grains have an average ECD of from about 0.65 to about 0.8 μm. Moreover, the cubic silver halide grains are doped with a hexacoordination complex compound within part or all of the innermost 95% of the grains. The film can be exposed to provide a black-and-white image having a d(γ)/d(log E) value greater than 5.
Owner:CARESTREAM HEALTH INC

Intelligent membrane based on supermolecule and preparation method thereof

The invention provides an intelligent membrane comprising a supramolecular structure and polymer materials and a preparation method of the intelligent membrane. The intelligent membrane comprises a basilemma of which the surface has a polycation graft chain, and a supramolecular structure of porphyrin, wherein the basilemma is obtained by the membrane surface grafting modification, and can interact with the porphyrin to realize porphyrin load and the supramolecular structure. When the pH of material liquid is less than 1.2, the porphyrin forms a J-aggregated supramolecular structure, the water flux of the membrane is smaller, and reject rate is high; when the pH of the material liquid is greater than 4.0, the porphyrin forms an H-aggregated supramolecular structure, the water flux of the membrane is greater, and reject rate is low. When the pH of the material liquid gradually changes from the pH less than1.2 to the pH greater than 4.0, the J-aggregated supramolecular structure is gradually transformed into the H-aggregated supramolecular structure, the water flux of the membrane is increased, the reject rate is lowered, the process is reversible, and the intelligent membrane has pH-responsiveness. The intelligent membrane and the preparation method thereof can be applied to the relevant fields of separation and purification, water treatment, chemical sensors and the like.
Owner:TIANJIN POLYTECHNIC UNIV

Preparation method and application of j-aggregate photothermal nanoagent based on dyes and polymers

The invention relates to a preparation method and application of a J aggregate photothermal nano-agent constructed based on dyes and polymers. The nanophotothermal reagent takes fluoroborondipyrrole dye molecules and high molecular polymers as basic building units, and is co-assembled in an aqueous solution to obtain a J-aggregate nanosolution that can be stably dispersed in the aqueous system. The formation of J aggregates changes the photophysical / chemical properties of the dye molecules, the absorption spectrum is red-shifted by more than 100 nanometers, and the molar extinction coefficient increases significantly, showing a good photothermal conversion effect. Combined with further supramolecular structure remodeling, the morphology of the J-aggregate material is transformed into nanoparticles, the cellular uptake rate of the material is enhanced, and the biological application of the material is better realized. The J-aggregate nanophotothermal material proposed in the present invention has many advantages such as good biocompatibility, high photothermal conversion efficiency, and resistance to photobleaching, and has broad application prospects in the fields of photothermal therapy and photoacoustic imaging.
Owner:NANKAI UNIV

A supramolecular-based smart membrane and its preparation method

The invention provides an intelligent membrane comprising a supramolecular structure and polymer materials and a preparation method of the intelligent membrane. The intelligent membrane comprises a basilemma of which the surface has a polycation graft chain, and a supramolecular structure of porphyrin, wherein the basilemma is obtained by the membrane surface grafting modification, and can interact with the porphyrin to realize porphyrin load and the supramolecular structure. When the pH of material liquid is less than 1.2, the porphyrin forms a J-aggregated supramolecular structure, the water flux of the membrane is smaller, and reject rate is high; when the pH of the material liquid is greater than 4.0, the porphyrin forms an H-aggregated supramolecular structure, the water flux of the membrane is greater, and reject rate is low. When the pH of the material liquid gradually changes from the pH less than1.2 to the pH greater than 4.0, the J-aggregated supramolecular structure is gradually transformed into the H-aggregated supramolecular structure, the water flux of the membrane is increased, the reject rate is lowered, the process is reversible, and the intelligent membrane has pH-responsiveness. The intelligent membrane and the preparation method thereof can be applied to the relevant fields of separation and purification, water treatment, chemical sensors and the like.
Owner:TIANJIN POLYTECHNIC UNIV

A flocculant with excellent dehydration of floc sediment

The invention provides a flocculating agent with an excellent floc precipitate dehydrating property and a preparation method thereof which are applied to the sewage treatment industry, and belongs to the technical field of environment friendliness. According to the preparation method, a mixture which is in a network-shaped molecular structure is finally formed to serve as the flocculating agent by performing a substitution reaction and a polymerization reaction on chitosan, tetraethoxysilane, aluminium nitrate and iron oxide serving as raw materials; the preparation method has the characteristics that the floc formation speed is high, floc aggregates are large and cannot be re-dissolved, the formed sewage is easy to dehydrate and is easy to degrade; the removal rate of suspended solids reaches up to 97 percent; the capillary water suction time is below 24 seconds. The flocculating agent with the excellent floc precipitate dehydrating property and the preparation method thereof have the advantages that the flocculating agent and the formed flocs are of porous structures on a micro level; pores are mutually communicated with one another from interiors to body surfaces; water in sewage can naturally permeate from the pores, so that the sewage formed by the flocculating agent has the excellent dehydrating property.
Owner:SHANDONG DESHI CHEM IND CO LTD

A method for measuring the mixing ratio of coarse and fine aggregate

A measuring method for a mixing proportion of coarse and fine aggregate relates to the field of building construction. A first contrast group is prepared, aggregate of the particle size of 0mm to 120mm is separated into eight piles of aggregate via screen meshes in the diameters of 80mm, 40mm, 20mm, 5mm, 1mm, 0.5mm and 0.25mm sequentially, and containers of the same model are used to take aggregate from the eight piles to form eight groups numbered from 1 to 8 respectively; and a second contrast group is prepared, containers of the above model are used, aggregate of any two of the eight piles is taken and mixed and stirred fully in one container, and twenty eight groups of mixed aggregate, numbered from 9 to 36, are obtained via all combination manners. The groups in the numbers from 1 to 36 are filled into glass grooves of the same depth, length and width, and smoothed out, a power switch of a ground geological radar 2 is switched on, a handheld rod 1 is held by two hands, and pushed to move in the same heights, over the numbers 1 to 36, along the glass grooves, and radar oscillograms of the first and second contrast groups are obtained. The method has the advantages that whether coarse and fine concrete aggregate is mixed uniformly can be detected at any time in the construction process.
Owner:SICHUAN UNIV
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